{"product_id":"applied-homogeneous-catalysis-9783527326334","title":"Applied Homogeneous Catalysis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eAdopting a didactic approach at an advanced, masters level, this concise textbook provides an array of questions \u0026amp; answers and features numerous industrial case studies and examples, with references for further, more detailed reading and to the latest peer-reviewed articles at the end of each chapter. A significant feature is the book's treatment of more recently developed catalytic processes and their applications in the pharmaceutical and fine chemical industries, with an indication of their present and future commercial impact. \u003cbr\u003eWritten by a dedicated lecturer with a wealth of experience in industry, this is an invaluable tool for practicing chemical engineers and chemists who need to advance their education in this vibrant and expanding field.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e“High recommended and excellent value in the paperback format.” (\u003ci\u003eOrganic Process Research and Development Journal\u003c\/i\u003e, 2012)\u003c\/p\u003e \u003cp\u003e \u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eFOREWORD \u003cbr\u003e PREFACE \u003cbr\u003e PART I CHEMICAL BASICS \u003cbr\u003e DEFINITION, OPTIONS, AND EXAMPLES: WHAT ACTUALLY IS CATALYSIS? \u003cbr\u003e Definition of Catalysis \u003cbr\u003e The Different Varieties of Catalysis\u003cbr\u003e The Directing Effect of the Catalyst \u003cbr\u003e Catalysis as a Part of \"Green Chemistry\"\u003cbr\u003e Sources of Information about Catalysis \u003cbr\u003e \u003cbr\u003e A BRIEF HISTORY: HOMOGENEOUS TRANSITION METAL CATALYSIS: A YOUNG SCIENCE \u003cbr\u003e A Brief History \u003cbr\u003e \u003cbr\u003e INDUSTRIAL HOMOGENEOUS CATALYSIS: WHAT IS THE ECONOMIC IMPORTANCE? \u003cbr\u003e Application Areas of Catalysis \u003cbr\u003e Important Homogeneous Catalyzed Processes \u003cbr\u003e Synthesis of Fine Chemicals by Homogeneous Catalysis \u003cbr\u003e \u003cbr\u003e DEFINITIONS OF IMPORTANT TERMS: SELECTIVITY, STY, TON, TOF, AND MORE. . . \u003cbr\u003e Conversion \u003cbr\u003e Yield \u003cbr\u003e Selectivity \u003cbr\u003e Other Important Target Values \u003cbr\u003e The Choice is Yours! \u003cbr\u003e \u003cbr\u003e BONDS, ELEMENTAL STEPS, AND CATALYST CYCLES: BASICS OF ORGANOMETALLIC CHEMISTRY \u003cbr\u003e Ligands \u003cbr\u003e Change in Oxidation State \u003cbr\u003e Changing of Coordination Number (CN) and Coordination Geometry \u003cbr\u003e The Elementary Steps \u003cbr\u003e Catalytic Cycles \u003cbr\u003e \u003cbr\u003e TRANSITION METAL COMPLEXES: THE \"CAPTAINS\" OF HOMOGENEOUS CATALYSIS \u003cbr\u003e Group IIIB Metals and Lanthanides \u003cbr\u003e Metals of Group IVB \u003cbr\u003e Metals of Groups VB to VIIB \u003cbr\u003e The \"Iron Metals\" of