{"title":"Catalysis Books","description":"","products":[{"product_id":"introduction-to-photocatalysis-from-basic-science-to-applications-9781782623205","title":"Introduction to Photocatalysis: From Basic","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003ePresenting the basic science of semiconductor photocatalysis together with the various practical applications, this textbook is ideal for graduate students. It covers fundamental principles and applicable techniques of light, solid state physics, electrochemistry, reaction kinetics, and materials processing. A solid understanding of semiconductor photoelectrochemistry is developed through discussing the basic properties of a representative photocatalytic material, TiO2; the basic science of the light absorption phenomenon and the application to the powder suspension useful for the photocatalytic research; and the electronic state of semiconductors. Following this, the textbook moves on to explore photoelectrochemistry; the mechanism and kinetic analysis of photocatalytic reactions; typical fabrication methods of common photocatalysts and the factors for improving photocatalytic activity; and evaluation methods of photocatalytic activity. The textbook concludes by looking at the future prospects of the applications of photocatalysis. This introductory textbook provides a foundation in photocatalysis to supplement graduate courses in catalysis, environmental science, materials science and chemical engineering.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eWhat is a Photocatalyst?; Principles of Light Over Solids; Principles of Semiconductors; Principles of Photoelectrochemistry; Photocatalyst Surface and Active Species; Kinetics and Mechanism in Photocatalysis; Methods for Improving Photocatalytic Activity; Fabrication of Practical Photocatalysts; Evaluation Methods of Reactivity; Future Applications of Photocatalysis.","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48741113692503,"sku":"9781782623205","price":73.14,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781782623205.jpg?v=1791476900"},{"product_id":"introduction-to-heterogeneous-catalysis-9781800611504","title":"Introduction To Heterogeneous Catalysis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eCatalysis is a multidisciplinary subject. This book introduces the chemical, materials, and engineering principles of catalysis so that both MSc and PhD students with a basic but not extensive knowledge of chemistry and physics and those with a basic understanding of chemical engineering can learn more about catalysis. Examples are taken from catalytic reactions and catalysts used in the energy, petroleum, and base-chemicals industry.The second edition differs from the first edition in the way basic topics are integrated with catalytic applications. The authors introduce two new chapters: 'Cleaning of Fuels by Hydrotreating' and 'Electrocatalysis'. Hydrotreating is a very important industrial process and offers the opportunity to discuss metal sulfide catalysts. Electrocatalysis gains more and more attention because it can be used to minimize the anthropogenic CO₂ emissions. Solar, wind, and hydroelectricity can drive water electrolysis and CO₂ electroreduction and, therefore, excess renewable electricity can be stored in chemicals.Introduction to Heterogeneous Catalysis (Second Edition) is intended for a one-semester course for master and PhD students who want to learn more about the principles of catalysis. This must-read textbook will enable students to read catalysis literature without much difficulty and presents not only the basic concepts of catalysis but integrates the chemical, materials, and engineering aspects of catalysis with industry examples.","brand":"World Scientific Europe Ltd","offers":[{"title":"Default Title","offer_id":48741753684311,"sku":"9781800611504","price":90.0,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781800611504.jpg?v=1720058693"},{"product_id":"introduction-to-heterogeneous-catalysis-9781800611610","title":"Introduction To Heterogeneous Catalysis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eCatalysis is a multidisciplinary subject. This book introduces the chemical, materials, and engineering principles of catalysis so that both MSc and PhD students with a basic but not extensive knowledge of chemistry and physics and those with a basic understanding of chemical engineering can learn more about catalysis. Examples are taken from catalytic reactions and catalysts used in the energy, petroleum, and base-chemicals industry.The second edition differs from the first edition in the way basic topics are integrated with catalytic applications. The authors introduce two new chapters: 'Cleaning of Fuels by Hydrotreating' and 'Electrocatalysis'. Hydrotreating is a very important industrial process and offers the opportunity to discuss metal sulfide catalysts. Electrocatalysis gains more and more attention because it can be used to minimize the anthropogenic CO₂ emissions. Solar, wind, and hydroelectricity can drive water electrolysis and CO₂ electroreduction and, therefore, excess renewable electricity can be stored in chemicals.Introduction to Heterogeneous Catalysis (Second Edition) is intended for a one-semester course for master and PhD students who want to learn more about the principles of catalysis. This must-read textbook will enable students to read catalysis literature without much difficulty and presents not only the basic concepts of catalysis but integrates the chemical, materials, and engineering aspects of catalysis with industry examples.","brand":"World Scientific Europe Ltd","offers":[{"title":"Default Title","offer_id":48741753880919,"sku":"9781800611610","price":49.5,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781800611610.jpg?v=1720058693"},{"product_id":"modern-ylide-chemistry-applications-in-ligand-design-organic-and-catalytic-transformations-9783319895444","title":"Modern Ylide Chemistry: Applications in Ligand","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis volume covers recent advances in the chemistry of ylidic compounds with focus on their application in the design of ligands with unique donor properties, the development of novel organic transformations as well as the use of ylides in homogenous catalysis. Thereby, this volume particularly aims at the community of organic and organometallic chemists engaged in synthetic chemistry and catalysis as well as in the use of special ligands for the stabilization of unusual main group element species and the “transition-metal free” activation of element-element\/hydrogen bonds. These fields of research are highly active and vivid research areas to which ylide chemistry has only recently started to contribute, but has already led to fascinating developments in most different directions. This volume highlights these recent developments, thus giving not only an overview over the past achievements, but also possibilities for future applications. To this end, the chapters selected in this volume combine different aspects of ylide chemistry, starting with theoretical aspects in ligand design followed by synthetic organic methods, catalytic transformations and complex chemistry. \u003cbr\u003e\u003cp\u003e\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eStructure and Reactivity of Carbones and Ylide Stabilized Carbenes: Contributions from Theory.- Synthesis, Structure, and Reactivity of Carbodiphosphoranes,Carbodicarbenes,and Related Species.- Synthesis and Structure of Carbodicarbenes and Their Application in Catalysis.- Sulfur Ylides in Organic Synthesis and Transition Metal Catalysis.- Reactivity and Applications of α-Metalated Ylides.\u003c\/p\u003e","brand":"Springer International Publishing AG","offers":[{"title":"Default Title","offer_id":48743108411735,"sku":"9783319895444","price":999.99,"currency_code":"GBP","in_stock":false}]},{"product_id":"industrial-catalysis-a-practical-approach-9783527331659","title":"Industrial Catalysis: A Practical Approach","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eNow in it's 3rd Edition,\u003ci\u003e Industrial Catalysis\u003c\/i\u003e offers all relevant information on catalytic processes in industry, including many recent examples. Perfectly suited for self-study, it is the ideal companion for scientists who want to get into the field or refresh existing knowledge.\u003cbr\u003e\u003cbr\u003eThe updated edition covers the full range of industrial aspects, from catalyst development and testing to process examples and catalyst recycling. The book is characterized by its practical relevance, expressed by a selection of over 40 examples of catalytic processes in industry. In addition, new chapters on catalytic processes with renewable materials and polymerization catalysis have been included. Existing chapters have been carefully revised and supported by new subchapters, for example, on metathesis reactions, refinery processes, petrochemistry and new reactor concepts.\u003cbr\u003e\u003cbr\u003e\u003ci\u003e \"I found the book accesible, readable and interesting - both as a refresher and as an introduction to new topics - and a convenient first reference on current industrial catalytic practise and processes.\"\u003c\/i\u003e\u003cbr\u003e Excerpt from a book review for the second edition by P. C. H. Mitchell, Applied Organometallic Chemistry (2007)\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e\"This is the third addition of Jens Hagen�s overview of the industrial application of catalytic science and engineering. As with previous editions this work covers a wide range of catalytic processes spanning heterogeneous and homogeneous catalysis, including chapters on biocatalysis and electrocatalysis. This edition has been extensively revised and includes additions not present in earlier versions. A key feature of the text is inclusion of exercises in each chapter, with solutions provided...[This book] would...be a useful reference for an introductory undergraduate course on catalysis, for whom the exercises would be particularly valuable, or to a researcher starting out in area unfamiliar to them...\u003c\/p\u003e \u003cp\u003e...an excellent overview of catalysis and its applications more broadly...\"(\u003cb\u003eAOC review March 2017\u003cb\u003e)\u003c\/b\u003e\u003c\/b\u003e\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003ePreface to the Third Edition XV\u003c\/p\u003e \u003cp\u003eAbbreviations XVII\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introduction 1\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e1.1 The Phenomenon Catalysis 1\u003c\/p\u003e \u003cp\u003e1.2 Mode of Action of Catalysts 2\u003c\/p\u003e \u003cp\u003e1.2.1 Activity 4\u003c\/p\u003e \u003cp\u003e1.2.1.1 Turnover Frequency TOF 6\u003c\/p\u003e \u003cp\u003e1.2.1.2 Turnover Number TON 7\u003c\/p\u003e \u003cp\u003e1.2.2 Selectivity 7\u003c\/p\u003e \u003cp\u003e1.2.3 Stability 8\u003c\/p\u003e \u003cp\u003e1.2.4 Mole Balance and Conversion 8\u003c\/p\u003e \u003cp\u003e1.3 Classification of Catalysts 10\u003c\/p\u003e \u003cp\u003e1.4 Comparison of Homogeneous and Heterogeneous Catalysis 11\u003c\/p\u003e \u003cp\u003eExercises 14\u003c\/p\u003e \u003cp\u003eReferences 15\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Homogeneous Catalysis with Transition Metal Catalysts 17\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e2.1 Key Reactions in Homogeneous Catalysis 18\u003c\/p\u003e \u003cp\u003e2.1.1 Coordination and Exchange of Ligands 18\u003c\/p\u003e \u003cp\u003e2.1.2 Complex Formation 20\u003c\/p\u003e \u003cp\u003e2.1.3 Acid–Base Reactions 22\u003c\/p\u003e \u003cp\u003e2.1.4 Redox Reactions: Oxidative Addition and Reductive Elimination 23\u003c\/p\u003e \u003cp\u003e2.1.4.1 Oxidative Coupling and Reductive Cleavage 27\u003c\/p\u003e \u003cp\u003e2.1.5 Insertion and Elimination Reactions 28\u003c\/p\u003e \u003cp\u003e2.1.5.1 β-Elimination 30\u003c\/p\u003e \u003cp\u003e2.1.5.2 α-Elimination 30\u003c\/p\u003e \u003cp\u003e2.1.6 Reactions at Coordinated Ligands 31\u003c\/p\u003e \u003cp\u003e2.2 Catalyst Concepts in Homogeneous Catalysis 32\u003c\/p\u003e \u003cp\u003e2.2.1 The 16\/18-Electron Rule 32\u003c\/p\u003e \u003cp\u003e2.2.2 Catalytic Cycles 34\u003c\/p\u003e \u003cp\u003e2.3 Characterization of Homogeneous Catalysts 35\u003c\/p\u003e \u003cp\u003e2.3.1 Infrared Spectroscopy 38\u003c\/p\u003e \u003cp\u003e2.3.2 NMR Spectroscopy 40\u003c\/p\u003e \u003cp\u003eExercises 42\u003c\/p\u003e \u003cp\u003eReferences 45\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Homogeneously Catalyzed Industrial Processes 47\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e3.1 Overview 47\u003c\/p\u003e \u003cp\u003e3.2 Examples of Industrial Processes 48\u003c\/p\u003e \u003cp\u003e3.2.1 Oxo Synthesis 50\u003c\/p\u003e \u003cp\u003e3.2.2 Production of Acetic Acid by Carbonylation of Methanol 52\u003c\/p\u003e \u003cp\u003e3.2.3 Selective Ethylene Oxidation by theWacker Process 55\u003c\/p\u003e \u003cp\u003e3.2.4 Oxidation of Cyclohexane 57\u003c\/p\u003e \u003cp\u003e3.2.5 Suzuki Coupling 58\u003c\/p\u003e \u003cp\u003e3.2.6 Oligomerization of Ethylene (SHOP Process) 59\u003c\/p\u003e \u003cp\u003e3.2.7 Telomerization of Butadiene 61\u003c\/p\u003e \u003cp\u003e3.2.8 Adipodinitrile 63\u003c\/p\u003e \u003cp\u003e3.3 Asymmetric Catalysis 63\u003c\/p\u003e \u003cp\u003e3.3.1 Introduction 63\u003c\/p\u003e \u003cp\u003e3.3.2 Catalysts 64\u003c\/p\u003e \u003cp\u003e3.3.3 Commercial Applications 65\u003c\/p\u003e \u003cp\u003e3.3.3.1 Asymmetric Hydrogenation 65\u003c\/p\u003e \u003cp\u003e3.3.3.2 Enantioselective Isomerization: L-Menthol 67\u003c\/p\u003e \u003cp\u003e3.3.3.3 Asymmetric Epoxidation 68\u003c\/p\u003e \u003cp\u003e3.4 Alkene Metathesis 69\u003c\/p\u003e \u003cp\u003e3.4.1 Examples of Heterogeneous Catalysis 72\u003c\/p\u003e \u003cp\u003e3.5 Recycling of Homogeneous Catalysts 73\u003c\/p\u003e \u003cp\u003e3.5.1 Overview 73\u003c\/p\u003e \u003cp\u003e3.5.1.1 Precipitation of the Catalyst or of the Product(s) 73\u003c\/p\u003e \u003cp\u003e3.5.1.2 Thermal Separation 