{"product_id":"biobased-adhesives-9781394174638","title":"Biobased Adhesives","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eBiobased Adhesives Unique and comprehensive book edited by acknowledged leaders on biobased adhesives that will replace petroleum-based adhesives. This book contains 23 chapters covering the various ramifications of biobased adhesives. The chapters are written by world-class scientists and technologists actively involved in the arena of biobased adhesives. The book is divided into three parts: Part 1: Fundamental Aspects; Part 2: Classes of Biobased Adhesives; and Part 3: Applications of Biobased Adhesives. Topics covered include: an introduction to biobased adhesives; adhesion theories and adhesion and surface issues with biobased adhesives; chemistry of adhesives; biorefinery products as biobased raw materials for adhesives; naturally aldehyde-based thermosetting resins; natural crosslinkers; curing and adhesive bond strength development in biobased adhesives; mimicking nature; bio-inspired adhesives; protein adhesives; carbohydrates as adhesives; natural polymer-based adhesives; epo\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003ePreface xvii\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart 1: Fundamental Aspects 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introduction to Naturally-Based (Bio-) Adhesives 3\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eManfred Dunky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 3\u003c\/p\u003e \u003cp\u003e1.2 Overview and Challenges For Adhesives Based on Natural Resources 6\u003c\/p\u003e \u003cp\u003e1.2.1 Combined Use of Synthetic and Naturally-Based Adhesives 8\u003c\/p\u003e \u003cp\u003e1.2.2 Overview on Adhesives Based on Natural Resources 9\u003c\/p\u003e \u003cp\u003e1.2.3 Requirements, Limitations, and Opportunities for Wood Adhesives Based on Natural Resources 11\u003c\/p\u003e \u003cp\u003e1.3 Biorefinery and Platform Chemicals 11\u003c\/p\u003e \u003cp\u003e1.4 Lignin as Raw Material for Platform Chemicals 20\u003c\/p\u003e \u003cp\u003e1.5 5-Hydroxymethylfurfural (5-HMF) as Platform Chemical 23\u003c\/p\u003e \u003cp\u003e1.6 Mimicking Nature 27\u003c\/p\u003e \u003cp\u003e1.7 Special Topics and Latest Developments 29\u003c\/p\u003e \u003cp\u003e1.8 Prospects 30\u003c\/p\u003e \u003cp\u003e1.9 Summary 30\u003c\/p\u003e \u003cp\u003eGeneral Literature on Biobased Adhesives 30\u003c\/p\u003e \u003cp\u003eList of Abbreviations 34\u003c\/p\u003e \u003cp\u003eReferences 35\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Adhesion Theories in Naturally-Based Bonding: Adhesion and Surface Issues with Naturally-Based Adhesives 45\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eDouglas J. Gardner, Geeta Pokhrel and Alexander Collins\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 45\u003c\/p\u003e \u003cp\u003e2.2 Adhesion Theories 46\u003c\/p\u003e \u003cp\u003e2.2.1 Mechanical Interlocking 47\u003c\/p\u003e \u003cp\u003e2.2.2 Electrostatic Mechanism 48\u003c\/p\u003e \u003cp\u003e2.2.3 Adsorption (Thermodynamic) or Wetting Mechanism 49\u003c\/p\u003e \u003cp\u003e2.2.4 Diffusion Mechanism 50\u003c\/p\u003e \u003cp\u003e2.2.5 Chemical (Covalent) Bonding Mechanism 50\u003c\/p\u003e \u003cp\u003e2.2.5.1 Hydrogen Bonding 51\u003c\/p\u003e \u003cp\u003e2.2.6 Acid-Base Theory 51\u003c\/p\u003e \u003cp\u003e2.2.7 Weak Boundary Layers 52\u003c\/p\u003e \u003cp\u003e2.2.8 Stickiness or Tackiness 53\u003c\/p\u003e \u003cp\u003e2.3 Protein Adhesives 54\u003c\/p\u003e \u003cp\u003e2.3.1 Animal-Sourced Proteins 55\u003c\/p\u003e \u003cp\u003e2.3.2 Plant Proteins 57\u003c\/p\u003e \u003cp\u003e2.4 Carbohydrate-Based Adhesives 59\u003c\/p\u003e \u003cp\u003e2.5 Plant or Wood-Based Extractives 60\u003c\/p\u003e \u003cp\u003e2.5.1 Rubber 60\u003c\/p\u003e \u003cp\u003e2.5.2 Resins 61\u003c\/p\u003e \u003cp\u003e2.5.2.1 Rosin 62\u003c\/p\u003e \u003cp\u003e2.5.2.2 Terpene Resins 63\u003c\/p\u003e \u003cp\u003e2.5.2.3 Tannins 64\u003c\/p\u003e \u003cp\u003e2.5.2.4 Gums 65\u003c\/p\u003e \u003cp\u003e2.6 Fats or Oils 66\u003c\/p\u003e \u003cp\u003e2.6.1 Tung