Group VIII \u003cbr\u003e The Noble Metals from Group VIII \u003cbr\u003e Gold: A Noble Metal from Group IB \u003cbr\u003e The Cost of Catalyst Metals \u003cbr\u003e The Availability of Transition Metal Catalysts \u003cbr\u003e A Typical Experiment: Synthesis of Pd(acac)2 \u003cbr\u003e \u003cbr\u003e THE COMPLEX LIGANDS: THE \"MATES\" OF HOMOGENEOUS CATALYSIS \u003cbr\u003e Monodentate Ligand or Chelate? \u003cbr\u003e Basicity of Ligands \u003cbr\u003e Cone Angle (\"Tolman Cone Angle\") \u003cbr\u003e The Bite Angle \u003cbr\u003e Costs and Accessibility of Ligands \u003cbr\u003e A Typical Experiment: The Synthesis of Biphephos \u003cbr\u003e Stability of Ligands \u003cbr\u003e \u003cbr\u003e THE SOLVENTS: THE REACTION MEDIUM \u003cbr\u003e Criteria for Choosing Solvents \u003cbr\u003e Miscibility of Solvents \u003cbr\u003e Solvents as Activators \u003cbr\u003e Solvents as Deactivators \u003cbr\u003e Availability and Purity of Solvents \u003cbr\u003e Special Solvents \u003cbr\u003e \u003cbr\u003e ASYMMETRIC CATALYSIS: THE \"SPECIAL CASE\"\u003cbr\u003e A Glossary of Asymmetric Catalysis \u003cbr\u003e A Quick Look Back \u003cbr\u003e Mechanistic Considerations \u003cbr\u003e Chiral Ligands \u003cbr\u003e Overview on Homogeneous Catalyzed Asymmetric Syntheses \u003cbr\u003e Industrial Applications \u003cbr\u003e \u003cbr\u003e THERMODYNAMICS OF HOMOGENEOUS CATALYSIS: WHEN DOES A CHEMICAL REACTION RUN? \u003cbr\u003e Gibbs Energy and Energy Plot \u003cbr\u003e Calculation or Assessment of the Free Reaction Enthalpy \u003cbr\u003e Thermodynamic Analysis of Complex Reaction Systems \u003cbr\u003e \u003cbr\u003e KINETICS OF HOMOGENEOUS CATALYSIS: HOW DOES THE REACTION PROCEED? \u003cbr\u003e Frequently Occurring Kinetics \u003cbr\u003e The Energy Diagram for Explaining Regioselectivity \u003cbr\u003e The Energy Diagram for Explaining Enantioselectivity \u003cbr\u003e Execution of Kinetic Measurements \u003cbr\u003e A Concrete Example: The (Isomerizing) Hydroformylation of Octenes \u003cbr\u003e Possible Failures in Kinetic Measurements \u003cbr\u003e \u003cbr\u003e OVERVIEW ON SPECTROSCOPIC METHODS: CAN WE SEE INTO HOMOGENEOUS CATALYSIS? \u003cbr\u003e UV\/Visible Spectroscopy \u003cbr\u003e IR Spectroscopy \u003cbr\u003e NMR Spectroscopy \u003cbr\u003e Mass Spectroscopy \u003cbr\u003e Extended X-Ray Absorption Fine Structure Analysis \u003cbr\u003e Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) \u003cbr\u003e \u003cbr\u003e PART II PROCESS ENGINEERING FUNDAMENTALS \u003cbr\u003e REACTOR TYPES: WHERE DOES CATALYSIS OCCUR? \u003cbr\u003e Reactions in Homogeneous Liquid Phase \u003cbr\u003e Fluid-Fluid Systems \u003cbr\u003e The \"Embarras de Richesses\"\u003cbr\u003e Pressure Reactors \u003cbr\u003e New Trends \u003cbr\u003e \u003cbr\u003e OVERVIEW ON CATALYST RECYCLING METHODS: IS MY CATALYST ECONOMICAL? \u003cbr\u003e