73\u003c\/p\u003e \u003cp\u003e3.5.1.3 Membrane Separation 73\u003c\/p\u003e \u003cp\u003e3.5.1.4 Adsorption 74\u003c\/p\u003e \u003cp\u003e3.5.1.5 Phase Separation\/Extraction 74\u003c\/p\u003e \u003cp\u003e3.5.2 Reactions in Two-Phase Liquid–Liquid Systems 74\u003c\/p\u003e \u003cp\u003eExercises 76\u003c\/p\u003e \u003cp\u003eReferences 78\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Biocatalysis 81\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 81\u003c\/p\u003e \u003cp\u003e4.1.1 Active Sites 83\u003c\/p\u003e \u003cp\u003e4.1.2 Coenzymes 84\u003c\/p\u003e \u003cp\u003e4.2 Kinetics of Enzyme-Catalyzed Reactions 84\u003c\/p\u003e \u003cp\u003e4.3 Industrial Processes with Biocatalysts 90\u003c\/p\u003e \u003cp\u003e4.3.1 Acrylamide from Acrylonitrile 90\u003c\/p\u003e \u003cp\u003e4.3.2 Aspartame Through Enzymatic Peptide Synthesis 91\u003c\/p\u003e \u003cp\u003e4.3.3 L-Amino Acids by Aminoacylase Process 92\u003c\/p\u003e \u003cp\u003e4.3.4 Pharmaceuticals 93\u003c\/p\u003e \u003cp\u003e4.3.5 Herbicides 95\u003c\/p\u003e \u003cp\u003e4.3.5.1 4-Hydroxyphenoxypropionic Acid as Herbicide Intermediate 96\u003c\/p\u003e \u003cp\u003eExercises 97\u003c\/p\u003e \u003cp\u003eReferences 97\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Heterogeneous Catalysis: Fundamentals 99\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e5.1 Individual Steps in Heterogeneous Catalysis 99\u003c\/p\u003e \u003cp\u003e5.2 Kinetics and Mechanisms of Heterogeneously Catalyzed Reactions 101\u003c\/p\u003e \u003cp\u003e5.2.1 The Importance of Adsorption in Heterogeneous Catalysis 102\u003c\/p\u003e \u003cp\u003e5.2.2 Kinetic Treatment 106\u003c\/p\u003e \u003cp\u003e5.2.3 Mechanisms of Heterogeneously Catalyzed Gas-Phase Reactions 108\u003c\/p\u003e \u003cp\u003e5.2.3.1 Langmuir–Hinshelwood Mechanism (1921) 109\u003c\/p\u003e \u003cp\u003e5.2.3.2 Eley–Rideal Mechanism (1943) 111\u003c\/p\u003e \u003cp\u003e5.3 Catalyst Concepts in Heterogeneous Catalysis 113\u003c\/p\u003e \u003cp\u003e5.3.1 Energetic Aspects of Catalytic Activity 113\u003c\/p\u003e \u003cp\u003e5.3.2 Steric Effects 124\u003c\/p\u003e \u003cp\u003e5.3.3 Electronic Factors 134\u003c\/p\u003e \u003cp\u003e5.3.3.1 Redox Catalysts 134\u003c\/p\u003e \u003cp\u003e5.3.3.2 Acid\/Base Catalysts (Ionic Catalysts) 135\u003c\/p\u003e \u003cp\u003e5.3.3.3 Metals 136\u003c\/p\u003e \u003cp\u003e5.3.3.4 Bimetallic Catalysts 140\u003c\/p\u003e \u003cp\u003e5.3.3.5 Semiconductors 144\u003c\/p\u003e \u003cp\u003e5.3.3.6 Insulators: Acidic and Basic Catalysts 157\u003c\/p\u003e \u003cp\u003e5.4 Catalyst Performance 164\u003c\/p\u003e \u003cp\u003e5.4.1 FactorsWhich Affect the Catalyst Performance 164\u003c\/p\u003e \u003cp\u003e5.4.2 Supported Catalysts 166\u003c\/p\u003e \u003cp\u003e5.4.3 Promoters 172\u003c\/p\u003e \u003cp\u003e5.4.4 Inhibitors 176\u003c\/p\u003e \u003cp\u003e5.5 Catalyst Deactivation 177\u003c\/p\u003e \u003cp\u003e5.5.1 Catalyst Poisoning 179\u003c\/p\u003e \u003cp\u003e5.5.2 Poisoning of Metals 179\u003c\/p\u003e \u003cp\u003e5.5.3 Poisoning of Semiconductor Oxides 182\u003c\/p\u003e \u003cp\u003e5.5.4 Poisoning of Solid Acids 182\u003c\/p\u003e \u003cp\u003e5.5.5 Deposits on the Catalyst Surface 183\u003c\/p\u003e \u003cp\u003e5.5.6 Thermal Processes and Sintering 185\u003c\/p\u003e \u003cp\u003e5.5.7 Catalyst Losses via the Gas Phase 186\u003c\/p\u003e \u003cp\u003e5.6 Regeneration and Recycling of Heterogeneous Catalysts 186\u003c\/p\u003e \u003cp\u003e5.7 Characterization of Heterogeneous Catalysts 189\u003c\/p\u003e \u003cp\u003e5.7.1 Physical Characterization 190\u003c\/p\u003e \u003cp\u003e5.7.1.1 Temperature-Programmed Desorption 195\u003c\/p\u003e \u003cp\u003e5.7.2 Chemical Characterization and Surface Analysis 195\u003c\/p\u003e \u003cp\u003e5.7.2.1 Temperature-Programmed Reaction Methods 196\u003c\/p\u003e \u003cp\u003e5.7.2.2 Transmission Electron Microscopy 197\u003c\/p\u003e \u003cp\u003e5.7.2.3 Low-Energy Electron Diffraction (LEED) 198\u003c\/p\u003e \u003cp\u003e5.7.2.4 IR Spectroscopy 199\u003c\/p\u003e \u003cp\u003e5.7.2.5 Electron Spectroscopy for Chemical Analysis (ESCA) 199\u003c\/p\u003e \u003cp\u003e5.7.2.6 Auger Electron Spectroscopy (AES) 201\u003c\/p\u003e \u003cp\u003e5.7.2.7 Ion Scattering Spectroscopy (ISS) 201\u003c\/p\u003e \u003cp\u003e5.7.2.8 Secondary Ion Mass Spectrometry (SIMS) 202\u003c\/p\u003e \u003cp\u003eExercises 203\u003c\/p\u003e \u003cp\u003eReferences 209\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Catalyst Shapes and Production of Heterogeneous Catalysts 211\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 211\u003c\/p\u003e \u003cp\u003e6.2 Bulk Catalysts 212\u003c\/p\u003e \u003cp\u003e6.2.1 Precipitation 212\u003c\/p\u003e \u003cp\u003e6.2.2 Fusion and Alloy Leaching 214\u003c\/p\u003e \u003cp\u003e6.2.3 Sol–Gel Synthesis 215\u003c\/p\u003e \u003cp\u003e6.2.4 Flame Hydrolysis 217\u003c\/p\u003e \u003cp\u003e6.2.5 Hydrothermal Synthesis 217\u003c\/p\u003e \u003cp\u003e6.2.6 Heteropolyacids 219\u003c\/p\u003e \u003cp\u003e6.3 Supported Catalysts 219\u003c\/p\u003e \u003cp\u003e6.3.1 Impregnation 220\u003c\/p\u003e \u003cp\u003e6.3.2 Coprecipitation 225\u003c\/p\u003e \u003cp\u003e6.3.3 Adsorption\/Ion-Exchange 226\u003c\/p\u003e \u003cp\u003e6.3.3.1 Ion-Exchange Resins 227\u003c\/p\u003e \u003cp\u003e6.3.4 Anchoring\/Grafting 228\u003c\/p\u003e \u003cp\u003e6.3.5 Monolithic Catalysts 229\u003c\/p\u003e \u003cp\u003e6.4 Shaping of Catalysts and Catalyst Supports 230\u003c\/p\u003e \u003cp\u003e6.5 Immobilization of Homogeneous Catalysts 232\u003c\/p\u003e \u003cp\u003e6.5.1 Supported Solid-Phase Catalysts (SSPC) 234\u003c\/p\u003e \u003cp\u003e6.5.2 Supported Liquid-Phase Catalysts (SLPC) 236\u003c\/p\u003e \u003cp\u003e6.5.3 Encapsulation 236\u003c\/p\u003e \u003cp\u003eExercises 237\u003c\/p\u003e \u003cp\u003eReferences 238\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Shape-Selective Catalysis: Zeolites 239\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e7.1 Composition and Structure of Zeolites 239\u003c\/p\u003e \u003cp\u003e7.2 Catalytic Properties of the Zeolites 242\u003c\/p\u003e \u003cp\u003e7.2.1 Shape Selectivity 243\u003c\/p\u003e \u003cp\u003e7.2.1.1 Reactant Selectivity 243\u003c\/p\u003e \u003cp\u003e7.2.1.2 Product Selectivity 246\u003c\/p\u003e \u003cp\u003e7.2.1.3 Restricted Transition State Selectivity 246\u003c\/p\u003e \u003cp\u003e7.2.2 Acidity of Zeolites 247\u003c\/p\u003e \u003cp\u003e7.3 Isomorphic Substitution of Zeolites 251\u003c\/p\u003e \u003cp\u003e7.4 Metal-Doped Zeolites 252\u003c\/p\u003e \u003cp\u003e7.5 Applications of Zeolites 255\u003c\/p\u003e \u003cp\u003eExercises 258\u003c\/p\u003e \u003cp\u003eReferences 259\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Heterogeneously Catalyzed Processes in Industry 261\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e8.1 Overview 261\u003c\/p\u003e \u003cp\u003e8.1.1 Production of Inorganic Chemicals 261\u003c\/p\u003e \u003cp\u003e8.1.2 Production of Organic Chemicals 261\u003c\/p\u003e \u003cp\u003e8.1.3 Refinery Processes 262\u003c\/p\u003e \u003cp\u003e8.1.4 Catalysts in Environmental Protection 264\u003c\/p\u003e \u003cp\u003e8.2 Examples of Industrial Processes – Bulk Chemicals 266\u003c\/p\u003e \u003cp\u003e8.2.1 Ammonia Synthesis 266\u003c\/p\u003e \u003cp\u003e8.2.2 Hydrogenation 268\u003c\/p\u003e \u003cp\u003e8.2.3 Methanol Synthesis 270\u003c\/p\u003e \u003cp\u003e8.2.4 Selective Oxidation of Propene 272\u003c\/p\u003e \u003cp\u003e8.2.4.1 Oxidation of Propene with H2O2 to Propylene Oxide 277\u003c\/p\u003e \u003cp\u003e8.2.5 Selective Oxidation of Hydrocarbons 277\u003c\/p\u003e \u003cp\u003e8.2.5.1 n-Butane to Maleic Anhydride 278\u003c\/p\u003e \u003cp\u003e8.2.5.2 o-Xylene to Phthalic Anhydride 280\u003c\/p\u003e \u003cp\u003e8.3 Fine Chemicals Manufacture 281\u003c\/p\u003e \u003cp\u003e8.3.1 Fine Chemicals andTheir Synthesis 281\u003c\/p\u003e \u003cp\u003e8.3.2 Selected Examples of Industrial Processes 285\u003c\/p\u003e \u003cp\u003e8.3.2.1 Hydrogenation 286\u003c\/p\u003e \u003cp\u003e8.3.2.2 Oxidation 288\u003c\/p\u003e \u003cp\u003e8.3.2.3 Catalytic C–C Linkage 290\u003c\/p\u003e \u003cp\u003e8.3.2.4 Acid\/Base Catalysis 292\u003c\/p\u003e \u003cp\u003eExercises 294\u003c\/p\u003e \u003cp\u003eReferences 297\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Refinery Processes and Petrochemistry 299\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e9.1 Hydrotreating 300\u003c\/p\u003e \u003cp\u003e9.2 Catalytic Cracking 302\u003c\/p\u003e \u003cp\u003e9.3 Hydrocracking 304\u003c\/p\u003e \u003cp\u003e9.4 Catalytic Reforming 306\u003c\/p\u003e \u003cp\u003e9.5 Alkylation 307\u003c\/p\u003e \u003cp\u003e9.6 Hydroisomerization 308\u003c\/p\u003e \u003cp\u003e9.7 Synthesis Gas and Hydrogen by Steam Reforming 310\u003c\/p\u003e \u003cp\u003e9.8 Natural Gas Conversion to Fuels and Chemicals 312\u003c\/p\u003e \u003cp\u003e9.9 Fischer–Tropsch Synthesis 313\u003c\/p\u003e \u003cp\u003e9.10 Etherification Reactions 315\u003c\/p\u003e \u003cp\u003eExercises 316\u003c\/p\u003e \u003cp\u003eReferences 317\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Electrocatalytic Processes 319\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e10.1 Comparison Between Electrocatalysis and Heterogeneous Catalysis 319\u003c\/p\u003e \u003cp\u003e10.2 Electroorganic Syntheses 319\u003c\/p\u003e \u003cp\u003e10.2.1 Electrocatalytic Hydrogenation 320\u003c\/p\u003e \u003cp\u003e10.2.2 Electrocatalytic Oxidation 322\u003c\/p\u003e \u003cp\u003e10.2.3 Electrochemical Addition 323\u003c\/p\u003e \u003cp\u003e10.3 Electrocatalysis in Fuel Cells 324\u003c\/p\u003e \u003cp\u003e10.3.1 Basic Principles 324\u003c\/p\u003e \u003cp\u003e10.3.2 Types of Fuel Cell and Catalyst 325\u003c\/p\u003e \u003cp\u003e10.3.3 Important Reactions in Fuel Cell Technology 328\u003c\/p\u003e \u003cp\u003e10.3.3.1 The Anodic Reaction 328\u003c\/p\u003e \u003cp\u003e10.3.3.2 The Cathodic Reaction 329\u003c\/p\u003e \u003cp\u003e10.3.3.3 Methanol Oxidation 331\u003c\/p\u003e \u003cp\u003eExercises 332\u003c\/p\u003e \u003cp\u003eReferences 333\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Environmental Catalysis and Green Chemistry 335\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e11.1 Automotive Exhaust Catalysis 335\u003c\/p\u003e \u003cp\u003e11.2 NOx Removal Systems 338\u003c\/p\u003e \u003cp\u003e11.2.1 Selective Catalytic Reduction of Nitrogen Oxides 338\u003c\/p\u003e \u003cp\u003e11.2.2 NOx Storage-Reduction Catalyst for Lean-Burning Engines 340\u003c\/p\u003e \u003cp\u003e11.3 Catalytic Afterburning 341\u003c\/p\u003e \u003cp\u003e11.4 Green Chemistry and Catalysis 344\u003c\/p\u003e \u003cp\u003e11.4.1 Examples of Catalytical Processes 345\u003c\/p\u003e \u003cp\u003e11.4.1.1 Aldol Condensation 345\u003c\/p\u003e \u003cp\u003e11.4.1.2 Diels–Alder Reaction 346\u003c\/p\u003e \u003cp\u003e11.4.1.3 Hydrogenation 347\u003c\/p\u003e \u003cp\u003e11.4.1.4 Cyclization inWater 347\u003c\/p\u003e \u003cp\u003e11.4.1.5 Use of Ionic Liquids 347\u003c\/p\u003e \u003cp\u003e11.4.1.6 Green Solvents 349\u003c\/p\u003e \u003cp\u003eExercises 350\u003c\/p\u003e \u003cp\u003eReferences 351\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Phase-Transfer Catalysis 353\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e12.1 Definition 353\u003c\/p\u003e \u003cp\u003e12.2 Catalysts for PTC 353\u003c\/p\u003e \u003cp\u003e12.3 Mechanism and Benefits of PTC 354\u003c\/p\u003e \u003cp\u003e12.4 PTC Reactions 355\u003c\/p\u003e \u003cp\u003e12.5 Selected Industrial Processes with PTC 356\u003c\/p\u003e \u003cp\u003e12.5.1 Continuous Dehydrohalogenation to Produce the Large-Scale Monomer Chloroprene 356\u003c\/p\u003e \u003cp\u003e12.5.2 Polycarbonate Manufacture with Phosgene 356\u003c\/p\u003e \u003cp\u003e12.5.3 Etherification (O-Alkylation) 357\u003c\/p\u003e \u003cp\u003e12.5.4 Aldehydes by Oxidation of Alcohols with Hypochlorite 357\u003c\/p\u003e \u003cp\u003e12.5.5 Carbonylation 357\u003c\/p\u003e \u003cp\u003e12.5.6 2-Phenylbutyronitrile by Alkylation 358\u003c\/p\u003e \u003cp\u003eExercises 359\u003c\/p\u003e \u003cp\u003eReferences 359\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Catalytic Processes with Renewable Materials 361\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e13.1 Biofuels 361\u003c\/p\u003e \u003cp\u003e13.2 Biorefinery 366\u003c\/p\u003e \u003cp\u003e13.2.1 Lignocellulose Feedstock Biorefinery 368\u003c\/p\u003e \u003cp\u003e13.3 Chemicals from Biomass 369\u003c\/p\u003e \u003cp\u003e13.3.1 Chemicals from Biomass via Platform Molecules 369\u003c\/p\u003e \u003cp\u003e13.3.1.1 Carbohydrates 369\u003c\/p\u003e \u003cp\u003e13.3.1.2 Fats and Oils 373\u003c\/p\u003e \u003cp\u003e13.3.1.3 Terpenes 375\u003c\/p\u003e \u003cp\u003e13.3.2 Direct Biomass Conversion to End-Products 376\u003c\/p\u003e \u003cp\u003eExercises 378\u003c\/p\u003e \u003cp\u003eReferences 378\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 Polymerization Catalysis 381\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction 381\u003c\/p\u003e \u003cp\u003e14.2 Fundamentals of Catalytical Polymerization Processes 381\u003c\/p\u003e \u003cp\u003e14.3 Coordination Polymerization 383\u003c\/p\u003e \u003cp\u003e14.3.1 Ziegler–Natta Catalysts 383\u003c\/p\u003e \u003cp\u003e14.3.1.1 Heterogeneous Ziegler–Natta Catalysts 384\u003c\/p\u003e \u003cp\u003e14.3.1.2 Homogeneous Ziegler–Natta Catalysts 386\u003c\/p\u003e \u003cp\u003e14.3.1.3 Metallocenes 386\u003c\/p\u003e \u003cp\u003e14.3.1.4 Ring-OpeningMetathetic Polymerization 388\u003c\/p\u003e \u003cp\u003e14.4 Examples of Catalytical Polymerization Processes 389\u003c\/p\u003e \u003cp\u003e14.4.1 Polyethylene Production 389\u003c\/p\u003e \u003cp\u003e14.4.2 Polypropylene Production 391\u003c\/p\u003e \u003cp\u003eExercises 392\u003c\/p\u003e \u003cp\u003eReferences 393\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Planning, Development, and Testing of Catalysts 395\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e15.1 Stages of Catalyst Development 395\u003c\/p\u003e \u003cp\u003e15.2 Development