Oil 67\u003c\/p\u003e \u003cp\u003e2.6.2 Linseed Oil 68\u003c\/p\u003e \u003cp\u003e2.6.3 Soybean Oil 69\u003c\/p\u003e \u003cp\u003e2.6.4 Castor Oil 70\u003c\/p\u003e \u003cp\u003e2.6.5 Miscellaneous Oils 71\u003c\/p\u003e \u003cp\u003e2.7 Summary 72\u003c\/p\u003e \u003cp\u003eAcknowledgements 72\u003c\/p\u003e \u003cp\u003eList of Abbreviations 72\u003c\/p\u003e \u003cp\u003eReferences 74\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 The Chemistry of Bioadhesives 85\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eA. Pizzi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 85\u003c\/p\u003e \u003cp\u003e3.2 Carbohydrate Bioadhesives 86\u003c\/p\u003e \u003cp\u003e3.3 Protein Bioadhesives 91\u003c\/p\u003e \u003cp\u003e3.4 Lignin-Based Bioadhesives 93\u003c\/p\u003e \u003cp\u003e3.5 Tannin-Based Bioadhesives 95\u003c\/p\u003e \u003cp\u003e3.5.1 Hydrolysable Tannins 96\u003c\/p\u003e \u003cp\u003e3.5.1.1 Gallo-Tannins 96\u003c\/p\u003e \u003cp\u003e3.5.1.2 Ellagi-Tannins 96\u003c\/p\u003e \u003cp\u003e3.5.2 Condensed Polyflavonoid Tannins 96\u003c\/p\u003e \u003cp\u003e3.5.3 Reactions of Condensed Flavonoid Tannins 99\u003c\/p\u003e \u003cp\u003e3.6 Other Bio-Adhesives for Wood Composites 106\u003c\/p\u003e \u003cp\u003e3.7 Summary 108\u003c\/p\u003e \u003cp\u003eList of Abbreviations 109\u003c\/p\u003e \u003cp\u003eReferences 110\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Biorefinery Products as Naturally-Based Key Raw Materials for Adhesives 119\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eJohannes Karl Fink\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Biorefinery Systems 119\u003c\/p\u003e \u003cp\u003e4.1.1 History of Biomaterials 119\u003c\/p\u003e \u003cp\u003e4.1.2 Classification of Biorefinery Systems 120\u003c\/p\u003e \u003cp\u003e4.1.3 Biorefinery Processes 123\u003c\/p\u003e \u003cp\u003e4.1.3.1 Hydrothermal Processes 123\u003c\/p\u003e \u003cp\u003e4.1.3.2 Thermochemical Processes 123\u003c\/p\u003e \u003cp\u003e4.1.3.3 Chemical Processes 124\u003c\/p\u003e \u003cp\u003e4.1.3.4 Biochemical Processes 124\u003c\/p\u003e \u003cp\u003e4.1.3.5 Bacterial Processes 124\u003c\/p\u003e \u003cp\u003e4.1.4 Renewable Materials for Biorefinery 126\u003c\/p\u003e \u003cp\u003e4.1.4.1 Carbohydrates 126\u003c\/p\u003e \u003cp\u003e4.1.4.2 Lignin 126\u003c\/p\u003e \u003cp\u003e4.1.4.3 Triglycerides 127\u003c\/p\u003e \u003cp\u003e4.1.4.4 Mixed Organic Residues 127\u003c\/p\u003e \u003cp\u003e4.2 Biobased Materials 128\u003c\/p\u003e \u003cp\u003e4.2.1 Biobased Monomers 128\u003c\/p\u003e \u003cp\u003e4.2.2 Synthesis Methods 129\u003c\/p\u003e \u003cp\u003e4.2.2.1 L-3,4-Dihydroxyphenylalanine 135\u003c\/p\u003e \u003cp\u003e4.2.2.2 2-Pyrone-4,6-dicarboxylic acid 136\u003c\/p\u003e \u003cp\u003e4.3 Biobased Materials Suitable for Adhesives 137\u003c\/p\u003e \u003cp\u003e4.3.1 Additives 137\u003c\/p\u003e \u003cp\u003e4.3.2 Wood Adhesives 138\u003c\/p\u003e \u003cp\u003e4.3.3 Lignin-Based Adhesives 139\u003c\/p\u003e \u003cp\u003e4.3.4 Biorefinery Process of Kash 139\u003c\/p\u003e \u003cp\u003e4.3.5 Lignin-Phenol Adhesives 140\u003c\/p\u003e \u003cp\u003e4.3.5.1 Enzymatic Hydrolysis of Lignin 141\u003c\/p\u003e \u003cp\u003e4.3.5.2 Biorefinery Residues 142\u003c\/p\u003e \u003cp\u003e4.3.5.3 Phenol Replacement by Lignins 142\u003c\/p\u003e \u003cp\u003e4.3.6 Lignin-Epoxy Adhesives 143\u003c\/p\u003e \u003cp\u003e4.3.7 Lignosulfonates 145\u003c\/p\u003e \u003cp\u003e4.3.8 Tannins 145\u003c\/p\u003e \u003cp\u003e4.3.9 Protein-Based Adhesives 146\u003c\/p\u003e \u003cp\u003e4.4 Synthesis Methods for Biobased Adhesives 147\u003c\/p\u003e \u003cp\u003e4.4.1 Methylolated Wood-Derived Bio-Oil 147\u003c\/p\u003e \u003cp\u003e4.4.2 Biosynthesis of Lignin 148\u003c\/p\u003e \u003cp\u003e4.4.3 Soy-Based Adhesives 149\u003c\/p\u003e \u003cp\u003e4.4.4 Bisphenol A-Glycidyl Methacrylate Replacement 149\u003c\/p\u003e \u003cp\u003e4.5 Modification of Lignin for Better Performance 150\u003c\/p\u003e \u003cp\u003e4.5.1 Functionalization with Aromatic Compounds 152\u003c\/p\u003e \u003cp\u003e4.5.1.1 Functionalization of Lignin 153\u003c\/p\u003e \u003cp\u003e4.5.1.2 Phenolation of Lignin 154\u003c\/p\u003e \u003cp\u003e4.5.2 Organosolv Lignin-Based Materials 155\u003c\/p\u003e \u003cp\u003e4.6 Pressure-Sensitive Adhesives 155\u003c\/p\u003e \u003cp\u003e4.6.1 Lignin as Filler 156\u003c\/p\u003e \u003cp\u003e4.6.2 Biobased Acrylic Compounds 156\u003c\/p\u003e \u003cp\u003e4.6.3 UV-Tunable Pressure-Sensitive Adhesives 157\u003c\/p\u003e \u003cp\u003e4.7 Summary 158\u003c\/p\u003e \u003cp\u003eReferences 158\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Natural Aldehyde-Based Thermosetting Resins 167\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eManfred Dunky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 167\u003c\/p\u003e \u003cp\u003e5.2 Aliphatic Aldehydes 168\u003c\/p\u003e \u003cp\u003e5.2.1 Acetaldehyde 168\u003c\/p\u003e \u003cp\u003e5.2.2 Glyoxal 169\u003c\/p\u003e \u003cp\u003e5.2.2.1 Glyoxalation of Lignin 171\u003c\/p\u003e \u003cp\u003e5.2.2.2 Glyoxylic Acid and Glyoxal 176\u003c\/p\u003e \u003cp\u003e5.2.2.3 Glyoxal and Glutaraldehyde 176\u003c\/p\u003e \u003cp\u003e5.2.2.4 Glyoxal and 5-Hydroxymethylfurfural (5-HMF) 177\u003c\/p\u003e \u003cp\u003e5.2.3 Dimethoxy-Ethanal (Dimethoxy-Acetaldehyde, DME) 177\u003c\/p\u003e \u003cp\u003e5.2.4 Propanal (Propionaldehyde) 178\u003c\/p\u003e \u003cp\u003e5.2.5 Butyraldehyde 178\u003c\/p\u003e \u003cp\u003e5.2.6 Isobutyraldehyde (Isobutanal) 179\u003c\/p\u003e \u003cp\u003e5.2.7 Succinaldehyde (Butandial) 179\u003c\/p\u003e \u003cp\u003e5.2.8 Glutar(di)aldehyde (GA) (Pentandial) 180\u003c\/p\u003e \u003cp\u003e5.3 Aldehydes Based on Cyclic Structures 180\u003c\/p\u003e \u003cp\u003e5.3.1 Furfural (Furfurylaldehyde) 180\u003c\/p\u003e \u003cp\u003e5.3.2 Furfuryl Alcohol (FA) 184\u003c\/p\u003e \u003cp\u003e5.3.3 5-Hydroxymethylfurfural (5-HMF) (see also Chapters 1 and 17) 185\u003c\/p\u003e \u003cp\u003e5.3.4 2,5-Diformylfuran (2,5-Furan-Dicarbaldehyde) 192\u003c\/p\u003e \u003cp\u003e5.3.5 Aromatic Aldehyde Precursors 193\u003c\/p\u003e \u003cp\u003e5.3.6 Polymers with Pendent Aldehyde Groups 194\u003c\/p\u003e \u003cp\u003e5.4 Summary 195\u003c\/p\u003e \u003cp\u003eList of Abbreviations 195\u003c\/p\u003e \u003cp\u003eReferences 198\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Natural Crosslinkers for Naturally-Based Adhesives 207\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eManfred Dunky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 207\u003c\/p\u003e \u003cp\u003e6.2 Crosslinking Reactions 208\u003c\/p\u003e \u003cp\u003e6.2.1 Proteins 208\u003c\/p\u003e \u003cp\u003e6.2.2 Tannins 211\u003c\/p\u003e \u003cp\u003e6.2.3 Carbohydrates 214\u003c\/p\u003e \u003cp\u003e6.2.4 Lignins 217\u003c\/p\u003e \u003cp\u003e6.3 Aliphatic Aldehydes as Crosslinkers 219\u003c\/p\u003e \u003cp\u003e6.3.1 Formaldehyde 219\u003c\/p\u003e \u003cp\u003e6.3.2 Higher Aldehydes 221\u003c\/p\u003e \u003cp\u003e6.3.3 Glyoxal 221\u003c\/p\u003e \u003cp\u003e6.3.4 Glutaraldehyde 223\u003c\/p\u003e \u003cp\u003e6.3.5 Higher Aliphatic Aldehydes 226\u003c\/p\u003e \u003cp\u003e6.4 Cyclic and Aromatic Aldehydes as Crosslinkers 226\u003c\/p\u003e \u003cp\u003e6.4.1 Furfural 226\u003c\/p\u003e \u003cp\u003e6.4.2 5-Hydroxymethylfurfural (5-HMF) 228\u003c\/p\u003e \u003cp\u003e6.4.3 Non-Volatile Aldehydes from Carbohydrates 230\u003c\/p\u003e \u003cp\u003e6.5 Crosslinkers Prepared from Biomass 231\u003c\/p\u003e \u003cp\u003e6.5.1 Furfuryl Alcohol 231\u003c\/p\u003e \u003cp\u003e6.5.2 Extracts as Crosslinkers 234\u003c\/p\u003e \u003cp\u003e6.5.3 Glycerol Diglycidyl Ether (GDE), Glycerol Polyglycidyl Ether (GPE), and Ethylene Glycol Diglycidyl Ether (EGDE) 234\u003c\/p\u003e \u003cp\u003e6.5.4 Triglycidylamine (TGA) 236\u003c\/p\u003e \u003cp\u003e6.5.5 Diethylene-Triamine (DETA) 237\u003c\/p\u003e \u003cp\u003e6.5.6 Citric Acid 237\u003c\/p\u003e \u003cp\u003e6.6 Synthetic Crosslinkers 240\u003c\/p\u003e \u003cp\u003e6.6.1 Polyamidoamine–Epichlorohydrin (PAE) Resins 240\u003c\/p\u003e \u003cp\u003e6.6.2 Epoxy Resins 241\u003c\/p\u003e \u003cp\u003e6.6.3 Polyethylenimine (PEI) 242\u003c\/p\u003e \u003cp\u003e6.6.4 Polyamidoamine (PADA) 243\u003c\/p\u003e \u003cp\u003eList of Abbreviations 243\u003c\/p\u003e \u003cp\u003eReferences 245\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Curing and Adhesive Bond Strength Development in Naturally-Based Adhesives 255\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eMilan Šernek and Jure Žigon\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 255\u003c\/p\u003e \u003cp\u003e7.2 Curing Monitoring Techniques 256\u003c\/p\u003e \u003cp\u003e7.2.1 Gel Time Test 256\u003c\/p\u003e \u003cp\u003e7.2.2 Differential Scanning Calorimetry (DSC) 257\u003c\/p\u003e \u003cp\u003e7.2.3 Thermogravimetric Analysis (TGA) 258\u003c\/p\u003e \u003cp\u003e7.2.4 Dielectric Analysis (DEA) 259\u003c\/p\u003e \u003cp\u003e7.3 Bond Strength Development Monitoring Techniques 260\u003c\/p\u003e \u003cp\u003e7.3.1 Dynamic Mechanical Analysis (DMA) 260\u003c\/p\u003e \u003cp\u003e7.3.2 Thermomechanical Analysis (TMA) 261\u003c\/p\u003e \u003cp\u003e7.3.3 Automated Bonding Evaluation System (ABES) 262\u003c\/p\u003e \u003cp\u003e7.3.4 Tensile-Shear Strength 263\u003c\/p\u003e \u003cp\u003e7.4 Curing Mechanisms in Naturally-Based Adhesives 263\u003c\/p\u003e \u003cp\u003e7.4.1 Tannin-Based Adhesives 263\u003c\/p\u003e \u003cp\u003e7.4.2 Lignin-Based Adhesives 265\u003c\/p\u003e \u003cp\u003e7.4.3 Soy-Based Adhesives 267\u003c\/p\u003e \u003cp\u003e7.4.4 Sucrose-Based Adhesives 269\u003c\/p\u003e \u003cp\u003e7.4.5 Starch-Based Adhesives 270\u003c\/p\u003e \u003cp\u003e7.4.6 Liquefied Wood (LW)-Based Adhesives 271\u003c\/p\u003e \u003cp\u003e7.5 Summary 272\u003c\/p\u003e \u003cp\u003eAcknowledgements 273\u003c\/p\u003e \u003cp\u003eList of Abbreviations 273\u003c\/p\u003e \u003cp\u003eReferences 274\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Mimicking Nature: Bio-Inspired Adhesives 279\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eManfred Dunky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 279\u003c\/p\u003e \u003cp\u003e8.2 Improvement of Adhesive Performance 282\u003c\/p\u003e \u003cp\u003e8.3 Underwater Adhesives (Wet Application Adhesives) 286\u003c\/p\u003e \u003cp\u003e8.4 Detechable Bonding and Self-Healing Polymers 289\u003c\/p\u003e \u003cp\u003e8.5 Medical Applications 292\u003c\/p\u003e \u003cp\u003e8.6 Summary 294\u003c\/p\u003e \u003cp\u003eList of Abbreviations 294\u003c\/p\u003e \u003cp\u003eReferences 295\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart 2: Classes of Biobased Adhesives 305\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Protein Adhesives – Composition, Structure and Performance 307\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eCharles R. Frihart\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 307\u003c\/p\u003e \u003cp\u003e9.2 Composition of Proteins 308\u003c\/p\u003e \u003cp\u003e9.3 Types, Sources, Processing, and Properties of Proteins 309\u003c\/p\u003e \u003cp\u003e9.3.1 Collagen (Animal) 309\u003c\/p\u003e \u003cp\u003e9.3.2 Globular (Plant) 311\u003c\/p\u003e \u003cp\u003e9.3.3 Globular (Milk) 315\u003c\/p\u003e \u003cp\u003e9.3.4 Globular (Egg) 316\u003c\/p\u003e \u003cp\u003e9.3.5 Globular (Blood) 317\u003c\/p\u003e \u003cp\u003e9.3.6 Other Protein Sources 317\u003c\/p\u003e \u003cp\u003e9.4 Conclusion (Future of Protein Adhesives) and Summary 317\u003c\/p\u003e \u003cp\u003eList of Abbreviations 318\u003c\/p\u003e \u003cp\u003eReferences 319\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Carbohydrates (Polysaccharides) as Adhesives 325\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eLee Seng Hua and Lum Wei Chen\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 325\u003c\/p\u003e \u003cp\u003e10.2 Cellulose Derivatives 326\u003c\/p\u003e \u003cp\u003e10.3 Starch-Based Adhesives 330\u003c\/p\u003e \u003cp\u003e10.4 Dextrin 331\u003c\/p\u003e \u003cp\u003e10.5 Natural Gums 333\u003c\/p\u003e \u003cp\u003e10.6 Chitosan 335\u003c\/p\u003e \u003cp\u003e10.7 Summary and Prospects 339\u003c\/p\u003e \u003cp\u003eAcknowledgements 340\u003c\/p\u003e \u003cp\u003eList of Abbreviations 340\u003c\/p\u003e \u003cp\u003eReferences 341\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Natural