The Principles of Separation \u003cbr\u003e Precipitation \u003cbr\u003e Crystallization \u003cbr\u003e Adsorption \u003cbr\u003e \u003cbr\u003e THERMAL SEPARATION: THE SIMPLEST REMOVAL OF VOLATILE PRODUCTS \u003cbr\u003e The Basics \u003cbr\u003e Example: Hydroformylation \u003cbr\u003e Example: Oxidation of Ethene to Acetaldehyde \u003cbr\u003e Example: Carbonylation of Methanol to Acetic Acid \u003cbr\u003e \u003cbr\u003e IMMOBILIZATION ON SOLID SUPPORTS: FROM HOMOGENEOUS TO HETEROGENEOUS \u003cbr\u003e The Basic Principle \u003cbr\u003e Organic Supports \u003cbr\u003e Inorganic Supports \u003cbr\u003e \u003cbr\u003e LIQUID-LIQUID MULTIPHASE SYSTEMS: THE SMART APPROACH TO CATALYST SEPARATION \u003cbr\u003e Variants of Liquid?Liquid Biphasic (LLB) Systems \u003cbr\u003e Reaction and Separation\u003cbr\u003e Reactions with In-Situ Extraction \u003cbr\u003e Reactions with Post Extraction \u003cbr\u003e \u003cbr\u003e THERMOMORPHIC SOLVENT SYSTEMS: CLEVER ENHANCEMENTS \u003cbr\u003e Thermoregulated Phase-Transfer Catalysis \u003cbr\u003e Thermoregulated Microemulsions \u003cbr\u003e  Thermoregulated Fluorous Solvent Systems \u003cbr\u003e Thermoregulated Polymer-Bound Catalysts \u003cbr\u003e Thermomorphic Multicomponent Solvent Systems \u003cbr\u003e A Retrospective Look at Catalyst Recycling Methods \u003cbr\u003e \u003cbr\u003e PART III HOMOGENEOUS CATALYZED REACTION TYPES \u003cbr\u003e AN OVERVIEW OF C?C-BONDING REACTIONS: A GUIDE THROUGH THE JUNGLE \u003cbr\u003e \u003cbr\u003e HYDROFORMYLATIONS: THE INDUSTRIAL ROUTE TO ALDEHYDES AND ALCOHOLS \u003cbr\u003e Substrates \u003cbr\u003e Catalysts \u003cbr\u003e Mechanisms \u003cbr\u003e Industrial Processes\u003cbr\u003e Asymmetric Hydroformylation \u003cbr\u003e A Typical Experiment: Hydroformylation of 1-Octene \u003cbr\u003e \u003cbr\u003e CARBONYLATIONS: THE VERSATILE INSERTIONS OF CARBON MONOXIDE \u003cbr\u003e Reactions between CO and Hydrogen \u003cbr\u003e Reactions of CO with Alkenes and Vinyl Arenes \u003cbr\u003e Reactions of CO with Dienes \u003cbr\u003e Reactions of CO with Alkynes \u003cbr\u003e Reactions of CO with Alcohols \u003cbr\u003e A Typical Experiment \u003cbr\u003e \u003cbr\u003e OLIGOMERIZATION AND CYCLOOLIGOMERIZATION: THE CONVERSION OF UNSATURATED ALIPHATICS INTO SHORT CHAINS OR MEDIUM-SIZED RINGS \u003cbr\u003e Oligomerization of Alkenes \u003cbr\u003e Dienes \u003cbr\u003e Alkynes \u003cbr\u003e Cooligomerizations \u003cbr\u003e A Typical Experiment \u003cbr\u003e \u003cbr\u003e METATHESIS: A \"CHANGE-YOUR-PARTNERS\" DANCE \u003cbr\u003e Mechanism and Catalysts \u003cbr\u003e Industrial Applications \u003cbr\u003e A Typical Experiment: Self Metathesis of 1-Octene\u003cbr\u003e \u003cbr\u003e POLYMERIZATIONS: THE PURPOSEFUL ASSEMBLY OF MACROMOLECULES \u003cbr\u003e Polyethylene and Ziegler Catalysts \u003cbr\u003e Polypropylene