of a Catalytical Process: Hydrogenation of Benzene to Cyclohexane 398\u003c\/p\u003e \u003cp\u003e15.3 Selection and Testing of Catalysts in Practice 401\u003c\/p\u003e \u003cp\u003e15.3.1 Catalyst Screening 401\u003c\/p\u003e \u003cp\u003e15.3.2 Catalyst Test Reactors and Kinetic Modeling 405\u003c\/p\u003e \u003cp\u003e15.3.2.1 Differential Reactor 405\u003c\/p\u003e \u003cp\u003e15.3.2.2 Differential Circulating Reactor 407\u003c\/p\u003e \u003cp\u003e15.3.2.3 Integral reactor 411\u003c\/p\u003e \u003cp\u003e15.3.3 Kinetic Modeling and Simulation 416\u003c\/p\u003e \u003cp\u003e15.3.3.1 Hydrogenation of Benzaldehyde 416\u003c\/p\u003e \u003cp\u003e15.3.3.2 Modeling of a Trickle Bed Reactor 420\u003c\/p\u003e \u003cp\u003e15.3.4 Catalyst Discovery via High-Throughput Experimentation 427\u003c\/p\u003e \u003cp\u003eExercises 430\u003c\/p\u003e \u003cp\u003eReferences 430\u003c\/p\u003e \u003cp\u003e\u003cb\u003e16 Catalysis Reactors 433\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e16.1 Plug Flow Reactor (PFR) 433\u003c\/p\u003e \u003cp\u003e16.2 Continuous Stirred-Tank Reactor (CSTR) 435\u003c\/p\u003e \u003cp\u003e16.3 Reactor Calculations 436\u003c\/p\u003e \u003cp\u003e16.4 Two-Phase Reactors 440\u003c\/p\u003e \u003cp\u003e16.4.1 Single-Bed Reactor 441\u003c\/p\u003e \u003cp\u003e16.4.2 Multibed Reactor 441\u003c\/p\u003e \u003cp\u003e16.4.3 Multitubular Reactors 442\u003c\/p\u003e \u003cp\u003e16.4.4 Shallow-Bed Reactors 442\u003c\/p\u003e \u003cp\u003e16.4.5 Fluidized-Bed Reactors 443\u003c\/p\u003e \u003cp\u003e16.5 Three-Phase Reactors 443\u003c\/p\u003e \u003cp\u003e16.5.1 Fixed-Bed Reactors 445\u003c\/p\u003e \u003cp\u003e16.5.2 Suspension Reactors 447\u003c\/p\u003e \u003cp\u003e16.6 Reactors for Homogeneously Catalyzed Reactions 451\u003c\/p\u003e \u003cp\u003e16.7 New Reactor Concepts 452\u003c\/p\u003e \u003cp\u003e16.7.1 Membrane Reactors 452\u003c\/p\u003e \u003cp\u003e16.7.2 Catalytic Reactive Distillation 453\u003c\/p\u003e \u003cp\u003e16.7.3 Catalytic Microreactors 454\u003c\/p\u003e \u003cp\u003eExercises 455\u003c\/p\u003e \u003cp\u003eReferences 457\u003c\/p\u003e \u003cp\u003e\u003cb\u003e17 Economic Importance of Catalysts 459\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003eReferences 462\u003c\/p\u003e \u003cp\u003e\u003cb\u003e18 Future Development of Catalysis 463\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e18.1 Homogeneous Catalysis 463\u003c\/p\u003e \u003cp\u003e18.2 Heterogeneous Catalysis 465\u003c\/p\u003e \u003cp\u003e18.2.1 Use of Other Cheaper Raw Materials 467\u003c\/p\u003e \u003cp\u003e18.2.2 Catalysts for Energy Generation 468\u003c\/p\u003e \u003cp\u003e18.2.3 Better Strategies for Catalyst Development 469\u003c\/p\u003e \u003cp\u003eReferences 472\u003c\/p\u003e \u003cp\u003eSolutions to the Exercises 473\u003c\/p\u003e \u003cp\u003eIndex 513\u003c\/p\u003e","brand":"Wiley-VCH Verlag GmbH","offers":[{"title":"Default Title","offer_id":48743117226327,"sku":"9783527331659","price":116.41,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9783527331659.jpg?v=1791379136"},{"product_id":"sustainable-catalysis-energy-efficient-reactions-and-applications-9783527338672","title":"Sustainable Catalysis: Energy-Efficient Reactions","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eHighlighting sustainable catalytic processes in synthetic organic chemistry and industry, this useful guide places special emphasis on catalytic reactions carried out at room temperature.\u003cbr\u003e It describes the fundamentals, summarizes key advances, and covers applications in industrial processes in the field of energy generation from renewables, food science, and pollution control. Throughout, the latest research from various disciplines is combined, such as homogeneous and heterogeneous catalysis, biocatalysis, and photocatalysis. The book concludes with a chapter on future trends and energy challenges for the latter half of the 21st century. \u003cbr\u003e With its multidisciplinary approach this is an essential reference for academic and industrial researchers in catalysis science aiming to design more sustainable and energy-efficient processes.\u003cbr\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e\u003cb\u003e1 Introduction to Room-Temperature Catalysis 1\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eEduardo J. Garcia-Suarez and Anders Riisager\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 Room-Temperature Homogeneous Catalysts 2\u003c\/p\u003e \u003cp\u003e1.2.1 Ionic-Liquid-Based Catalytic Systems at Room Temperature 2\u003c\/p\u003e \u003cp\u003e1.2.2 Transition Metal Homogeneous Catalysts 6\u003c\/p\u003e \u003cp\u003e1.2.2.1 Group 9-Based Homogeneous Catalysts (Co, Rh, Ir) 6\u003c\/p\u003e \u003cp\u003e1.2.2.2 Group 10-Based Homogeneous Catalysts (Ni, Pd, Pt) 7\u003c\/p\u003e \u003cp\u003e1.2.2.3 Group 11-Based Homogeneous Catalysts (Ag, Au) 10\u003c\/p\u003e \u003cp\u003e1.3 Room-Temperature Heterogeneous Catalysts 10\u003c\/p\u003e \u003cp\u003e1.3.1 Group 9-Based Heterogeneous Catalysts (Co, Rh, Ir) 11\u003c\/p\u003e \u003cp\u003e1.3.2 Group 10-Based Heterogeneous Catalysts (Ni, Pd, Pt) 13\u003c\/p\u003e \u003cp\u003e1.3.3 Group 11-Based Heterogeneous Catalysts (Cu, Pt, Au) 23\u003c\/p\u003e \u003cp\u003e1.4 Conclusions and Perspectives 29\u003c\/p\u003e \u003cp\u003eReferences 31\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Functionalized Ionic Liquid-based Catalytic Systems with Diversified Performance Enhancements 35\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eShiguo Zhang and Yanlong Gu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 35\u003c\/p\u003e \u003cp\u003e2.2 Functionalized ILs for Enhancing Catalytic Activity 36\u003c\/p\u003e \u003cp\u003e2.3 Functionalized ILs for Improving Reaction Selectivity 38\u003c\/p\u003e \u003cp\u003e2.4 Functionalized ILs for Facilitating Catalyst Recycling and Product Isolation 40\u003c\/p\u003e \u003cp\u003e2.5 Functionalized ILs for Making Relay Catalysis 43\u003c\/p\u003e \u003cp\u003e2.6 Cation and Anion Synergistic Catalysis in Ionic Liquids 45\u003c\/p\u003e \u003cp\u003e2.7 Functionalized ILs for Aqueous Catalysis 46\u003c\/p\u003e \u003cp\u003e2.8 Catalysis by Porous Poly-ILs 47\u003c\/p\u003e \u003cp\u003e2.9 Functionalized IL-Based Carbon Material for Catalysis 49\u003c\/p\u003e \u003cp\u003e2.10 Summary and Conclusions 54\u003c\/p\u003e \u003cp\u003eReferences 54\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Heterogeneous Room Temperature Catalysis – Nanomaterials 59\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eLiyu Chen and Yingwei Li\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 59\u003c\/p\u003e \u003cp\u003e3.2 Solid-Acid-Based Nanomaterials 60\u003c\/p\u003e \u003cp\u003e3.3 Grafted-Metal-Ions-Based Nanomaterial 65\u003c\/p\u003e \u003cp\u003e3.4 Metal NPs-Based Nanomaterial 67\u003c\/p\u003e \u003cp\u003e3.4.1 Metal NPs Stabilized by Ligands 67\u003c\/p\u003e \u003cp\u003e3.4.2 Metal NPs@Polymers 68\u003c\/p\u003e \u003cp\u003e3.4.3 Metal NPs@Metal Oxides 70\u003c\/p\u003e \u003cp\u003e3.4.4 Metal NPs@Carbonaceous Support 72\u003c\/p\u003e \u003cp\u003e3.4.5 Metal NPs@Siliceous Base Support 74\u003c\/p\u003e \u003cp\u003e3.4.6 Metal NPs@MOF Nanocomposites 77\u003c\/p\u003e \u003cp\u003e3.5 Metal Oxide NPs-Based Nanomaterial 82\u003c\/p\u003e \u003cp\u003e3.6 Summary and Conclusions 83\u003c\/p\u003e \u003cp\u003eReferences 84\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Biocatalysis at Room Temperature 89\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eIvaldo Itabaiana Jr and Rodrigo O. M. A. De Souza\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 89\u003c\/p\u003e \u003cp\u003e4.2 Transaminases 90\u003c\/p\u003e \u003cp\u003e4.2.1 General Features 90\u003c\/p\u003e \u003cp\u003e4.2.2 Transaminase Applications at Room Temperature 90\u003c\/p\u003e \u003cp\u003e4.3 Hydrolases 98\u003c\/p\u003e \u003cp\u003e4.3.1 General Features 98\u003c\/p\u003e \u003cp\u003e4.3.2 Application of Hydrolases at Room Temperature 100\u003c\/p\u003e \u003cp\u003e4.3.2.1 Lipases 100\u003c\/p\u003e \u003cp\u003e4.3.2.2 Aldol Additions 101\u003c\/p\u003e \u003cp\u003e4.3.2.3 Michael Addition 102\u003c\/p\u003e \u003cp\u003e4.3.2.4 Mannich Reaction 102\u003c\/p\u003e \u003cp\u003e4.3.2.5 C-Heteroatom and Heteroatom–Heteroatom Bond Formations 103\u003c\/p\u003e \u003cp\u003e4.3.2.6 Epoxidation 103\u003c\/p\u003e \u003cp\u003e4.3.2.7 Synthesis of Heterocycles 104\u003c\/p\u003e \u003cp\u003e4.3.2.8 Kinetic Resolutions 105\u003c\/p\u003e \u003cp\u003e4.3.3 Cutinases 107\u003c\/p\u003e \u003cp\u003e4.4 Laccases 108\u003c\/p\u003e \u003cp\u003e4.4.1 General Features 108\u003c\/p\u003e \u003cp\u003e4.4.2 Applications of Laccases 110\u003c\/p\u003e \u003cp\u003e4.5 Enzymes in Ionic Liquids 115\u003c\/p\u003e \u003cp\u003e4.5.1 General Features 115\u003c\/p\u003e \u003cp\u003eReferences 125\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Room Temperature Catalysis Enabled by Light 135\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eTimothy Noël\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 135\u003c\/p\u003e \u003cp\u003e5.2 UV Photochemistry 136\u003c\/p\u003e \u003cp\u003e5.3 Visible Light Photoredox Catalysis 139\u003c\/p\u003e \u003cp\u003e5.4 Room Temperature Cross-Coupling Enabled by Light 141\u003c\/p\u003e \u003cp\u003e5.5 Photochemistry and Microreactor Technology –A Perfect Match? 144\u003c\/p\u003e \u003cp\u003e5.6 The Use of Photochemistry in Material Science 146\u003c\/p\u003e \u003cp\u003e5.7 Solar Fuels 149\u003c\/p\u003e \u003cp\u003e5.8 Conclusion 151\u003c\/p\u003e \u003cp\u003eReferences 151\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Mechanochemically Enhanced Organic Transformations 155\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eDavin Tan and Tomislav Frišcic\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 155\u003c\/p\u003e \u003cp\u003e6.2 Mechanochemical Techniques and Mechanisms: Neat versus Liquid-Assisted Grinding (LAG) 156\u003c\/p\u003e \u003cp\u003e6.3 Oxidation and Reduction Using Mechanochemistry 160\u003c\/p\u003e \u003cp\u003e6.3.1 Direct Oxidation of Organic Substrates Using Oxone 160\u003c\/p\u003e \u003cp\u003e6.3.2 Mechanochemical Halogenations Aided by Oxone 162\u003c\/p\u003e \u003cp\u003e6.3.3 Reduction Reactions by Mechanochemistry 163\u003c\/p\u003e \u003cp\u003e6.4 Electrocyclic Reactions: Equilibrium and Templating in Mechanochemistry 165\u003c\/p\u003e \u003cp\u003e6.4.1 The Diels–Alder Reaction: Mechanochemical Equilibrium in Reversible C—C Bond Formation 165\u003c\/p\u003e \u003cp\u003e6.4.2 Photochemical [2+2] Cycloaddition during Grinding: Supramolecular Catalysis and Structure Templating 167\u003c\/p\u003e \u003cp\u003e6.5 Recent Advances in Metal-CatalyzedMechanochemical Reactions 168\u003c\/p\u003e \u003cp\u003e6.5.1 Copper-Catalyzed [2+3] Cycloaddition (Huisgen Coupling) 168\u003c\/p\u003e \u003cp\u003e6.5.2 Olefin Metathesis by Ball Milling 169\u003c\/p\u003e \u003cp\u003e6.5.3 Mechanochemical C—H Bond Activation 170\u003c\/p\u003e \u003cp\u003e6.5.4 Cyclopropanation of Alkenes Using Silver Foil as a Catalyst Source 171\u003c\/p\u003e \u003cp\u003e6.6 New Frontiers in Organic Synthesis Enabled by Mechanochemistry 171\u003c\/p\u003e \u003cp\u003e6.6.1 Synthesis of Active Pharmaceutical Ingredients (APIs) 172\u003c\/p\u003e \u003cp\u003e6.6.2 Reactivity Enabled or Facilitated by Mechanochemistry 173\u003c\/p\u003e \u003cp\u003e6.6.3 Trapping Unstable Reaction Intermediates 175\u003c\/p\u003e \u003cp\u003e6.7 Conclusion and Outlook 176\u003c\/p\u003e \u003cp\u003eAcknowledgments 176\u003c\/p\u003e \u003cp\u003eReferences 176\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Palladium-Catalyzed Cross-Coupling in Continuous Flow at Room andMild Temperature 183\u003cbr\u003e\u003c\/b\u003eChristophe Len\u003c\/p\u003e \u003cp\u003e7.1 Introduction 183\u003c\/p\u003e \u003cp\u003e7.2 Suzuki Cross-Coupling in Continuous Flow 184\u003c\/p\u003e \u003cp\u003e7.3 Heck Cross-Coupling in Continuous Flow 192\u003c\/p\u003e \u003cp\u003e7.4 Murahashi Cross-Coupling in Continuous Flow 199\u003c\/p\u003e \u003cp\u003e7.5 Concluding Remarks 202\u003c\/p\u003e \u003cp\u003eReferences 202\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Catalysis for Environmental Applications 207\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eChangseok Han, Endalkachew Sahle-Demessie, Afzal Shah, Saima Nawaz, Latif-ur-Rahman, Niall B.McGuinness, Suresh C. Pillai, Hyeok Choi, Dionysios, D. Dionysiou, andMallikarjuna N. Nadagouda\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 207\u003c\/p\u003e \u003cp\u003e8.2 Ferrate (FeO42−) forWater Treatment 208\u003c\/p\u003e \u003cp\u003e8.3 Magnetically Separable Ferrite forWater Treatment 209\u003c\/p\u003e \u003cp\u003e8.3.1 Magnetic Nanoparticles 209\u003c\/p\u003e \u003cp\u003e8.3.2 Magnetic Recovery of Materials Used forWater Treatment 211\u003c\/p\u003e \u003cp\u003e8.3.3 Ferrite Photocatalyst forWater Treatment 212\u003c\/p\u003e \u003cp\u003e8.4 UV, Solar, and Visible Light-Activated TiO2 Photocatalysts for Environmental Application 212\u003c\/p\u003e \u003cp\u003e8.5 Catalysis for Remediation of Contaminated Groundwater and Soils 215\u003c\/p\u003e \u003cp\u003e8.5.1 Catalytic Oxidative Pathways 215\u003c\/p\u003e \u003cp\u003e8.5.2 Catalytic Reductive Pathways 217\u003c\/p\u003e \u003cp\u003e8.5.3 Prospects and Limitations 218\u003c\/p\u003e \u003cp\u003e8.6 Novel Catalysis for Environmental Applications 218\u003c\/p\u003e \u003cp\u003e8.6.1 Graphene and Graphene Composites 219\u003c\/p\u003e \u003cp\u003e8.6.2 Perovskites and Perovskites Composites 221\u003c\/p\u003e \u003cp\u003e8.6.3 Graphitic Carbon Nitride (g-C3N4) and g-C3N4 Composites 222\u003c\/p\u003e \u003cp\u003e8.7 Summary and Conclusions 223\u003c\/p\u003e \u003cp\u003eAcknowledgments 224\u003c\/p\u003e \u003cp\u003eDisclaimer 224\u003c\/p\u003e \u003cp\u003eReferences 224\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Future Development in Room-Temperature Catalysis and Challenges in the Twenty-first Century 231\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eFannie P. Y. Lau, R. Luque, and Frank L. Y. Lam\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e\u003cb\u003eCase Study 1: Magnetic Pd Catalysts for Benzyl Alcohol Oxidation to Benzaldehyde 237\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYingying Li, Frank L.