Polymer-Based Adhesives 345\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eA.A. Shybi, Siby Varghese, Hanna J. Maria and Sabu Thomas\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 345\u003c\/p\u003e \u003cp\u003e11.2 Natural Rubber (NR)-Based Adhesives 346\u003c\/p\u003e \u003cp\u003e11.2.1 Introduction to NR-Based Adhesives 346\u003c\/p\u003e \u003cp\u003e11.2.2 NR-Based Wood Adhesives 350\u003c\/p\u003e \u003cp\u003e11.2.3 NR-Based Pressure-Sensitive Adhesives 352\u003c\/p\u003e \u003cp\u003e11.2.4 NR-Based Adhesives in Leather, Rubber, Textile and Metal Bonding Applications 353\u003c\/p\u003e \u003cp\u003e11.3 Poly(lactic acid) (PLA)-Based Wood Adhesives 354\u003c\/p\u003e \u003cp\u003e11.3.1 Introduction to PLA-Based Adhesives 354\u003c\/p\u003e \u003cp\u003e11.3.2 PLA-Based Wood Adhesives 355\u003c\/p\u003e \u003cp\u003e11.3.3 PLA-Based Hot-Melt Adhesives 356\u003c\/p\u003e \u003cp\u003e11.3.4 PLA-Based Adhesives for Metal Bonding 357\u003c\/p\u003e \u003cp\u003e11.4 Chitosan-Based Adhesives 357\u003c\/p\u003e \u003cp\u003e11.4.1 Introduction to Chitosan-Based Adhesives 357\u003c\/p\u003e \u003cp\u003e11.4.2 Chitosan-Based Wood Adhesives 358\u003c\/p\u003e \u003cp\u003e11.5 Summary 359\u003c\/p\u003e \u003cp\u003eList of Abbreviations 360\u003c\/p\u003e \u003cp\u003eReferences 361\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Epoxy Adhesives from Natural Materials 367\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eCharles R. Frihart\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction and Morphology 367\u003c\/p\u003e \u003cp\u003e12.2 Basic Properties of Epoxies 369\u003c\/p\u003e \u003cp\u003e12.3 Epoxy Synthesis 370\u003c\/p\u003e \u003cp\u003e12.4 Epoxy Curing 373\u003c\/p\u003e \u003cp\u003e12.4.1 One-Component Epoxies 375\u003c\/p\u003e \u003cp\u003e12.4.2 Two-Component Epoxies 376\u003c\/p\u003e \u003cp\u003e12.5 Aromatic Epoxies 376\u003c\/p\u003e \u003cp\u003e12.5.1 Aromatic Bis-Phenol Epoxies 376\u003c\/p\u003e \u003cp\u003e12.5.2 Aromatic Novolac Epoxies 377\u003c\/p\u003e \u003cp\u003e12.5.3 Biobased Aromatic Epoxies from Polyphenols, Tannins, Cardanol, and Lignin 378\u003c\/p\u003e \u003cp\u003e12.5.4 Aromatic Epoxies from Lignin and Woody Biomass 378\u003c\/p\u003e \u003cp\u003e12.6 Aliphatic Epoxies 379\u003c\/p\u003e \u003cp\u003e12.6.1 Aliphatic Epoxies from Vegetable Oils 380\u003c\/p\u003e \u003cp\u003e12.6.2 Aliphatic Epoxies from Sugars 381\u003c\/p\u003e \u003cp\u003e12.6.3 Aliphatic Epoxies from Terpenoids 382\u003c\/p\u003e \u003cp\u003e12.6.4 Other Aliphatic Epoxies 382\u003c\/p\u003e \u003cp\u003e12.7 Hardeners 383\u003c\/p\u003e \u003cp\u003e12.7.1 Amines 383\u003c\/p\u003e \u003cp\u003e12.7.1.1 Aliphatic Amines 383\u003c\/p\u003e \u003cp\u003e12.7.1.2 Biobased Aliphatic Amines 384\u003c\/p\u003e \u003cp\u003e12.7.1.3 Aromatic Amines 385\u003c\/p\u003e \u003cp\u003e12.7.2 Anhydrides of Organic Acids 386\u003c\/p\u003e \u003cp\u003e12.8 Other Curing Mechanisms 386\u003c\/p\u003e \u003cp\u003e12.9 Other Additives 386\u003c\/p\u003e \u003cp\u003e12.9.1 Tougheners 386\u003c\/p\u003e \u003cp\u003e12.9.2 Modifiers 387\u003c\/p\u003e \u003cp\u003e12.10 Status of Biobased Epoxy Adhesives 387\u003c\/p\u003e \u003cp\u003e12.11 Summary 388\u003c\/p\u003e \u003cp\u003eList of Abbreviations 389\u003c\/p\u003e \u003cp\u003eReferences 389\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Naturally-Based Polyurethane Bioadhesives 395\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eA. Pizzi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 395\u003c\/p\u003e \u003cp\u003e13.2 Biopolyols-Isocyanate Polyurethanes 396\u003c\/p\u003e \u003cp\u003e13.3 Non-Isocyanate Polyurethanes (NIPUs) 399\u003c\/p\u003e \u003cp\u003e13.4 NIPUs as Adhesives 402\u003c\/p\u003e \u003cp\u003e13.5 Summary 408\u003c\/p\u003e \u003cp\u003eReferences 408\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Nanocellulose-Modified Wood Adhesives 415\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eStefan Veigel, Stefan Pinkl and Wolfgang Gindl-Altmutter\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction 415\u003c\/p\u003e \u003cp\u003e14.2 Nanocellulose as Additive for Conventional and Biobased Wood Adhesives 416\u003c\/p\u003e \u003cp\u003e14.3 Nanocellulose-Derived Wood Adhesives 420\u003c\/p\u003e \u003cp\u003e14.4 Prospects 421\u003c\/p\u003e \u003cp\u003e14.5 Summary 421\u003c\/p\u003e \u003cp\u003eNote 422\u003c\/p\u003e \u003cp\u003eList of Abbreviations 422\u003c\/p\u003e \u003cp\u003eReferences 423\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Debondable, Recyclable and\/or Biodegradable Naturally-Based Adhesives 427\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eNatanel Jarach and Hanna Dodiuk\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 Introduction 427\u003c\/p\u003e \u003cp\u003e15.2 Debondable Adhesives 428\u003c\/p\u003e \u003cp\u003e15.2.1 Types of Debonding Adhesives 428\u003c\/p\u003e \u003cp\u003e15.2.2 Reversible Covalent Bonds Containing Adhesives 429\u003c\/p\u003e \u003cp\u003e15.3 Biobased Debondable and Recyclable Adhesives 431\u003c\/p\u003e \u003cp\u003e15.3.1 Biodegradable Adhesives 431\u003c\/p\u003e \u003cp\u003e15.3.2 Biobased Reversible Covalent Bonds Containing Adhesives 438\u003c\/p\u003e \u003cp\u003e15.4 Summary 453\u003c\/p\u003e \u003cp\u003eList of Abbreviations 453\u003c\/p\u003e \u003cp\u003eReferences 454\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Fungal Mycelia as Bioadhesives 463\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eWenjing Sun, Mehdi Tajvidi and Christopher G. Hunt\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e16.1 Introduction 463\u003c\/p\u003e \u003cp\u003e16.2 Basics of Fungal Mycelia 464\u003c\/p\u003e \u003cp\u003e16.2.1 Fungal Species 464\u003c\/p\u003e \u003cp\u003e16.2.2 Fungal Cell Wall 464\u003c\/p\u003e \u003cp\u003e16.2.3 Effects of Fungal Mycelia on Lignocellulosic Substrates 465\u003c\/p\u003e \u003cp\u003e16.3 Production Procedure 465\u003c\/p\u003e \u003cp\u003e16.4 Adhesive Performance 467\u003c\/p\u003e \u003cp\u003e16.4.1 As-Grown Foams 467\u003c\/p\u003e \u003cp\u003e16.4.2 Hot-Pressed Panels 470\u003c\/p\u003e \u003cp\u003e16.4.3 Engineered Living Materials 470\u003c\/p\u003e \u003cp\u003e16.5 Improvement Strategies 470\u003c\/p\u003e \u003cp\u003e16.5.1 Incorporating Natural Fibers 471\u003c\/p\u003e \u003cp\u003e16.5.2 Infusing Bio-Resin 471\u003c\/p\u003e \u003cp\u003e16.5.3 Incorporating Natural Reinforcement Particles 471\u003c\/p\u003e \u003cp\u003e16.6 Prospects 471\u003c\/p\u003e \u003cp\u003e16.7 Summary 471\u003c\/p\u003e \u003cp\u003eAcknowledgements 472\u003c\/p\u003e \u003cp\u003eList of Abbreviations 472\u003c\/p\u003e \u003cp\u003eReferences 472\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 5-Hydroxymethylfurfural-Based Adhesives: Challenges and Opportunities 477\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eWilfried Sailer-Kronlachner, Catherine Rosenfeld, Johannes Konnerth and Hendrikus van Herwijnen\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e17.1 Introduction 477\u003c\/p\u003e \u003cp\u003e17.2 5-Hydroxymethylfurfural as Biobased Platform Chemical 479\u003c\/p\u003e \u003cp\u003e17.2.1 Potential as Chemical Building Block 479\u003c\/p\u003e \u003cp\u003e17.2.2 Challenges in the Implementation of an Industrial 5-HMF Production 480\u003c\/p\u003e \u003cp\u003e17.3 5-HMF-Based Adhesive Systems 483\u003c\/p\u003e \u003cp\u003e17.3.1 Wood Adhesives 484\u003c\/p\u003e \u003cp\u003e17.3.2 Non-Wood Applications of 5-HMF-Based Adhesives 487\u003c\/p\u003e \u003cp\u003e17.3.3 Examples of Adhesives Produced from 5-HMF Derivatives 488\u003c\/p\u003e \u003cp\u003e17.4 Prospects 490\u003c\/p\u003e \u003cp\u003e17.5 Summary 491\u003c\/p\u003e \u003cp\u003eAcknowledgements 491\u003c\/p\u003e \u003cp\u003eList of Abbreviations 492\u003c\/p\u003e \u003cp\u003eReferences 492\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 Adhesive Precursors from Tree-Derived Naval Stores 499\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eCharles R. Frihart\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e18.1 Introduction 499\u003c\/p\u003e \u003cp\u003e18.2 Sources and Structures 500\u003c\/p\u003e \u003cp\u003e18.2.1 Rosins 