and Metallocene Catalysis \u003cbr\u003e Further Polyolefins \u003cbr\u003e Polydienes \u003cbr\u003e Polyketones \u003cbr\u003e Polyalkynes \u003cbr\u003e Post-Metallocenes \u003cbr\u003e Current Topics in Polymer Research \u003cbr\u003e A Typical Experiment \u003cbr\u003e \u003cbr\u003e TELOMERIZATIONS: THE CONSTRUCTION OF C8 AND C10 CHAINS \u003cbr\u003e Reactions, Mechanisms, and Catalysts \u003cbr\u003e Butadiene Telomerizations \u003cbr\u003e Telomerizations with Isoprene \u003cbr\u003e Telomerizations in Liquid?Liquid Biphasic Systems \u003cbr\u003e A Typical Experiment \u003cbr\u003e \u003cbr\u003e REACTIONS WITH CARBON DIOXIDE: THE ACTIVATION OF AN \"INACTIVE\" MOLECULE \u003cbr\u003e Carbon Dioxide and Alkanes \u003cbr\u003e Carbon Dioxide and Alkenes \u003cbr\u003e Carbon Dioxide and Dienes \u003cbr\u003e Carbon Dioxide and Alkynes \u003cbr\u003e Carbon Dioxide and Aromatics \u003cbr\u003e Carbon Dioxide and Hydrogen \u003cbr\u003e Carbon Dioxide and Epoxides \u003cbr\u003e Carbon Dioxide and Amines \u003cbr\u003e Carbon Dioxide-Containing Polymers \u003cbr\u003e A Typical Experiment \u003cbr\u003e \u003cbr\u003e CARBON-CARBON COUPLING WITH AROMATICS: NEW NAME REACTIONS \u003cbr\u003e Mizoroki-Heck Reactions \u003cbr\u003e Sonogashira-Hagihara Reactions \u003cbr\u003e Suzuki-Miyaura Reaction \u003cbr\u003e Cross-Couplings with Metal Organyles \u003cbr\u003e A Typical Experiment \u003cbr\u003e \u003cbr\u003e HYDROGENATIONS: C-H BOND FORMATION \u003cbr\u003e Catalysts and Mechanisms \u003cbr\u003e Asymmetric Hydrogenation \u003cbr\u003e Hydrogenation of Various Functional Groups \u003cbr\u003e Technical Applications \u003cbr\u003e A Typical Experiment \u003cbr\u003e \u003cbr\u003e OXIDATIONS: FORMATION OF C-O BONDS \u003cbr\u003e Wacker Oxidations \u003cbr\u003e Epoxidations \u003cbr\u003e Asymmetric Dihydroxylations \u003cbr\u003e Oxidative Cleavage of C=C Double Bonds \u003cbr\u003e Oxidations of Alkyl Aromatics \u003cbr\u003e A Typical Experiment \u003cbr\u003e \u003cbr\u003e AMINATIONS: FORMATION OF C-N BONDS \u003cbr\u003e Amination of Aryl Halides \u003cbr\u003e Hydroamination of Alkenes \u003cbr\u003e Hydroaminations of Dienes \u003cbr\u003e Hydroamination of Alkynes \u003cbr\u003e Amination of Functional Groups \u003cbr\u003e . . .Some More Aminations \u003cbr\u003e A Typical Experiment \u003cbr\u003e \u003cbr\u003e ISOMERIZATIONS: MIGRATION OF DOUBLE BONDS AND REARRANGEMENT OF THE CARBON BACKBONE \u003cbr\u003e Isomerization of Alkenes \u003cbr\u003e Isomerization of Substituted Alkenes \u003cbr\u003e Rearrangement of the Backbone \u003cbr\u003e A Typical Experiment \u003cbr\u003e \u003cbr\u003e PART IV NEW TRENDS\u003cbr\u003e TANDEM REACTIONS: MULTIPLE SYNTHESIS STEPS IN ONE POT \u003cbr\u003e Multicomponent Reactions \u003cbr\u003e Multifunctional Catalysis \u003cbr\u003e Tandem and