-Y. Lam, and Xijun Hu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 237\u003c\/p\u003e \u003cp\u003e1.2 Pd\/MagSBA Magnetic Catalyst for Selective Benzyl Alcohol Oxidation to Benzaldehyde 239\u003c\/p\u003e \u003cp\u003e1.2.1 Results and Discussion 239\u003c\/p\u003e \u003cp\u003e1.2.1.1 Characterization 239\u003c\/p\u003e \u003cp\u003e1.2.1.2 Effect of Reaction Temperature 240\u003c\/p\u003e \u003cp\u003e1.2.1.3 Effect of Pd Loading 241\u003c\/p\u003e \u003cp\u003e1.2.1.4 Recycling Test 246\u003c\/p\u003e \u003cp\u003e1.3 Summary and Conclusions 246\u003c\/p\u003e \u003cp\u003eReferences 247\u003c\/p\u003e \u003cp\u003e\u003cb\u003eCase Study 2: Development of Hydrothermally Stable Functional Materials for Sustainable Conversion of Biomass to Furan Compounds 251\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eAmrita Chatterjee, Xijun Hu, and Frank L.-Y. Lam\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 251\u003c\/p\u003e \u003cp\u003e2.2 Metal–Organic-Framework as a Potential Catalyst for Biomass Valorization 254\u003c\/p\u003e \u003cp\u003e2.3 Xylose Dehydration to Furfural Using Metal–Organic-Framework, MIL-101(Cr) 255\u003c\/p\u003e \u003cp\u003e2.3.1 Xylose Dehydration Catalyzed by Organosilane Coated MIL-101(Cr) 255\u003c\/p\u003e \u003cp\u003e2.3.2 Xylose to Furfural Transformation Catalyzed by Fly-Ash and MIL-101(Cr) Composite 258\u003c\/p\u003e \u003cp\u003e2.3.3 Xylose to Furfural Transformation Catalyzed by Tin Phosphate and MIL-101(Cr) Composite 262\u003c\/p\u003e \u003cp\u003e2.3.4 Role of Acid Sites, Textural Properties and Hydrothermal Stability of Catalyst in Xylose Dehydration Reaction 264\u003c\/p\u003e \u003cp\u003e2.4 Conclusion 267\u003c\/p\u003e \u003cp\u003eReferences 268\u003c\/p\u003e \u003cp\u003eIndex 273\u003c\/p\u003e","brand":"Wiley-VCH Verlag GmbH","offers":[{"title":"Default Title","offer_id":48743119061335,"sku":"9783527338672","price":999.99,"currency_code":"GBP","in_stock":false}]},{"product_id":"early-main-group-metal-catalysis-concepts-and-reactions-9783527344482","title":"Early Main Group Metal Catalysis: Concepts and","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eEarly Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003ePreface xiii\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Introduction to Early Main Group Organometallic Chemistry and Catalysis \u003c\/b\u003e\u003cb\u003e1\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eSjoerd Harder\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 s-Block Organometallics 1\u003c\/p\u003e \u003cp\u003e1.2.1 Short History 1\u003c\/p\u003e \u003cp\u003e1.2.2 Synthesis of Group 1 Organometallics 2\u003c\/p\u003e \u003cp\u003e1.2.3 Synthesis of Group 2 Organometallics 4\u003c\/p\u003e \u003cp\u003e1.2.4 Bonding and Structures of s-Block Organometallics 8\u003c\/p\u003e \u003cp\u003e1.2.5 Dynamics of s-Block Organometallics in Solution 13\u003c\/p\u003e \u003cp\u003e1.2.6 Low-Valent s-Block Chemistry 16\u003c\/p\u003e \u003cp\u003e1.3 s-Block Organometallics in Catalysis 17\u003c\/p\u003e \u003cp\u003e1.3.1 Working Principles in Lewis Acid Catalysis 17\u003c\/p\u003e \u003cp\u003e1.3.2 Working Principles in s-Block Organometallic Catalysis 19\u003c\/p\u003e \u003cp\u003e1.3.3 Substrate Activation by s-Block Metals 21\u003c\/p\u003e \u003cp\u003e1.3.4 Future of Early Main Group Metal Catalysis 23\u003c\/p\u003e \u003cp\u003eList of Abbreviations 24\u003c\/p\u003e \u003cp\u003eReferences 24\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 Polymerization of Alkenes and Polar Monomers by Early Main Group Metal Complexes \u003c\/b\u003e\u003cb\u003e31\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eSjoerd Harder\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 31\u003c\/p\u003e \u003cp\u003e2.2 Alkene Polymerization 32\u003c\/p\u003e \u003cp\u003e2.2.1 Styrene Polymerization 33\u003c\/p\u003e \u003cp\u003e2.2.2 Polymerization of Modified Styrene 40\u003c\/p\u003e \u003cp\u003e2.2.3 Polymerization of Butadiene or Isoprene 43\u003c\/p\u003e \u003cp\u003e2.3 Polymerization of Polar Monomers 45\u003c\/p\u003e \u003cp\u003e2.3.1 Polymerization of Lactides 45\u003c\/p\u003e \u003cp\u003e2.3.2 Copolymerization of Epoxides and CO\u003csub\u003e2\u003c\/sub\u003e 50\u003c\/p\u003e \u003cp\u003e2.4 Conclusions 53\u003c\/p\u003e \u003cp\u003eList of Abbreviations 54\u003c\/p\u003e \u003cp\u003eReferences 54\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Intramolecular Hydroamination of Alkenes \u003c\/b\u003e\u003cb\u003e59\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eSebastian Bestgen and Peter W. Roesky\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 59\u003c\/p\u003e \u003cp\u003e3.2 Hydroamination 60\u003c\/p\u003e \u003cp\u003e3.2.1 Scope 62\u003c\/p\u003e \u003cp\u003e3.3 s-Block Metal Catalysis 64\u003c\/p\u003e \u003cp\u003e3.3.1 General Remarks 64\u003c\/p\u003e \u003cp\u003e3.3.2 Mechanistic Aspects 65\u003c\/p\u003e \u003cp\u003e3.3.3 Group 1-Based Catalysis 68\u003c\/p\u003e \u003cp\u003e3.3.3.1 Concerted Reaction 68\u003c\/p\u003e \u003cp\u003e3.3.3.2 Radical-Mediated Intramolecular Hydroamination 71\u003c\/p\u003e \u003cp\u003e3.3.3.3 Reactions of \u003ci\u003eN\u003c\/i\u003e-Arylhydrazones and Ketoximes 72\u003c\/p\u003e \u003cp\u003e3.3.4 Group 2 Metal-Mediated Catalysis 74\u003c\/p\u003e \u003cp\u003e3.3.5 Group 2-Mediated Asymmetric Cyclohydroamination 83\u003c\/p\u003e \u003cp\u003e3.3.6 Lewis Acidic Metal Cation Catalysis 84\u003c\/p\u003e \u003cp\u003e3.3.7 Miscellaneous 85\u003c\/p\u003e \u003cp\u003e3.4 Outlook 86\u003c\/p\u003e \u003cp\u003eAcknowledgments 87\u003c\/p\u003e \u003cp\u003eList of Abbreviations 87\u003c\/p\u003e \u003cp\u003eReferences 88\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Molecular s-Block Catalysts for Alkene Hydrophosphination and Related Reactions \u003c\/b\u003e\u003cb\u003e93\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYann Sarazin and Jean-François Carpentier\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 93\u003c\/p\u003e \u003cp\u003e4.2 General Considerations 95\u003c\/p\u003e \u003cp\u003e4.3 Hydrophosphination of Alkenes 96\u003c\/p\u003e \u003cp\u003e4.3.1 Precatalysts with Nitrogen-Based Ligands 97\u003c\/p\u003e \u003cp\u003e4.3.2 Precatalysts with Oxygen-Based Ligands 110\u003c\/p\u003e \u003cp\u003e4.4 Hydrophosphination of Carbodiimides 112\u003c\/p\u003e \u003cp\u003e4.5 Miscellaneous Reactions 114\u003c\/p\u003e \u003cp\u003e4.5.1 Hydrophosphinylation of Alkenes and Enones 114\u003c\/p\u003e \u003cp\u003e4.5.2 Hydrophosphonylation of Aldehydes and Ketones 116\u003c\/p\u003e \u003cp\u003e4.6 Summary and Conclusions 117\u003c\/p\u003e \u003cp\u003eList of Abbreviations 118\u003c\/p\u003e \u003cp\u003eReferences 118\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 H—Nand H—P Bond Addition to Alkynes and Heterocumulenes \u003c\/b\u003e\u003cb\u003e123\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eSven Krieck and Matthias Westerhausen\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Introduction 123\u003c\/p\u003e \u003cp\u003e5.2 Hydroamination 124\u003c\/p\u003e \u003cp\u003e5.2.1 Hydroamination with Secondary Amines 125\u003c\/p\u003e \u003cp\u003e5.2.2 Hydroamination with Primary Amines 128\u003c\/p\u003e \u003cp\u003e5.2.3 Proposed Mechanisms for the Hydroamination of Butadiynes 130\u003c\/p\u003e \u003cp\u003e5.3 Hydrophosphanylation (Hydrophosphination) 134\u003c\/p\u003e \u003cp\u003e5.4 Hydrophosphorylation and Hydrophosphonylation 138\u003c\/p\u003e \u003cp\u003e5.5 Summary and Conclusions 143\u003c\/p\u003e \u003cp\u003e5.6 Acknowledgments 146\u003c\/p\u003e \u003cp\u003e5.7 Abbreviations 146\u003c\/p\u003e \u003cp\u003eReferences 146\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Early Main Group Metal-Catalyzed Hydrosilylation of Unsaturated Bonds \u003c\/b\u003e\u003cb\u003e151\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eSjoerd Harder\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 151\u003c\/p\u003e \u003cp\u003e6.2 Historical Development 151\u003c\/p\u003e \u003cp\u003e6.3 Nonprecious Metal Hydrosilylation Catalysts 153\u003c\/p\u003e \u003cp\u003e6.4 C=C Bond Hydrosilylation with s-Block Metal Catalysts 155\u003c\/p\u003e \u003cp\u003e6.5 C=O Bond Hydrosilylation with s-Block Metal Catalysts 161\u003c\/p\u003e \u003cp\u003e6.6 C=N Bond Hydrosilylation with s-Block Metal Catalysts 167\u003c\/p\u003e \u003cp\u003e6.7 Conclusions 170\u003c\/p\u003e \u003cp\u003eReferences 171\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Early Main Group Metal Catalyzed Hydrogenation \u003c\/b\u003e\u003cb\u003e175\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eHeiko Bauer and Sjoerd Harder\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 175\u003c\/p\u003e \u003cp\u003e7.2 Hydrogenation of C\u003cb\u003e=\u003c\/b\u003eC Double Bonds 178\u003c\/p\u003e \u003cp\u003e7.3 Hydrogenation of C\u003cb\u003e=\u003c\/b\u003eN Double Bonds 187\u003c\/p\u003e \u003cp\u003e7.4 Hydrogenation of C\u003cb\u003e=\u003c\/b\u003eO Double Bonds 191\u003c\/p\u003e \u003cp\u003e7.5 Summary and Perspectives 194\u003c\/p\u003e \u003cp\u003eReferences 197\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Alkali and Alkaline Earth Element-Catalyzed Hydroboration Reactions \u003c\/b\u003e\u003cb\u003e201\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eAaron D. Sadow\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction and Overview 201\u003c\/p\u003e \u003cp\u003e8.2 Thermodynamic Considerations 203\u003c\/p\u003e \u003cp\u003e8.2.1 Hydroboration, Hydrosilylation, and Hydrogenation 203\u003c\/p\u003e \u003cp\u003e8.2.2 Thermochemistry of Metal–Oxygen Bonds and Element–Hydrogen Bonds 205\u003c\/p\u003e \u003cp\u003e8.3 Group 1-Catalyzed Hydroboration Reactions 207\u003c\/p\u003e \u003cp\u003e8.3.1 Overview 207\u003c\/p\u003e \u003cp\u003e8.3.2 Base-Catalyzed Hydroborations 207\u003c\/p\u003e \u003cp\u003e8.3.3 Alkali Metal Hydridoborate and Aluminate-Catalyzed Hydroboration 210\u003c\/p\u003e \u003cp\u003e8.4 Group 2-Catalyzed Hydroboration Reactions 214\u003c\/p\u003e \u003cp\u003e8.4.1 Overview 214\u003c\/p\u003e \u003cp\u003e8.4.2 β-Diketiminate Magnesium-Catalyzed Hydroborations 215\u003c\/p\u003e \u003cp\u003e8.4.3 Tris(4,4-dimethyl-2-oxazolinyl)phenylborato Magnesium-Catalyzed Hydroboration of Ester and Amides 217\u003c\/p\u003e \u003cp\u003e8.4.4 Magnesium Triphenylborate-Catalyzed Hydroboration 221\u003c\/p\u003e \u003cp\u003e8.4.5 Supported Catalysts for Hydroboration 221\u003c\/p\u003e \u003cp\u003e8.5 Summary and Conclusions 222\u003c\/p\u003e \u003cp\u003eReferences 222\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Dehydrocoupling and Other Cross-couplings \u003c\/b\u003e\u003cb\u003e225\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eMerle Arrowsmith\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 225\u003c\/p\u003e \u003cp\u003e9.2 Early Main Group-Catalyzed Cross-DHC of Amines and Boranes 228\u003c\/p\u003e \u003cp\u003e9.2.1 Early Stoichiometric Studies with s-Block Elements 228\u003c\/p\u003e \u003cp\u003e9.2.2 s-Block-Catalyzed Cross-dehydrogenative Synthesis of Diaminoboranes 229\u003c\/p\u003e \u003cp\u003e9.2.3 s-Block-Catalyzed DHC of DMAB 231\u003c\/p\u003e \u003cp\u003e9.2.4 Calcium-Catalyzed Dehydrocoupling of \u003ci\u003etert\u003c\/i\u003e-Butylamine Borane 235\u003c\/p\u003e \u003cp\u003e9.2.5 s-Block-Catalyzed DHC of Amines and Monohydroboranes 235\u003c\/p\u003e \u003cp\u003e9.3 s-Block-Catalyzed Cross-DHC of Amines and Silanes 238\u003c\/p\u003e \u003cp\u003e9.3.1 Influence of Precatalysts and Substrates on Reactivity and Selectivity 238\u003c\/p\u003e \u003cp\u003e9.3.2 Mechanistic and Computational Analysis 240\u003c\/p\u003e \u003cp\u003e9.3.3 Application to the Synthesis of Oligo- and Polysilazanes 242\u003c\/p\u003e \u003cp\u003e9.4 Other s-Block-Catalyzed Cross-DHC Reactions 243\u003c\/p\u003e \u003cp\u003e9.4.1 Alkali Metal-Catalyzed DHC of Si—H and O—H Bonds 243\u003c\/p\u003e \u003cp\u003e9.4.2 s-Block-Catalyzed DHC of Si—H and C—H Bonds 243\u003c\/p\u003e \u003cp\u003e9.5 Early Main Group-Mediated Nondehydrogenative Cross-couplings 244\u003c\/p\u003e \u003cp\u003e9.6 Conclusion and Outlook 245\u003c\/p\u003e \u003cp\u003eReferences 246\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 Enantioselective Catalysis with s-Block Organometallics \u003c\/b\u003e\u003cb\u003e251\u003cbr\u003e\u003c\/b\u003e\u003ci\u003ePhilipp Stegner and Sjoerd Harder\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 251\u003c\/p\u003e \u003cp\u003e10.2 Lithium-Based Catalysts 252\u003c\/p\u003e \u003cp\u003e10.2.1 Lithium Catalysts Based on Neutral Chiral Ligands 252\u003c\/p\u003e \u003cp\u003e10.2.2 Lithium Catalysts Based on Monoanionic Chiral Ligands 255\u003c\/p\u003e \u003cp\u003e10.2.3 Lithium Catalysts Based on Dianionic Chiral Ligands 257\u003c\/p\u003e \u003cp\u003e10.3 Potassium-Based Catalysts 259\u003c\/p\u003e \u003cp\u003e10.3.1 Potassium Catalysts Based on Monoanionic Chiral Ligands 260\u003c\/p\u003e \u003cp\u003e10.4 Magnesium-Based Catalysts 262\u003c\/p\u003e \u003cp\u003e10.4.1 Magnesium Catalysts Based on Monoanionic Chiral Ligands 263\u003c\/p\u003e \u003cp\u003e10.4.2 Magnesium Catalysts Based on Dianionic Chiral Ligands 266\u003c\/p\u003e \u003cp\u003e10.5 Calcium-Based Catalysts 269\u003c\/p\u003e \u003cp\u003e10.5.1 Calcium Catalysts Based on Monoanionic Chiral Ligands 269\u003c\/p\u003e \u003cp\u003e10.5.2 Calcium Catalysts Based on Dianionic Chiral Ligands 273\u003c\/p\u003e \u003cp\u003e10.6 Conclusion and Outlook 275\u003c\/p\u003e \u003cp\u003eList of Abbreviations 275\u003c\/p\u003e \u003cp\u003eReferences 276\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Early Main Group Metal Lewis Acid Catalysis \u003c\/b\u003e\u003cb\u003e279\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eMarian Rauser, Sebastian Schröder, and Meike Niggemann\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 279\u003c\/p\u003e \u003cp\u003e11.1.1 Lewis Acidity of s-Block Metal Cations 280\u003c\/p\u003e \u003cp\u003e11.1.2 Interactions with More than One Lewis Base 281\u003c\/p\u003e \u003cp\u003e11.1.3 Counter Anions 282\u003c\/p\u003e \u003cp\u003e11.1.4 Solvation 283\u003c\/p\u003e \u003cp\u003e11.1.5 Solubility and Aggregation 283\u003c\/p\u003e \u003cp\u003e11.1.6 Water Tolerance 284\u003c\/p\u003e \u003cp\u003e11.1.7 Relative Lewis Acid Activity of Alkaline and Alkaline Earth Metals 285\u003c\/p\u003e \u003cp\u003e11.1.8 Hidden Brønsted Acid 287\u003c\/p\u003e \u003cp\u003e11.2 Polarized Carbon–Heteroatom Double Bonds 287\u003c\/p\u003e \u003cp\u003e11.2.1 Carboxylates: Anhydrides and Carbonates 288\u003c\/p\u003e \u003cp\u003e11.2.2 Aldehydes, Ketones, and Formates 289\u003c\/p\u003e \u003cp\u003e11.2.3 α,β-Unsaturated Carbonyl Compounds 291\u003c\/p\u003e \u003cp\u003e11.2.4 Imines and Enamines 292\u003c\/p\u003e \u003cp\u003e11.2.5 Mannich Reactions 294\u003c\/p\u003e \u003cp\u003e11.2.6 Oxidation and Reduction 294\u003c\/p\u003e \u003cp\u003e11.2.7 Donor–Acceptor Cyclopropanes 294\u003c\/p\u003e \u003cp\u003e11.2.8 Diels–Alder Reaction and Cycloaddition 295\u003c\/p\u003e \u003cp\u003e11.3 Activation of Polarized Single Bonds 296\u003c\/p\u003e \u003cp\u003e11.3.1 Opening of Three-Membered Heterocycles 296\u003c\/p\u003e \u003cp\u003e11.3.2 Leaving Groups 297\u003c\/p\u003e \u003cp\u003e11.3.3 Ca\u003csup\u003e2+\u003c\/sup\u003e-Catalyzed Dehydroxylation as a Special Case 299\u003c\/p\u003e \u003cp\u003e11.4 Activation of Unpolarized Double Bonds 305\u003c\/p\u003e \u003cp\u003e11.5 Summary and Conclusions 307\u003c\/p\u003e \u003cp\u003eReferences 307\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Enantioselective Group 2Metal Lewis Acid Catalysis \u003c\/b\u003e\u003cb\u003e311\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eYasuhiro Yamashita, Tetsu Tsubogo, and Shū Kobayashi\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Introduction 311\u003c\/p\u003e \u003cp\u003e12.2 Catalytic Enantioselective Reactions Using Chiral Magnesium Complexes 313\u003c\/p\u003e \u003cp\u003e12.2.1 Chiral Magnesium-Catalyzed Diels–Alder and 1,3-Dipolar Cycloaddition Reactions 313\u003c\/p\u003e \u003cp\u003e12.2.2 Chiral Magnesium-Catalyzed 1,4-Addition Reactions 315\u003c\/p\u003e \u003cp\u003e12.2.3 Chiral Magnesium-Catalyzed Addition Reactions to Carbonyl Compounds 318\u003c\/p\u003e \u003cp\u003e12.2.4 Chiral Magnesium-Catalyzed Addition Reactions with Imines 319\u003c\/p\u003e \u003cp\u003e12.2.5 Chiral Magnesium-Catalyzed Ring-Opening Reactions of Epoxide and Aziridine 321\u003c\/p\u003e \u003cp\u003e12.2.6 Chiral Magnesium-Catalyzed α-Functionalization Reactions of Carbonyl Compounds 323\u003c\/p\u003e \u003cp\u003e12.2.7 Various Chiral Magnesium-Catalyzed Reactions 324\u003c\/p\u003e \u003cp\u003e12.3 Catalytic Enantioselective Reactions Using Chiral Calcium Complexes 324\u003c\/p\u003e \u003cp\u003e12.3.1 Chiral Calcium-Catalyzed Addition Reactions to Carbonyl Compounds 324\u003c\/p\u003e \u003cp\u003e12.3.2 Chiral Calcium-Catalyzed 1,4-Addition Reactions 326\u003c\/p\u003e \u003cp\u003e12.3.3 Chiral Calcium-Catalyzed Addition Reactions with Imines 331\u003c\/p\u003e \u003cp\u003e12.3.4 Chiral Calcium-Catalyzed α-Functionalization Reactions with Carbonyl Compounds 333\u003c\/p\u003e \u003cp\u003e12.3.5 Chiral Calcium-Catalyzed Cycloaddition Reactions 334\u003c\/p\u003e \u003cp\u003e12.3.6 Chiral Calcium-Catalyzed Hydroamination Reactions 334\u003c\/p\u003e \u003cp\u003e12.3.7 Chiral Calcium-Catalyzed Epoxidation Reactions 336\u003c\/p\u003e \u003cp\u003e12.3.8 Chiral Calcium-Catalyzed Aziridine Ring-Opening Reaction 337\u003c\/p\u003e \u003cp\u003e12.4 Catalytic Enantioselective Reactions Using Chiral Strontium Complexes 337\u003c\/p\u003e \u003cp\u003e12.4.1 Chiral Strontium-Catalyzed 1,4-Addition Reactions 337\u003c\/p\u003e \u003cp\u003e12.4.2 Chiral Strontium-Catalyzed Addition Reactions with Imines 338\u003c\/p\u003e \u003cp\u003e12.4.3 Chiral Strontium-Catalyzed Oxime Formation 339\u003c\/p\u003e \u003cp\u003e12.5 Catalytic Enantioselective Reactions Using Chiral Barium Complexes 339\u003c\/p\u003e \u003cp\u003e12.5.1 Chiral Barium-Catalyzed Addition Reactions to Carbonyl Compounds and Imines 339\u003c\/p\u003e \u003cp\u003e12.5.2 Chiral Barium-Catalyzed 1,4-Addition Reactions 340\u003c\/p\u003e \u003cp\u003e12.5.3 Chiral Barium-Catalyzed Diels–Alder Reactions 341\u003c\/p\u003e \u003cp\u003e12.6 Summary and Outlook 341\u003c\/p\u003e \u003cp\u003eReferences 342\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Miscellaneous Reactions \u003c\/b\u003e\u003cb\u003e347\u003cbr\u003e\u003c\/b\u003e\u003ci\u003eMichael S. Hill\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 347\u003c\/p\u003e \u003cp\u003e13.2 Privileged Substrates and s-Block Reactivity 347\u003c\/p\u003e \u003cp\u003e13.3 Reactivity with Multiply Bonded Substrates 351\u003c\/p\u003e \u003cp\u003e13.3.1 Tishchenko Dimerization of Aldehydes 351\u003c\/p\u003e \u003cp\u003e13.3.2 Trimerization of Organic Isocyanates 352\u003c\/p\u003e \u003cp\u003e13.3.3 Hydroalkoxylation of Alkynyl Alcohols 353\u003c\/p\u003e \u003cp\u003e13.3.4 Catalytic Isomerization and C–C Coupling with Terminal Alkynes 354\u003c\/p\u003e \u003cp\u003e13.3.5 Activation and Deoxygenation of C—O Multiple Bonds 358\u003c\/p\u003e \u003cp\u003e13.4 Single-Electron Transfer Steps in s-Block-Centered Catalysis 361\u003c\/p\u003e \u003cp\u003e13.5 “Beyond” Hydrofunctionalization and Dehydrocoupling 363\u003c\/p\u003e \u003cp\u003e13.6 Conclusions and Conjecture 365\u003c\/p\u003e \u003cp\u003eReferences 367\u003c\/p\u003e \u003cp\u003eIndex 373\u003c\/p\u003e","brand":"Wiley-VCH Verlag GmbH","offers":[{"title":"Default Title","offer_id":48743120634199,"sku":"9783527344482","price":98.96,"currency_code":"GBP","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9783527344482.jpg?v=1791481943"},{"product_id":"heterogeneous-photocatalysis-from-fundamentals-to-applications-in-energy-conversion-and-depollution-9783527344642","title":"Heterogeneous Photocatalysis: From Fundamentals","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cp\u003e\u003cb\u003eDiscover the latest research in photocatalysis combined with foundational topics in basic physical and chemical photocatalytic processes\u003c\/b\u003e \u003c\/p\u003e\u003cp\u003eIn \u003ci\u003eHeterogeneous Photocatalysis: From Fundamentals to Applications in Energy Conversion and Depollution\u003c\/i\u003e, distinguished researcher and editor Jennifer Strunk delivers a rigorous discussion of the two main topics in her field—energy conversion and depollution reactions. The book covers topics like water splitting, CO2 reduction, NOx abatement and harmful organics degradation. \u003c\/p\u003e\u003cp\u003eIn addition to the latest research on these topics, the reference provides readers with fundamental information about elementary physical and chemical processes in photocatalysis that are extremely practical in this interdisciplinary field. It offers an excellent overview of modern heterogeneous photocatalysis and combines concepts from different viewpoints to allow researchers with backgrounds as varied as electrochemistry, material science, and semiconductor physics to begin developing solutions with photocatalysis. \u003c\/p\u003e\u003cp\u003eIn addition to subjects like metal-free photocatalysts and photocarrier loss pathways in metal oxide absorber materials for photocatalysis explored with time-resolved spectroscopy, readers will also benefit from the inclusion of: \u003c\/p\u003e\u003cul\u003e\n\u003cli\u003eThorough introductions to kinetic and thermodynamic considerations for photocatalyst design and the logic, concepts, and methods of the design of reliable studies on photocatalysis\u003c\/li\u003e\n\u003cli\u003eDetailed explorations of in-situ spectroscopy for mechanistic studies in semiconductor photocatalysis and the principles and limitations of photoelectrochemical fuel generation\u003c\/li\u003e\n\u003cli\u003eDiscussions of photocatalysis, including the heterogeneous catalysis perspective and insights into photocatalysis from computational chemistry\u003c\/li\u003e\n\u003cli\u003eTreatments of selected aspects of photoreactor engineering and defects in photocatalysis\u003c\/li\u003e\n\u003c\/ul\u003e \u003cp\u003ePerfect for photochemists, physical and catalytic chemists, electrochemists, and materials scientists, \u003ci\u003eHeterogeneous Photocatalysis\u003c\/i\u003e will also earn a place in the libraries of surface physicists and environmental chemists seeking up-to-date information about energy conversion and depollution reactions.\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eKinetic and Thermodynamic Considerations for Photocatalyst Design\u003c\/p\u003e \u003cp\u003eDesign of Reliable Studies on Photocatalysis: Logic, Concepts and Methods\u003c\/p\u003e \u003cp\u003eIn-Situ Spectroscopy for Mechanistic Studies in Semiconductor Photocatalysis\u003c\/p\u003e \u003cp\u003ePrinciples and Limitations of Photoelectrochemical Fuel Generation\u003c\/p\u003e \u003cp\u003ePhotocatalysis - The Heterogeneous Catalysis Perspective\u003c\/p\u003e \u003cp\u003eInsights into Photocatalysis from Computational Chemistry\u003c\/p\u003e \u003cp\u003eSelected Aspects of Photoreactor Engineering\u003c\/p\u003e \u003cp\u003eDefects in photocatalysis\u003c\/p\u003e \u003cp\u003ePhotocarrier Loss Pathways in Metal Oxide Absorber Materials for Photocatalysis Explored with Time-Resolved Spectroscopy: The Case of BiVO\u003csub\u003e4\u003c\/sub\u003e\u003c\/p\u003e \u003cp\u003eMetal-Free Photocatalysts\u003c\/p\u003e \u003cp\u003ePhotocatalytic water splitting: Fundamentals and current concepts\u003c\/p\u003e \u003cp\u003ePhotocatalytic CO\u003csub\u003e2\u003c\/sub\u003e reduction and beyond\u003c\/p\u003e \u003cp\u003ePhotocatalytic NO\u003csub\u003ex\u003c\/sub\u003e Abatement\u003c\/p\u003e \u003cp\u003ePhotoactive Nanomaterials: Applications in Wastewater Treatment and their Environmental Fate\u003c\/p\u003e","brand":"Wiley-VCH Verlag GmbH","offers":[{"title":"Default Title","offer_id":48743120798039,"sku":"9783527344642","price":103.46,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9783527344642.jpg?v=1720064201"},{"product_id":"flavin-based-catalysis-principles-and-applications-9783527348343","title":"Flavin-Based Catalysis: Principles and","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eThe book gives a unique overview of this rapidly developing research field, presenting structures and properties of flavin derivatives as well as their proven application as bioinspired catalysts in various organocatalytic, biocatalytic, and photocatalytic reactions.\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eStructure and properties of flavins\u003c\/p\u003e \u003cp\u003eNatural flavins: occurrence, role and non-canonical chemistry\u003c\/p\u003e \u003cp\u003eSpectral properties of flavins\u003c\/p\u003e \u003cp\u003eModes of flavin-based catalysis\u003c\/p\u003e \u003cp\u003eOrganocatalytic monooxygenations\u003c\/p\u003e \u003cp\u003eFlavin-based supramolecular and coupled catalytic systems\u003c\/p\u003e \u003cp\u003eFlavoprotein monooxygenases and halogenases\u003c\/p\u003e \u003cp\u003eFlavoprotein-dependent bioreduction\u003c\/p\u003e \u003cp\u003eFlavoprotein oxidases\u003c\/p\u003e \u003cp\u003eBenzylic photooxidation by flavins\u003c\/p\u003e \u003cp\u003eNew applications of flavin photocatalysis\u003c\/p\u003e \u003cp\u003eLight-driven flavin-based biocatalysis\u003c\/p\u003e","brand":"Wiley-VCH Verlag GmbH","offers":[{"title":"Default Title","offer_id":48743124042071,"sku":"9783527348343","price":999.99,"currency_code":"GBP","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9783527348343.jpg?v=1791481951"},{"product_id":"co2-conversion-and-utilization-photocatalytic-and-electrochemical-methods-and-applications-9783527352029","title":"CO2 Conversion and Utilization: Photocatalytic","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e\u003cb\u003eCO\u003csub\u003e2\u003c\/sub\u003e Conversion and Utilization\u003c\/b\u003e \u003cp\u003e\u003cb\u003eComprehensive overview of current development of various catalysts in CO\u003csub\u003e2\u003c\/sub\u003e conversion and utilization through photocatalytic and electrochemical methods\u003c\/b\u003e \u003c\/p\u003e\u003cp\u003e\u003ci\u003eCO\u003csub\u003e2\u003c\/sub\u003e Conversion and Utilization \u003c\/i\u003esystematically summarizes the development of CO\u003csub\u003e2\u003c\/sub\u003e photo- and electro-conversion and utilization, especially the reaction mechanism, engineering and technology of testing, and preparation methods and physicochemical properties of various catalytic materials. The rational design and preparation of catalysts, development of characterization technologies, and in-depth understanding of catalytic mechanisms are systematically discussed. \u003c\/p\u003e\u003cp\u003eIn particular, the various parameters influencing the photocatalytic and electrochemical CO\u003csub\u003e2\u003c\/sub\u003e reduction are emphasized. The underlying challenges and perspectives for the future development of efficient catalysts for CO\u003csub\u003e2\u003c\/sub\u003e reduction to specific chemicals and fuels are discussed at the end of the text. \u003c\/p\u003e\u003cp\u003eWritten by a highly qualified author with significant experience in the field, \u003ci\u003eCO\u003csub\u003e2\u003c\/sub\u003e Conversion and Utilization \u003c\/i\u003eincludes information on: \u003c\/p\u003e\u003cul\u003e\n\u003cli\u003eMeasurement systems and parameters for CO\u003csub\u003e2\u003c\/sub\u003e photo\/electro-conversion, CO\u003csub\u003e2\u003c\/sub\u003e photo\/electro-conversion mechanism, and Cu-based and Cu-free metal materials for electrocatalytic CO\u003csub\u003e2\u003c\/sub\u003e reduction\u003c\/li\u003e\n\u003cli\u003eOrganic-inorganic, metal organic framework, and covalent organic framework hybrid materials for CO\u003csub\u003e2\u003c\/sub\u003e photo\/electro-conversion\u003c\/li\u003e\n\u003cli\u003eSingle\/dual-atom catalysts, homogeneous catalysts, and high-entropy alloys for CO\u003csub\u003e2\u003c\/sub\u003e photo\/electro-conversion\u003c\/li\u003e\n\u003cli\u003eSemiconductor composite and carbon-based materials for photocatalytic CO\u003csub\u003e2\u003c\/sub\u003e reduction, novel routes for CO\u003csub\u003e2\u003c\/sub\u003e utilization via metal-CO\u003csub\u003e2\u003c\/sub\u003e batteries, and CO\u003csub\u003e2\u003c\/sub\u003e conversion into long-chain compounds\u003c\/li\u003e\n\u003c\/ul\u003e \u003cp\u003eProviding comprehensive coverage of the subject, \u003ci\u003eCO\u003csub\u003e2\u003c\/sub\u003e Conversion and Utilization \u003c\/i\u003eis of high interest for scientific researchers as well as engineers and technicians in industry, including but not limited to photochemists, electrochemists, environmental chemists, catalytic chemists, chemists in industry, and inorganic chemists.