500\u003c\/p\u003e \u003cp\u003e18.2.2 Fatty Acids 502\u003c\/p\u003e \u003cp\u003e18.2.3 Terpenes 503\u003c\/p\u003e \u003cp\u003e18.3 Pressure-Sensitive Adhesives 503\u003c\/p\u003e \u003cp\u003e18.4 Chemistry and Products 505\u003c\/p\u003e \u003cp\u003e18.4.1 Rosins 505\u003c\/p\u003e \u003cp\u003e18.4.2 Modification of the Carboxylic Acid 506\u003c\/p\u003e \u003cp\u003e18.4.3 Modification of the Olefinic Portion 508\u003c\/p\u003e \u003cp\u003e18.4.4 Ink Pigment Binders 509\u003c\/p\u003e \u003cp\u003e18.4.5 Tall Oil Fatty Acids 510\u003c\/p\u003e \u003cp\u003e18.4.6 Terpenes 512\u003c\/p\u003e \u003cp\u003e18.5 Summary 513\u003c\/p\u003e \u003cp\u003eList of Abbreviations 513\u003c\/p\u003e \u003cp\u003eReferences 513\u003c\/p\u003e \u003cp\u003e\u003cb\u003ePart 3: Applications of Biobased Adhesives 517\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003e19 Naturally-Based Adhesives for Wood and Wood-Based Panels 519\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eManfred Dunky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e19.1 Introduction 519\u003c\/p\u003e \u003cp\u003e19.2 Protein-Based Wood Adhesives 521\u003c\/p\u003e \u003cp\u003e19.2.1 Wood Bonding with Proteins 522\u003c\/p\u003e \u003cp\u003e19.2.2 Plant-Based Proteins (for Soy Proteins see Section 19.2.3) 524\u003c\/p\u003e \u003cp\u003e19.2.3 Soy Proteins 525\u003c\/p\u003e \u003cp\u003e19.2.4 Animal-Based Proteins 528\u003c\/p\u003e \u003cp\u003e19.2.5 Denaturation and Modification of Proteins 531\u003c\/p\u003e \u003cp\u003e19.2.6 Crosslinking of Proteins 534\u003c\/p\u003e \u003cp\u003e19.3 Wood Adhesives Based on Carbohydrates 535\u003c\/p\u003e \u003cp\u003e19.3.1 Types and Sources of Carbohydrates for Use as Wood Adhesives 535\u003c\/p\u003e \u003cp\u003e19.3.2 Modification of Starch for Possible Use as Wood Adhesive 537\u003c\/p\u003e \u003cp\u003e19.3.3 Combination and Crosslinking of Carbohydrates with Natural and Synthetic Components 539\u003c\/p\u003e \u003cp\u003e19.3.4 Degradation and Repolymerization of Carbohydrates 539\u003c\/p\u003e \u003cp\u003e19.4 Tannin-Based Wood Adhesives 539\u003c\/p\u003e \u003cp\u003e19.4.1 Types and Chemistry of Condensed Tannins 540\u003c\/p\u003e \u003cp\u003e19.4.2 Hardening and Crosslinking of Tannins 542\u003c\/p\u003e \u003cp\u003e19.4.3 Combination of Tannins with Other Components 546\u003c\/p\u003e \u003cp\u003e19.5 Wood Adhesives Based on Lignin 547\u003c\/p\u003e \u003cp\u003e19.5.1 Chemistry and Structure of Lignin 547\u003c\/p\u003e \u003cp\u003e19.5.2 Modification of Lignin 548\u003c\/p\u003e \u003cp\u003e19.5.3 Lignin as Adhesive 552\u003c\/p\u003e \u003cp\u003e19.5.4 Lignin as Sole Adhesive 554\u003c\/p\u003e \u003cp\u003e19.5.5 Reactions of Lignin with Various Aldehydes and Other Naturally-Based Components 557\u003c\/p\u003e \u003cp\u003e19.6 Summary 558\u003c\/p\u003e \u003cp\u003eList of Abbreviations 558\u003c\/p\u003e \u003cp\u003eReferences 559\u003c\/p\u003e \u003cp\u003e\u003cb\u003e20 Activation of Wood Surfaces and “Binderless” Wood Composites 579\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eManfred Dunky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e20.1 Introduction 579\u003c\/p\u003e \u003cp\u003e20.2 Self-Adhesion and “Binderless” Boards 584\u003c\/p\u003e \u003cp\u003e20.2.1 Wood and Non-Wood Components for “Binderless” Boards 586\u003c\/p\u003e \u003cp\u003e20.2.2 Thermal and Physical Pretreatments of Wood Material and the Wood Surface 589\u003c\/p\u003e \u003cp\u003e20.2.3 Chemical Treatments of the Wood Surface 591\u003c\/p\u003e \u003cp\u003e20.2.4 Enzymatic Pretreatment of the Wood Surface 595\u003c\/p\u003e \u003cp\u003e20.2.5 Degradation and Re-Polymerization of Carbohydrates 598\u003c\/p\u003e \u003cp\u003e20.2.6 Citric Acid 601\u003c\/p\u003e \u003cp\u003e20.2.6.1 Sugars and Starch in Combination with Citric Acid 601\u003c\/p\u003e \u003cp\u003e20.2.6.2 Wood in Combination with Citric Acid 602\u003c\/p\u003e \u003cp\u003e20.2.7 Hardboards (Wet Fiber Process) 605\u003c\/p\u003e \u003cp\u003e20.2.8 Wood Welding 607\u003c\/p\u003e \u003cp\u003e20.3 Summary 611\u003c\/p\u003e \u003cp\u003eList of