Related Reactions \u003cbr\u003e A Typical Experiment \u003cbr\u003e \u003cbr\u003e COMBINATORIAL CHEMISTRY AND HIGH-THROUGHPUT CATALYST SCREENING: THE FAST WAY TO OPTIMUM RESULTS \u003cbr\u003e Basics and Definitions \u003cbr\u003e Parallel Reactor Systems \u003cbr\u003e Sequential Reactor Systems \u003cbr\u003e \u003cbr\u003e GREEN SOLVENTS: WORKING WITH ECO-FRIENDLY SOLVENTS \u003cbr\u003e Ionic Liquids \u003cbr\u003e Supercritical Fluids \u003cbr\u003e Fluorous Solvents \u003cbr\u003e Polyethers \u003cbr\u003e Conclusions \u003cbr\u003e \u003cbr\u003e \u003cbr\u003e ALKANE ACTIVATIONS: ACQUISITIONS OF NEW FEEDSTOCKS \u003cbr\u003e Mechanistic Considerations \u003cbr\u003e Alkane Oxidations \u003cbr\u003e Alkane Carbonylations \u003cbr\u003e Alkane Metathesis \u003cbr\u003e Alkane Hydrogenolysis \u003cbr\u003e Alkane Borylation \u003cbr\u003e Alkane Sulfonation \u003cbr\u003e A Look Back \u003cbr\u003e \u003cbr\u003e MORE EFFICIENT LIGANDS: THE BEST IS THE ENEMY OF THE GOOD \u003cbr\u003e Nitrogen-Containing Ligands \u003cbr\u003e Unusual Phosphorus Ligands \u003cbr\u003e Ligands Containing Elements from Group VIA \u003cbr\u003e Ligands Containing Elements from Group IVA \u003cbr\u003e \u003cbr\u003e NANOCATALYSIS: BETWEEN HOMOGENEOUS AND HETEROGENEOUS CATALYSIS \u003cbr\u003e Synthesis and Properties of Nanocatalysts \u003cbr\u003e Stabilization of Nanoparticles \u003cbr\u003e Heterogenization of Nanoparticles on Solid Supports \u003cbr\u003e Catalysis Involving Metal Nanoparticles \u003cbr\u003e \u003cbr\u003e HOMOGENEOUS CATALYSIS WITH RENEWABLES: USING NATURE.S TREASURES \u003cbr\u003e Catalytic Conversion of Fatty Compounds \u003cbr\u003e Catalytic Reactions of Carbohydrates \u003cbr\u003e Catalytic Reactions of Terpenes \u003cbr\u003e \u003cbr\u003e ELECTROCATALYSIS\/SONOCATALYSIS\/PHOTOCATALYSIS\/MICROWAVE\/EXTREME PRESSURE: ALTERNATIVE METHODS OF ACTIVATION \u003cbr\u003e Electrocatalysis \u003cbr\u003e Photocatalysis \u003cbr\u003e Sonocatalysis \u003cbr\u003e Microwave Catalysis \u003cbr\u003e Extreme High-Pressure Catalysis \u003cbr\u003e \u003cbr\u003e PROCESS DEVELOPMENT IN MINIPLANTS: FROM LABORATORY TO PRODUCTION \u003cbr\u003e Miniplant with Continuously Stirred-Tank Reactor (Miniplant I) \u003cbr\u003e Miniplant with Loop Reactor and Phase Separator (Miniplant II) \u003cbr\u003e Miniplant with Jetloop Reactor and Phase Separator (Miniplant III) \u003cbr\u003e Miniplant with a Mixer?Settler Battery (Miniplant IV) \u003cbr\u003e \u003cbr\u003e THE FUTURE OF HOMOGENEOUS CATALYSIS: A LOOK AHEAD \u003cbr\u003e New Resources \u003cbr\u003e New Reactions\u003cbr\u003e New Catalysts \u003cbr\u003e New Methods \u003cbr\u003e \u003cbr\u003e ANSWERS TO THE QUICKIES \u003cbr\u003e \u003cbr\u003e","brand":"Wiley-VCH Verlag GmbH","offers":[{"title":"Default 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