\u003c\/p\u003e\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003e\u003cp\u003ePreface xiii\u003c\/p\u003e \u003cp\u003e\u003cb\u003e1 Measurement Systems and Parameters for CO 2 Photo\/Electro-Conversion 1\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eli li, Zhenwei Zhao, Xinyi Wang, and Zhicheng Zhang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e1.1 Introduction 1\u003c\/p\u003e \u003cp\u003e1.2 The Measurement Systems for CO 2 Photo\/Electro-Conversion 1\u003c\/p\u003e \u003cp\u003e1.2.1 The Measurement Systems of Photocatalytic CO 2 Reduction 1\u003c\/p\u003e \u003cp\u003e1.2.1.1 CO 2 Reduction System Under Liquid-Phase Reaction System 2\u003c\/p\u003e \u003cp\u003e1.2.1.2 CO 2 Reduction System in Gas-Phase Reaction System 2\u003c\/p\u003e \u003cp\u003e1.2.1.3 Detection of CO 2 Reduction Products 3\u003c\/p\u003e \u003cp\u003e1.2.2 The Measurement Systems of Electrocatalytic CO 2 Reduction 3\u003c\/p\u003e \u003cp\u003e1.2.2.1 Electrocatalytic CO 2 Reduction Reaction Test in H-Cell 3\u003c\/p\u003e \u003cp\u003e1.2.2.2 Electrocatalytic CO 2 Reduction Reaction Test in Flow Cell 5\u003c\/p\u003e \u003cp\u003e1.2.2.3 Electrocatalytic CO 2 Reduction Reaction Test in MEA 5\u003c\/p\u003e \u003cp\u003e1.2.3 The Measurement Systems of Photo-Electro-Catalytic CO 2 Reduction 6\u003c\/p\u003e \u003cp\u003e1.2.3.1 Basic Device for Photocatalytic CO 2 Reduction Experiment 6\u003c\/p\u003e \u003cp\u003e1.2.3.2 Other Devices for Photocatalytic CO 2 Reduction 7\u003c\/p\u003e \u003cp\u003e1.2.3.3 Detection of CO 2 Reduction Reaction Products 7\u003c\/p\u003e \u003cp\u003e1.3 The Parameters for CO 2 Photo-Conversion 7\u003c\/p\u003e \u003cp\u003e1.3.1 The Parameters of Photocatalytic CO 2 Reduction 7\u003c\/p\u003e \u003cp\u003e1.3.1.1 Evaluation Parameters of Photocatalytic CO 2 Reduction Activity 8\u003c\/p\u003e \u003cp\u003e1.3.1.2 Evaluation Parameters of Photocatalytic CO 2 Reduction Selectivity 10\u003c\/p\u003e \u003cp\u003e1.3.1.3 Evaluation Parameters of Photocatalytic CO 2 Reduction Stability 10\u003c\/p\u003e \u003cp\u003e1.3.2 The Parameters of Electrocatalytic CO 2 Reduction 10\u003c\/p\u003e \u003cp\u003e1.3.3 The Parameters of Photo-Electro-Catalytic CO 2 Reduction 12\u003c\/p\u003e \u003cp\u003e1.3.3.1 Overpotential 12\u003c\/p\u003e \u003cp\u003e1.3.3.2 Total Photocurrent Density (j ph) and Partial Photocurrent Density (j A) 12\u003c\/p\u003e \u003cp\u003e1.3.3.3 Faraday Efficiency (FE) 13\u003c\/p\u003e \u003cp\u003e1.3.3.4 Solar Energy Conversion Efficiency 13\u003c\/p\u003e \u003cp\u003e1.3.3.5 Apparent Quantum Yield (AQY) 13\u003c\/p\u003e \u003cp\u003e1.3.3.6 Electrochemical Active Area (ECSA) 14\u003c\/p\u003e \u003cp\u003e1.3.3.7 Electrochemical Impedance (EIS) 14\u003c\/p\u003e \u003cp\u003e1.3.3.8 Tafel Slope (Tafel) 14\u003c\/p\u003e \u003cp\u003e1.3.3.9 Photocatalytic Stability 14\u003c\/p\u003e \u003cp\u003eReferences 15\u003c\/p\u003e \u003cp\u003e\u003cb\u003e2 CO 2 Photo\/Electro-Conversion Mechanism 17\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eYalin Guo, Shenghong Zhong, and Jianfeng Huang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e2.1 Introduction 17\u003c\/p\u003e \u003cp\u003e2.2 CO 2 Photo-Conversion Mechanism 18\u003c\/p\u003e \u003cp\u003e2.3 CO 2 Electro-Conversion Mechanism 25\u003c\/p\u003e \u003cp\u003e2.3.1 Thermodynamics of CO 2 Reduction 25\u003c\/p\u003e \u003cp\u003e2.3.2 Pathways of Electrochemical CO 2 Reduction 26\u003c\/p\u003e \u003cp\u003e2.3.2.1 Electrochemical CO 2 Reduction to CO 27\u003c\/p\u003e \u003cp\u003e2.3.2.2 Electrochemical CO 2 Reduction to Formate 28\u003c\/p\u003e \u003cp\u003e2.3.2.3 Electrochemical CO 2 Reduction to Products Beyond CO 29\u003c\/p\u003e \u003cp\u003e2.4 Summary and Perspectives 32\u003c\/p\u003e \u003cp\u003eReferences 32\u003c\/p\u003e \u003cp\u003e\u003cb\u003e3 Cu-Based Metal Materials for Electrocatalytic CO 2 Reduction 37\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eJunjun Li, Yongxia Shi, Man Hou, and Zhicheng Zhang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e3.1 Introduction 37\u003c\/p\u003e \u003cp\u003e3.2 Cu-Based Metal Materials for Electrocatalytic CO 2 Reduction 39\u003c\/p\u003e \u003cp\u003e3.2.1 Cu Materials for Electrocatalytic CO 2 Reduction 39\u003c\/p\u003e \u003cp\u003e3.2.2 Cu-Based Bimetal Materials for Electrocatalytic CO 2 Reduction 40\u003c\/p\u003e \u003cp\u003e3.2.2.1 Cu–Au 40\u003c\/p\u003e \u003cp\u003e3.2.2.2 Cu–Ag 42\u003c\/p\u003e \u003cp\u003e3.2.2.3 Cu–Pd 43\u003c\/p\u003e \u003cp\u003e3.2.2.4 Cu–Sn 44\u003c\/p\u003e \u003cp\u003e3.2.2.5 Cu–Bi 46\u003c\/p\u003e \u003cp\u003e3.2.2.6 Cu–In 46\u003c\/p\u003e \u003cp\u003e3.2.2.7 Cu–Al 49\u003c\/p\u003e \u003cp\u003e3.2.2.8 Cu–Zn 49\u003c\/p\u003e \u003cp\u003e3.2.3 Cu-Based Trimetallic Materials for Electrocatalytic CO 2 Reduction 50\u003c\/p\u003e \u003cp\u003e3.3 Conclusion and Outlook 50\u003c\/p\u003e \u003cp\u003eAcknowledgment 53\u003c\/p\u003e \u003cp\u003eReferences 53\u003c\/p\u003e \u003cp\u003e\u003cb\u003e4 Cu-Free Metal Materials for Electrocatalytic CO 2 Conversion 61\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eZhiqi Huang and Qingfeng Hua\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e4.1 Introduction 61\u003c\/p\u003e \u003cp\u003e4.2 CO-Producing Metals 62\u003c\/p\u003e \u003cp\u003e4.2.1 Au-Based Electrocatalysts 62\u003c\/p\u003e \u003cp\u003e4.2.2 Ag-Based Electrocatalysts 66\u003c\/p\u003e \u003cp\u003e4.2.3 Pd-Based Electrocatalysts 68\u003c\/p\u003e \u003cp\u003e4.2.4 Zn-Based Electrocatalysts 70\u003c\/p\u003e \u003cp\u003e4.3 HCOOH-Producing Metals 72\u003c\/p\u003e \u003cp\u003e4.3.1 Sn-Based Electrocatalysts 72\u003c\/p\u003e \u003cp\u003e4.3.2 Bi-Based Electrocatalysts 76\u003c\/p\u003e \u003cp\u003e4.3.3 In-Based Electrocatalysts 78\u003c\/p\u003e \u003cp\u003eReferences 80\u003c\/p\u003e \u003cp\u003e\u003cb\u003e5 Organic–Inorganic Hybrid Materials for CO 2 Photo\/Electro-Conversion 93\u003cbr\u003e \u003c\/b\u003e\u003ci\u003ePeilei He\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e5.1 Hybrid Materials for Photocatalytic CO 2 Reduction Reaction (co 2 Rr) 93\u003c\/p\u003e \u003cp\u003e5.1.1 Photocatalytic CO 2 RR on p-type Semiconductor\/Molecule Catalysts 93\u003c\/p\u003e \u003cp\u003e5.1.2 Photocatalytic CO 2 RR on Carbon Nitride (C 3 N 4)-supported Molecular Catalysts 95\u003c\/p\u003e \u003cp\u003e5.1.3 Photocatalytic CO 2 RR on Polyoxometalates (POMs)-based Catalysts 97\u003c\/p\u003e \u003cp\u003e5.2 Hybrid Materials for Electrochemical CO 2 RR 98\u003c\/p\u003e \u003cp\u003e5.2.1 Electrochemical CO 2 RR on Carbon-supported Molecular Catalysts 98\u003c\/p\u003e \u003cp\u003e5.2.2 Electrochemical CO 2 RR on TiO 2 -based Hybrid Materials 103\u003c\/p\u003e \u003cp\u003e5.3 Hybrid Materials for Photoelectrochemical (PEC) CO 2 RR 104\u003c\/p\u003e \u003cp\u003e5.4 Challenge and Opportunity 106\u003c\/p\u003e \u003cp\u003eReferences 107\u003c\/p\u003e \u003cp\u003e\u003cb\u003e6 Metal–Organic Framework Materials for CO 2 Photo-\/Electro-Conversion 111\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eBingqing Yao, Xiaoya Cui, and Zhicheng Zhang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e6.1 Introduction 111\u003c\/p\u003e \u003cp\u003e6.2 Photocatalysis 112\u003c\/p\u003e \u003cp\u003e6.2.1 MOFs with Photoactive Organic Ligands 113\u003c\/p\u003e \u003cp\u003e6.2.2 MOFs with Photoactive Metal Nodes 116\u003c\/p\u003e \u003cp\u003e6.2.3 MOF-Based Hybrid System 117\u003c\/p\u003e \u003cp\u003e6.3 Electrocatalysis 119\u003c\/p\u003e \u003cp\u003e6.3.1 MOFs with Active Sites at Organic Ligands 120\u003c\/p\u003e \u003cp\u003e6.3.2 MOFs with Active Sites at Metal Nodes 121\u003c\/p\u003e \u003cp\u003e6.3.3 MOF-Based Hybrid System 125\u003c\/p\u003e \u003cp\u003e6.4 Photoelectrocatalysis 128\u003c\/p\u003e \u003cp\u003e6.5 Conclusion and Outlook 129\u003c\/p\u003e \u003cp\u003eAcknowledgment 130\u003c\/p\u003e \u003cp\u003eReferences 130\u003c\/p\u003e \u003cp\u003e\u003cb\u003e7 Covalent Organic Frameworks for CO 2 Photo\/Electro-Conversion 137\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eTing He\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e7.1 Introduction 137\u003c\/p\u003e \u003cp\u003e7.2 COFs for Photocatalytic CO 2 Reduction 138\u003c\/p\u003e \u003cp\u003e7.2.1 Imine-Linked COFs 138\u003c\/p\u003e \u003cp\u003e7.2.2 Ketoenamine COFs 141\u003c\/p\u003e \u003cp\u003e7.2.3 Carbon–Carbon Double Bond-Linked COFs 145\u003c\/p\u003e \u003cp\u003e7.2.4 Dioxin-Linked COFs 147\u003c\/p\u003e \u003cp\u003e7.2.5 Azine-Linked and Hydrazone-Linked COFs 147\u003c\/p\u003e \u003cp\u003e7.3 COFs for Electrocatalytic CO 2 Reduction 148\u003c\/p\u003e \u003cp\u003e7.3.1 Porphyrin-Based COFs 148\u003c\/p\u003e \u003cp\u003e7.3.2 Phthalocyanine-Based COFs 151\u003c\/p\u003e \u003cp\u003e7.3.3 Other COFs 152\u003c\/p\u003e \u003cp\u003e7.4 Challenges and Perspectives 152\u003c\/p\u003e \u003cp\u003eReferences 154\u003c\/p\u003e \u003cp\u003e\u003cb\u003e8 Single\/Dual-Atom Catalysts for CO 2 Photo\/Electro-Conversion 157\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eHonghui Ou and Yao Wang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e8.1 Introduction 157\u003c\/p\u003e \u003cp\u003e8.2 Synthetic Methods of Single\/Dual-Atom Catalysts 158\u003c\/p\u003e \u003cp\u003e8.2.1 Single-Atom Photocatalysts 158\u003c\/p\u003e \u003cp\u003e8.2.2 Dual-Atom Photocatalysts 160\u003c\/p\u003e \u003cp\u003e8.2.3 Single-Atom Electro-Catalysts 162\u003c\/p\u003e \u003cp\u003e8.2.4 Dual-Atom Electro-Catalysts 164\u003c\/p\u003e \u003cp\u003e8.3 CO 2 Photo-Conversion 165\u003c\/p\u003e \u003cp\u003e8.4 CO 2 Electro-Conversion 169\u003c\/p\u003e \u003cp\u003e8.5 Summary and Perspective 171\u003c\/p\u003e \u003cp\u003eReferences 172\u003c\/p\u003e \u003cp\u003e\u003cb\u003e9 Homogeneous Catalytic CO 2 Photo\/Electro-Conversion 177\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eZhenguo Guo and Houjuan Yang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e9.1 Introduction 177\u003c\/p\u003e \u003cp\u003e9.2 Homogeneous Catalytic CO 2 Electro-Conversion 177\u003c\/p\u003e \u003cp\u003e9.2.1 The Structure Homogeneous Electrocatalytic CO 2 Reduction System 177\u003c\/p\u003e \u003cp\u003e9.2.2 Products in Homogeneous Electrocatalytic CO 2 Reduction 178\u003c\/p\u003e \u003cp\u003e9.2.3 Characterizing the Performance of Molecular Electrocatalysts 178\u003c\/p\u003e \u003cp\u003e9.2.3.1 Selectivity 178\u003c\/p\u003e \u003cp\u003e9.2.3.2 Activity 178\u003c\/p\u003e \u003cp\u003e9.2.3.3 Overpotential (η) 179\u003c\/p\u003e \u003cp\u003e9.2.3.4 Stability 179\u003c\/p\u003e \u003cp\u003e9.2.4 Catalysts for Homogeneous Electrocatalytic CO 2 Reduction 179\u003c\/p\u003e \u003cp\u003e9.3 Homogeneous Photocatalytic CO 2 Reduction 180\u003c\/p\u003e \u003cp\u003e9.3.1 Mechanism of Homogeneous Photocatalytic CO 2 Reduction 180\u003c\/p\u003e \u003cp\u003e9.3.2 Characterizing the Performance of Photocatalysis 181\u003c\/p\u003e \u003cp\u003e9.3.3 Photosensitizers Used in Homogeneous Photocatalytic CO 2 Reduction 181\u003c\/p\u003e \u003cp\u003e9.3.4 Sacrificial Electron Donors in Homogeneous Photocatalytic CO 2 Reduction 181\u003c\/p\u003e \u003cp\u003e9.3.5 Catalysts Used in Homogeneous Photocatalytic CO 2 Reduction 182\u003c\/p\u003e \u003cp\u003e9.4 Summary and Perspective 186\u003c\/p\u003e \u003cp\u003eAcknowledgments 187\u003c\/p\u003e \u003cp\u003eReferences 187\u003c\/p\u003e \u003cp\u003e\u003cb\u003e10 High-Entropy Alloys for CO 2 Photo\/Electro-Conversion 189\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eFengqi Wang, Pei Liu, and Yuchen Qin\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e10.1 Introduction 189\u003c\/p\u003e \u003cp\u003e10.2 Reaction Pathways and Evaluation Parameters of Electrochemical Co 2 Rr 191\u003c\/p\u003e \u003cp\u003e10.2.1 Reaction Pathways of CO 2 RR 191\u003c\/p\u003e \u003cp\u003e10.2.2 Evaluation Parameters of Electrochemical CO 2 RR 192\u003c\/p\u003e \u003cp\u003e10.2.2.1 Faraday Efficiency 192\u003c\/p\u003e \u003cp\u003e10.2.2.2 Current Density 193\u003c\/p\u003e \u003cp\u003e10.2.2.3 Turnover Number (TON) 194\u003c\/p\u003e \u003cp\u003e10.2.2.4 Turnover Frequency (TOF) 194\u003c\/p\u003e \u003cp\u003e10.2.2.5 Overpotential 194\u003c\/p\u003e \u003cp\u003e10.3 Characteristics and Synthesis of HEAs 194\u003c\/p\u003e \u003cp\u003e10.3.1 Characteristics of HEAs 194\u003c\/p\u003e \u003cp\u003e10.3.1.1 The Cocktail Effect 194\u003c\/p\u003e \u003cp\u003e10.3.1.2 The Sluggish Diffusion Effect 195\u003c\/p\u003e \u003cp\u003e10.3.1.3 The High-entropy Effect 195\u003c\/p\u003e \u003cp\u003e10.3.1.4 The Lattice Distortion Effect 195\u003c\/p\u003e \u003cp\u003e10.3.1.5 The Phase Structure 196\u003c\/p\u003e \u003cp\u003e10.3.2 Synthesis of HEAs 196\u003c\/p\u003e \u003cp\u003e10.3.2.1 Top-Down Method 196\u003c\/p\u003e \u003cp\u003e10.3.2.2 Down–Top Method 198\u003c\/p\u003e \u003cp\u003e10.4 High-Entropy Alloys for CO 2 RR 199\u003c\/p\u003e \u003cp\u003e10.5 Summary and Outlook 204\u003c\/p\u003e \u003cp\u003eReferences 