Abbreviations 611\u003c\/p\u003e \u003cp\u003eReferences 612\u003c\/p\u003e \u003cp\u003e\u003cb\u003e21 Bonding of Solid Wood-Based Materials for Timber Construction 621\u003cbr\u003e \u003c\/b\u003e\u003ci\u003ePeter Niemz and Manfred Dunky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e21.1 Introduction 621\u003c\/p\u003e \u003cp\u003e21.2 Brief Overview of Solid Wood-Based Materials 622\u003c\/p\u003e \u003cp\u003e21.3 Adhesives Used for Materials in Structural Timber Engineering 625\u003c\/p\u003e \u003cp\u003e21.3.1 Adhesives for the Production of Glued-Laminated Timber (Surface Bonding) 625\u003c\/p\u003e \u003cp\u003e21.3.2 Casein Adhesives 628\u003c\/p\u003e \u003cp\u003e21.4 Factors Influencing the Quality of Adhesively-Bonded Wood 631\u003c\/p\u003e \u003cp\u003e21.4.1 Short Overview 631\u003c\/p\u003e \u003cp\u003e21.4.2 Influence of the Wood Substrate (Structure and Wood Species) 631\u003c\/p\u003e \u003cp\u003e21.4.3 Influence of Adhesives 636\u003c\/p\u003e \u003cp\u003e21.4.4 Influence of Wood Machining 643\u003c\/p\u003e \u003cp\u003e21.4.5 Quality Control of Bonded Wood Joints 644\u003c\/p\u003e \u003cp\u003e21.4.6 Influence of Service Conditions 644\u003c\/p\u003e \u003cp\u003e21.4.7 Aging of Bonded Wood 646\u003c\/p\u003e \u003cp\u003e21.5 Trends in the Use of Biobased Adhesives 649\u003c\/p\u003e \u003cp\u003e21.6 Summary 650\u003c\/p\u003e \u003cp\u003eList of Abbreviations 651\u003c\/p\u003e \u003cp\u003eReferences 652\u003c\/p\u003e \u003cp\u003e\u003cb\u003e22 Applications and Industrial Implementations of Naturally-Based Adhesives 659\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eManfred Dunky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e22.1 Introduction 659\u003c\/p\u003e \u003cp\u003e22.2 Wood-Based Panels 660\u003c\/p\u003e \u003cp\u003e22.3 Shoe Fabrication (Footwear Industry) 664\u003c\/p\u003e \u003cp\u003e22.4 Bonding of Metals 666\u003c\/p\u003e \u003cp\u003e22.5 Composites in Automotive, Aircraft, and Aeronautical Industries 667\u003c\/p\u003e \u003cp\u003e22.6 Natural Composites with Matrices Based on Natural Resources 673\u003c\/p\u003e \u003cp\u003e22.7 Mineral Wool 679\u003c\/p\u003e \u003cp\u003e22.8 Packaging and Other Applications 679\u003c\/p\u003e \u003cp\u003e22.9 Biomedical Applications 680\u003c\/p\u003e \u003cp\u003e22.10 Biodegradability and Recycling 681\u003c\/p\u003e \u003cp\u003e22.11 Life Cycle Analysis (LCA) 683\u003c\/p\u003e \u003cp\u003e22.12 Summary 686\u003c\/p\u003e \u003cp\u003eList of Abbreviations 686\u003c\/p\u003e \u003cp\u003eReferences 688\u003c\/p\u003e \u003cp\u003e\u003cb\u003e23 Bioadhesives for the Advancement of Controlled Drug Delivery and Wearable Bioelectronics 705\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eMonalisha Ghosh Dastidar, Sharmili Roy and Sudarsan Neogi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e23.1 Introduction 705\u003c\/p\u003e \u003cp\u003e23.1.1 History of Bioadhesives and their Evolution 706\u003c\/p\u003e \u003cp\u003e23.1.2 Classification of Bioadhesives 706\u003c\/p\u003e \u003cp\u003e23.1.2.1 Natural Bioadhesives 707\u003c\/p\u003e \u003cp\u003e23.1.2.2 Biological and Biocompatible Bioadhesives 707\u003c\/p\u003e \u003cp\u003e23.1.2.3 Biomimetic and Bioinspired Bioadhesives 707\u003c\/p\u003e \u003cp\u003e23.1.3 Mechanism of Bioadhesives 708\u003c\/p\u003e \u003cp\u003e23.2 Bioadhesives in Controlled Drug Delivery 708\u003c\/p\u003e \u003cp\u003e23.3 Bioadhesives in Bioelectronics 710\u003c\/p\u003e \u003cp\u003e23.4 Limitations of Bioadhesives for Biomedical Applications 717\u003c\/p\u003e \u003cp\u003e23.5 Summary and Future Prospects 718\u003c\/p\u003e \u003cp\u003eList of Abbreviations 719\u003c\/p\u003e \u003cp\u003eReferences 720\u003c\/p\u003e \u003cp\u003eIndex 727\u003c\/p\u003e","brand":"John Wiley \u0026 Sons Inc","offers":[{"title":"Default Title","offer_id":49083884831063,"sku":"9781394174638","price":170.1,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781394174638.jpg?v=1725550322","url":"https:\/\/bookcurl.com\/products\/biobased-adhesives-9781394174638","provider":"Book Curl","version":"1.0","type":"link"}