205\u003c\/p\u003e \u003cp\u003e\u003cb\u003e11 Semiconductor Composite Materials for Photocatalytic CO 2 Reduction 215\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eShengyao Wang and Bo Jiang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e11.1 Introduction 215\u003c\/p\u003e \u003cp\u003e11.2 TiO 2 -Based Composite Photocatalysts 216\u003c\/p\u003e \u003cp\u003e11.2.1 Mixed-Phase TiO 2 Composites 217\u003c\/p\u003e \u003cp\u003e11.2.2 Metal-Modified TiO 2 218\u003c\/p\u003e \u003cp\u003e11.2.3 Nonmetallic-Modified TiO 2 219\u003c\/p\u003e \u003cp\u003e11.2.4 Organic Photosensitizer-Modified TiO 2 219\u003c\/p\u003e \u003cp\u003e11.2.5 Composited TiO 2 Catalyst 220\u003c\/p\u003e \u003cp\u003e11.3 Metal Oxides\/Hydroxides-Based Composite Photocatalysts 222\u003c\/p\u003e \u003cp\u003e11.3.1 Binary Metal Oxide 222\u003c\/p\u003e \u003cp\u003e11.3.2 Ternary Metal Oxide 222\u003c\/p\u003e \u003cp\u003e11.3.3 Oxide Perovskite 224\u003c\/p\u003e \u003cp\u003e11.3.4 Transition Metal Hydroxide 224\u003c\/p\u003e \u003cp\u003e11.3.5 Layered Double Hydroxides (LDHs) 226\u003c\/p\u003e \u003cp\u003e11.4 Metal Chalcogenides\/Nitrides-Based Composite Photocatalysts 226\u003c\/p\u003e \u003cp\u003e11.4.1 Metal Chalcogenides-Based Composite Photocatalysts 227\u003c\/p\u003e \u003cp\u003e11.4.2 Metal Nitrides-Based Composite Photocatalysts 228\u003c\/p\u003e \u003cp\u003e11.5 c 3 N 4 -Based composite Photocatalysts 229\u003c\/p\u003e \u003cp\u003e11.5.1 Change the Morphology and Structure 230\u003c\/p\u003e \u003cp\u003e11.5.2 Doped Elements and Other Structural Units 231\u003c\/p\u003e \u003cp\u003e11.5.3 Influence of Cocatalyst 232\u003c\/p\u003e \u003cp\u003e11.5.4 Constructing Heterojunction 233\u003c\/p\u003e \u003cp\u003e11.6 MOFs-Derived Composite Photocatalysts 233\u003c\/p\u003e \u003cp\u003e11.6.1 Tunable Frame Structure 234\u003c\/p\u003e \u003cp\u003e11.6.2 High Specific Surface Area Enhances CO 2 Adsorption 234\u003c\/p\u003e \u003cp\u003e11.6.3 MOFs-Derived Composite Photocatalysts 234\u003c\/p\u003e \u003cp\u003e11.7 Nonmetal-Based Composite Photocatalysts 236\u003c\/p\u003e \u003cp\u003e11.7.1 Graphene Oxide-Based Composite Photocatalysts 236\u003c\/p\u003e \u003cp\u003e11.7.2 SiC-Based Composite Photocatalysts 237\u003c\/p\u003e \u003cp\u003e11.7.3 BN-Based Composite Photocatalysts 237\u003c\/p\u003e \u003cp\u003e11.7.4 Black Phosphorus-Based Composite Photocatalysts 238\u003c\/p\u003e \u003cp\u003e11.7.5 COFs-Based Composite Photocatalysts 239\u003c\/p\u003e \u003cp\u003e11.7.6 CMPs-Based Composite Photocatalysts 240\u003c\/p\u003e \u003cp\u003e11.8 Conclusions and Perspectives 240\u003c\/p\u003e \u003cp\u003eReferences 242\u003c\/p\u003e \u003cp\u003e\u003cb\u003e12 Carbon-Based Materials for CO 2 Photo\/Electro-Conversion 251\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eQing Qin and Lei Dai\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e12.1 Advances of Carbon-Based Materials 251\u003c\/p\u003e \u003cp\u003e12.1.1 Heteroatom-Doped Carbon 251\u003c\/p\u003e \u003cp\u003e12.1.2 Metal-Based Carbon Composites 252\u003c\/p\u003e \u003cp\u003e12.1.3 Carbon–Carbon Composites 253\u003c\/p\u003e \u003cp\u003e12.1.4 Pore Construction 254\u003c\/p\u003e \u003cp\u003e12.2 Background of CO 2 Conversion 255\u003c\/p\u003e \u003cp\u003e12.3 EC CO 2 Conversion 256\u003c\/p\u003e \u003cp\u003e12.3.1 Heteroatom-Doped Carbon in EC CO 2 Conversion 257\u003c\/p\u003e \u003cp\u003e12.3.2 Metal-Modified Carbon Materials in EC CO 2 Conversion 259\u003c\/p\u003e \u003cp\u003e12.3.3 Carbon–Carbon Composites in EC CO 2 Conversion 261\u003c\/p\u003e \u003cp\u003e12.3.4 Pore Engineering in EC CO 2 Conversion 262\u003c\/p\u003e \u003cp\u003e12.4 PC CO 2 Reduction 264\u003c\/p\u003e \u003cp\u003e12.4.1 Heteroatom-Doped Carbon in PC CO 2 Conversion 265\u003c\/p\u003e \u003cp\u003e12.4.2 Metal-Based\/Carbon Nanocomposites in PC CO 2 Conversion 266\u003c\/p\u003e \u003cp\u003e12.4.3 Carbon–Carbon Composites in PC CO 2 Conversion 268\u003c\/p\u003e \u003cp\u003e12.5 Carbon-Based Materials in PEC CO 2 Reduction 269\u003c\/p\u003e \u003cp\u003e12.6 Challenge and Opportunity 270\u003c\/p\u003e \u003cp\u003eReferences 272\u003c\/p\u003e \u003cp\u003e\u003cb\u003e13 Metal–CO 2 Batteries: Novel Routes for CO 2 Utilization 283\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eXiangyu Zhang and Le Yu\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e13.1 Introduction 283\u003c\/p\u003e \u003cp\u003e13.2 The Mechanism for Metal–CO 2 Electrochemistry 284\u003c\/p\u003e \u003cp\u003e13.2.1 Discharge\/Charge Mechanisms of Li–CO 2 Batteries 284\u003c\/p\u003e \u003cp\u003e13.2.1.1 Discharge Mechanisms of Pure Li–CO 2 Batteries 284\u003c\/p\u003e \u003cp\u003e13.2.1.2 Charge Mechanisms of Pure Li–CO 2 Batteries 285\u003c\/p\u003e \u003cp\u003e13.2.2 Discharge\/Charge Mechanisms of Zn–CO 2 Batteries 286\u003c\/p\u003e \u003cp\u003e13.3 The Electrocatalysts for Metal–CO 2 Batteries 286\u003c\/p\u003e \u003cp\u003e13.3.1 Carbonaceous Materials 286\u003c\/p\u003e \u003cp\u003e13.3.2 Noble Metal-based Materials and Transition Metal-based Materials 287\u003c\/p\u003e \u003cp\u003e13.4 The Electrolytes for Metal–CO 2 Batteries 290\u003c\/p\u003e \u003cp\u003e13.4.1 Nonaqueous Aprotic Liquid Electrolytes for Pure Li–CO 2 Electrochemistry 290\u003c\/p\u003e \u003cp\u003e13.4.2 Solid-State Electrolytes for Pure Li–CO 2 Electrochemistry 290\u003c\/p\u003e \u003cp\u003e13.5 Conclusion and Outlook 292\u003c\/p\u003e \u003cp\u003eReferences 293\u003c\/p\u003e \u003cp\u003e\u003cb\u003e14 CO 2 Conversion into Long-Chain Compounds 297\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eTingting Zheng and Chuan Xia\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e14.1 Introduction 297\u003c\/p\u003e \u003cp\u003e14.2 Photobiochemical Synthesis (PBS) 299\u003c\/p\u003e \u003cp\u003e14.2.1 Principles in Designing the PBS System 299\u003c\/p\u003e \u003cp\u003e14.2.2 Multicarbon Compounds Produced from PBS 301\u003c\/p\u003e \u003cp\u003e14.2.3 Challenges and Prospects for PBS 304\u003c\/p\u003e \u003cp\u003e14.3 Microbial Electrosynthesis (MES) 306\u003c\/p\u003e \u003cp\u003e14.3.1 Extracellular Electron Transfer (EET) 306\u003c\/p\u003e \u003cp\u003e14.3.2 Approaches to Optimize MES 309\u003c\/p\u003e \u003cp\u003e14.3.2.1 Metabolic Pathways 309\u003c\/p\u003e \u003cp\u003e14.3.2.2 Metabolic Engineering 309\u003c\/p\u003e \u003cp\u003e14.3.2.3 Culture 311\u003c\/p\u003e \u003cp\u003e14.3.2.4 Biocathode 312\u003c\/p\u003e \u003cp\u003e14.3.3 Multicarbon Products Derived from MES 313\u003c\/p\u003e \u003cp\u003e14.3.4 The Status Quo and Challenges of MES 316\u003c\/p\u003e \u003cp\u003e14.4 Decoupling Biotic and Abiotic Processes 318\u003c\/p\u003e \u003cp\u003e14.5 Conclusions and Perspectives 322\u003c\/p\u003e \u003cp\u003eReferences 324\u003c\/p\u003e \u003cp\u003e\u003cb\u003e15 Conclusions and Perspectives 335\u003cbr\u003e \u003c\/b\u003e\u003ci\u003eHaiqing Wang\u003c\/i\u003e\u003c\/p\u003e \u003cp\u003e15.1 New CO 2 RR Catalyst 335\u003c\/p\u003e \u003cp\u003e15.2 New CO 2 RR Mechanism 336\u003c\/p\u003e \u003cp\u003e15.3 Industrial CO 2 RR Perspectives 337\u003c\/p\u003e \u003cp\u003eIndex 339\u003c\/p\u003e","brand":"Wiley-VCH Verlag GmbH","offers":[{"title":"Default Title","offer_id":48743126761815,"sku":"9783527352029","price":999.99,"currency_code":"GBP","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9783527352029.jpg?v=1720064227"},{"product_id":"iridium-catalysis-9783642153334","title":"Iridium Catalysis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eFrom the contents: Robert H Crabtree: Introduction and History. - Montserrat Diéguez, Oscar Pàmies and Carmen Claver: Iridium-catalysed hydrogenation using phosphorous ligands. - David H. Woodmansee and Andreas Pfaltz: Iridium Catalyzed Asymmetric Hydrogenation of Olefins with Chiral N,P and C,N Ligands. - Ourida Saidi and Jonathan M J Williams: Iridium-catalyzed Hydrogen Transfer Reactions. - John F. Bower and Michael J. Krische: Formation of C-C Bonds via Iridium Catalyzed Hydrogenation and Transfer Hydrogenation. - Jongwook Choi, Alan S. Goldman: Ir-Catalyzed Functionalization of CH Bonds. - Mark P. Pouy and John F. Hartwig: Iridium-Catalyzed Allylic Substitution. - Daniel Carmona and Luis A. Oro: Iridium-catalyzed 1.3-dipolar cycloadditions.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTrade Review\u003c\/b\u003e\u003cbr\u003e\u003cp\u003eFrom the reviews:\u003c\/p\u003e“Chapters cover a range of types of reactions … that are of strong interest in organic synthesis, and provide extensive up-to-date coverage of both the scope and limitations of the catalysts. … Overall, ‘Iridium Catalysis’ will serve as a useful up-to-date resource for both those entering the field and those experienced chemists who may not be aware of the advances that have been made. … Readers will be stimulated to find new applications for iridium in catalysis after they examine this book.” (William D. Jones, Platinum Metals Review, Vol. 56 (1), 2012)\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eRobert H Crabtree: Introduction and History.- Montserrat Diéguez, Oscar Pàmies and Carmen Claver: Iridium-catalysed hydrogenation using phosphorous ligands.- David H. Woodmansee and Andreas Pfaltz: Iridium Catalyzed Asymmetric Hydrogenation of Olefins with Chiral N,P and C,N Ligands.- Ourida Saidi and Jonathan M J Williams: Iridium-catalyzed Hydrogen Transfer Reactions.- John F. Bower and Michael J. Krische: Formation of C-C Bonds via Iridium Catalyzed Hydrogenation and Transfer Hydrogenation.- Jongwook Choi, Alan S. Goldman: Ir-Catalyzed Functionalization of CH Bonds.- Mark P. Pouy and John F. Hartwig: Iridium-Catalyzed Allylic Substitution.- Luis A. Oro and Daniel Carmona: Iridium-catalysed 1.3-dipolar cycloadditions.","brand":"Springer-Verlag Berlin and Heidelberg GmbH \u0026 Co. KG","offers":[{"title":"Default Title","offer_id":48743134232919,"sku":"9783642153334","price":187.49,"currency_code":"GBP","in_stock":false}]},{"product_id":"topics-in-enantioselective-catalysis-recent-achievements-and-future-challenges-9789811248429","title":"Topics In Enantioselective Catalysis: Recent","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis book illustrates the broad field of enantioselective catalysis by highlighting a few topics, out of myriads, with the double aim to typify selected synthetic achievements and future challenges. Eleven research groups have highlighted topics of interest in either organo- or organometallic catalysis, related to their own expertise. For mature fields, these short chapters, far from being exhaustive, show updated overviews including major recent advances and disclose a few prospects. Other chapters focus on upcoming topics in enantioselective catalysis, i.e. on classes of reactions or families of catalysts that are expected to provide appealing synthetic tools when suitably mastered. For all these areas, recent studies demonstrate highly promising perspectives.","brand":"World Scientific Publishing Co Pte Ltd","offers":[{"title":"Default Title","offer_id":48743282934103,"sku":"9789811248429","price":130.5,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9789811248429.jpg?v=1720064913"},{"product_id":"nanoalloys-from-theory-to-applications-9780854041190","title":"Nanoalloys From Theory to Applications","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eIn this exciting new title all aspects of nanoalloys are explored, including synthesis, characterisation, theory and simulation, property measurements and technological applications. Nanoalloys are of great interest due to their unique structures and properties which are distinct from those of the pure elemental clusters. They are used in a wide range of applications and their chemical and physical properties can be tuned by varying composition, atomic ordering, or clusters. This book will be of interest to academics working at the interfaces between chemistry, materials, physics and nanoscience, and to those working in the nanotechnology, catalysis and optoelectronics areas of industry.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eNanoalloys: tuning properties and characteristics through size and composition A study of bimetallic Cu-Ag, Au-Ag and Pd-Ag clusters adsorbed on a double-vacancy-defected MgO(100) terrace Global optimisation and growth simulation of AuCu clusters Mechanical properties of bimetallic crystalline and nanostructured nanowires Solid-solution precursor to melting in onion-ring Pd-Pt nanoclusters: a case of second-order-like phase change? Atomistic computer simulations on the generation of bimetallic nanoparticles Dynamical equilibrium in nanoalloys","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48884779188567,"sku":"9780854041190","price":197.6,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9780854041190.jpg?v=1791468092"},{"product_id":"heterogeneous-catalysts-design-applications-research-insights-9781536102888","title":"Heterogeneous Catalysts: Design, Applications \u0026","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48886048260439,"sku":"9781536102888","price":92.79,"currency_code":"GBP","in_stock":false}]},{"product_id":"introduction-to-non-linear-kinetics-in-heterogeneous-catalysis-9781560728191","title":"Introduction to Non-Linear Kinetics in","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis book comprises seven chapters. The first chapter addresses a phenomenological approach to the concept ''reaction rate'', which views the complex reaction as a single unit whose progress if judged from measurements of the formation rates of the reaction participants; it also sets forth the main strategies by which to determine the rates of heterogeneous catalytic reactions. Another approach, a mechanistic one, relying upon the reaction mechanisms considered in the second chapter that has recourse to the Horiuti-Temkin complex reaction kinetics theory and the elementary statement of the graph method application in chemical kinetics. The third, fourth and fifth chapters consistently expound the philosophy of the steady state multiplicity, auto-oscillations, and the reciprocal effect of competitive catalytic reactions. The sixth and seventh chapters concentrate on the kinetics of some pragmatically important heterogeneous and heterogeneous-homogeneous catalytic reactions. Most results, presented in these chapters were obtained in the authors'' laboratories.","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48886331998551,"sku":"9781560728191","price":103.19,"currency_code":"GBP","in_stock":false}]},{"product_id":"progress-in-catalysis-research-9781594544415","title":"Progress in Catalysis Research","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48886520774999,"sku":"9781594544415","price":999.99,"currency_code":"GBP","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781594544415.jpg?v=1722540433"},{"product_id":"new-developments-in-catalysis-research-9781594544408","title":"New Developments in Catalysis Research","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48886520840535,"sku":"9781594544408","price":143.24,"currency_code":"GBP","in_stock":false}]},{"product_id":"leading-edge-catalysis-research-9781594544965","title":"Leading Edge Catalysis Research","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThe chemical or biological process whereby the presence of an external compound, a catalyst, serves as an agent to cause a chemical reaction to occur or to improve reaction performance without altering the external compound. Catalysis is a very important process from an industrial point of view since the production of most industrially important chemicals involve catalysis. Catalysis research is a major field in applied science, and involves many fields of chemistry and physics. The new book brings together leading research in this vibrant field.","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48886521921879,"sku":"9781594544965","price":999.99,"currency_code":"GBP","in_stock":false}]},{"product_id":"catalysis-research-at-the-cutting-edge-9781594545122","title":"Catalysis Research at the Cutting Edge","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThe chemical or biological process whereby the presence of an external compound, a catalyst, serves as an agent to cause a chemical reaction to occur or to improve reaction performance without altering the external compound. Catalysis is a very important process from an industrial point of view since the production of most industrially important chemicals involve catalysis. Research into catalysis is a major field in applied science, and involves many fields of chemistry and physics. The new book brings together leading research in this vibrant field.","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48886522282327,"sku":"9781594545122","price":146.24,"currency_code":"GBP","in_stock":false}]},{"product_id":"trends-in-catalysis-research-9781594546594","title":"Trends in Catalysis Research","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThe chemical or biological process whereby the presence of an external compound, a catalyst, serves as an agent to cause a chemical reaction to occur or to improve reaction performance without altering the external compound. Catalysis is a very important process from an industrial point of view since the production of most industrially important chemicals involve catalysis. Research into catalysis is a major field in applied science, and involves many fields of chemistry and physics. The book brings together leading research in this vibrant field.","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48886526673239,"sku":"9781594546594","price":999.99,"currency_code":"GBP","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781594546594.jpg?v=1722540461"},{"product_id":"focus-on-catalysis-research-9781594548109","title":"Focus on Catalysis Research","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThe chemical or biological process whereby the presence of an external compound, a catalyst, serves as an agent to cause a chemical reaction to occur or to improve reaction performance without altering the external compound. Catalysis is a very important process from an industrial point of view since the production of most industrially important chemicals involve catalysis. Research into catalysis is a major field in applied science, and involves many fields of chemistry and physics. The new book brings together leading research in this vibrant field.","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48886530998615,"sku":"9781594548109","price":173.24,"currency_code":"GBP","in_stock":false}]},{"product_id":"frontiers-in-catalysis-research-9781594549021","title":"Frontiers in Catalysis Research","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThe chemical or biological process whereby the presence of an external compound, a catalyst, serves as an agent to cause a chemical reaction to occur or to improve reaction performance without altering the external compound. Catalysis is a very important process from an industrial point of view since the production of most industrially important chemicals involve catalysis. Research into catalysis is a major field in applied science, and involves many fields of chemistry and physics. The new book brings together leading research in this vibrant field.","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48886534734167,"sku":"9781594549021","price":122.99,"currency_code":"GBP","in_stock":false}]},{"product_id":"new-topics-in-catalysis-research-9781600212864","title":"New Topics in Catalysis Research","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48886590767447,"sku":"9781600212864","price":162.74,"currency_code":"GBP","in_stock":false}]},{"product_id":"asymmetric-heterogeneous-supported-catalysis-use-of-nitrogen-containing-ligands-9781616686802","title":"Asymmetric Heterogeneous Supported Catalysis: Use","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003e","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48886877421911,"sku":"9781616686802","price":39.74,"currency_code":"GBP","in_stock":false}]},{"product_id":"fundamentals-of-photocatalysis-9781685073749","title":"Fundamentals of Photocatalysis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eIn chemistry, photocatalysis refers to the acceleration of a photoreaction in the presence of a catalyst. Various aspects and applications of this process are described in the six chapters of this book. Chapter One addresses the reduction and oxidation of heavy metals by the photocatalytic process to produce less toxic forms, thus reducing pollution. Chapter Two reviews some issues of photocatalytic reactions which may have been overlooked in other reports. Chapter Three deals with the utilisation of ZnO-CdO nanoblocks as adsorbent and efficient solar photocatalysts towards brilliant cresol blue degradation. Chapter Four explains heterogeneous photocatalysis through the use of titanium and tungsten oxide nanostructures. Chapter Five reports the fabrication and evaluation of TiO2 nanowires supported on graphene and sensitised with Ag in a unique hierarchical three-dimensional sandwich structure. Lastly, Chapter Six provides an overview of recent achievements in C-N bond formation reactions triggered by visible light-induced DDQ-photoredox catalysis.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003ePreface; Oxidation and Reduction of Heavy Metals by Photocatalytic Processes; Peculiarities of the Reactions on Particulate Photocatalysts; ZnO-CdO Nanoblocks: Utilization as Adsorbent and Efficient Solar Photo-Catalyst towards Brilliant Cresol Blue Degradation; Heterogeneous Photocatalysis Explained through the Use of Titanium and Tungsten Oxide Nanostructures; Designing an Enhanced Visible-Light Activated Hierarchical Three-Dimensional Ag\/TIO2 Nanowires\/Graphene Sandwich Photocatalyst; Visible Light-Mediated DDQ Photoredox-Catalyzed C-N Bond Formation Reactions: A Review; Index.","brand":"Nova Science Publishers Inc","offers":[{"title":"Default Title","offer_id":48887494443351,"sku":"9781685073749","price":72.24,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781685073749.jpg?v=1791476394"},{"product_id":"metal-nanoparticles-for-catalysis-advances-and-applications-9781782620334","title":"Metal Nanoparticles for Catalysis: Advances and","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eCatalysis is a central topic in chemical transformation and energy conversion. Thanks to the spectacular achievements of colloidal chemistry and the synthesis of nanomaterials over the last two decades, there have also been significant advances in nanoparticle catalysis.   Catalysis on different metal nanostructures with well-defined structures and composition has been extensively studied. Metal nanocrystals synthesized with colloidal chemistry exhibit different catalytic performances in contrast to metal nanoparticles prepared with impregnation or deposition precipitation. Additionally, theoretical approaches in predicting catalysis performance and understanding catalytic mechanism on these metal nanocatalysts have made significant progress.   Metal Nanoparticles for Catalysis is a comprehensive text on catalysis on Nanoparticles, looking at both their synthesis and applications. Chapter topics include nanoreactor catalysis; Pd nanoparticles in C-C coupling reactions; metal salt-based gold nanocatalysts; theoretical insights into metal nanocatalysts; and nanoparticle mediated clock reaction.   This book bridges the gap between nanomaterials synthesis and characterization, and catalysis. As such, this text will be a valuable resource for postgraduate students and researchers in these exciting fields.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eIntroduction; Nanocatalysis: Definition and Case Studies; Strategies to Fabricate Nanostructured Colloidal and Supported Metal Nanoparticles and Their Efficient Catalytic Applications; Organometallic Approach for the Synthesis of Noble Metal Nanoparticles: Towards Application in Colloidal and Supported Nanocatalysis; Nickel Nanoparticles in the Transfer Hydrogenation of Functional Groups; Ammonium Surfactant-capped Rh(0) Nanoparticles for Biphasic Hydrogenation; Pd Nanoparticles in C-C Coupling Reactions; Metal Salt-based Gold Nanocatalysts; Catalysis with Colloidal Metallic Hollow Nanostructures: Cage Effect; Nanoreactor Catalysis; Theoretical Insights into Metal Nanocatalysts; Nanoparticle Mediated Clock Reaction: A Redox Phenomena; Porous Cryptomelane Type Manganese Oxide Octahedral Molecular Sieves (OMS-2): Synthesis, Characterization and Applications in Catalysis;","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887689380183,"sku":"9781782620334","price":137.75,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781782620334.jpg?v=1791476894"},{"product_id":"photocatalysis-fundamentals-and-perspectives-9781782620419","title":"Photocatalysis: Fundamentals and Perspectives","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eCombining the basic concepts of photocatalysis with the synthesis of new catalysts, reactor and reaction engineering, this book provides a comprehensive resource on the topic. The book introduces the fundamental aspects of photocatalysis including the role of surface chemistry and understanding the chemistry of photocatalytic processes before exploring the theory and experimental studies of charge carrier dynamics. Specific chapters then cover new materials for the degradation of organics; water splitting and CO2 reduction; as well as reactor and reaction engineering. Researchers new to this discipline can learn the first principles, whilst experienced researchers can gain further information about aspects in photocatalysis beyond their area of expertise. Together with Photocatalysis: Applications, these volumes provide a complete overview to photocatalysis.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003ePhotoelectrochemistry: From Basic Principles to Photocatalysis; Understanding the Chemistry of Photocatalytic Processes; Current Issues Concerning the Mechanism of Pristine TiO2 Photocatalysis and the Effects on Photonic Crystal Nanostructures; Specificity in Photocatalysis; Photoexcitation in Pure and Modified Semiconductor Photocatalysts; New Concepts in Photocatalysis; Kinetic Processes in the Presence of Photogenerated Charge Carriers; Traps and Interfaces in Photocatalysis: Model Studies on TiO2 Particle Systems; Interplay Between Physical and Chemical Events in Photoprocesses in Heterogeneous Systems; New Materials Outline; New Materials for Degradation of Organics; New Materials for Water Splitting; New Materials for CO2 Reduction; Fundamentals of Radiation Transport in Absorbing Scattering Media; Photocatalytic Reactor Design; Photocatalytic Reactor Modeling.","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887689544023,"sku":"9781782620419","price":170.05,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781782620419.jpg?v=1791476894"},{"product_id":"dienamine-catalysis-for-organic-synthesis-9781782620907","title":"Dienamine Catalysis for Organic Synthesis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eIn the past decade a new era in asymmetric catalysis has been realised by the discovery of L-proline induced chiral enamines from carbonyls. Inspired by this, researchers have developed many other primary catalytic species in situ, more recently secondary catalytic species such as aminals have been identified for use in asymmetric synthesis.   High-yielding asymmetric synthesis of bioactive and natural products through mild catalysis is an efficient approach in reaction engineering. In the early days, synthetic chemists mainly focused on the synthesis of complex molecules, with less attention on the reaction efficiency and eco-friendly conditions. Recent investigations have been directed towards the development of atom economy, eco-friendly and enantioselective synthesis for more targeted and efficient synthesis.   Building on the momentum of this rapidly expanding research area, Dienamine Catalysis for Organic Synthesis will provide a comprehensive introduction, from the preformed species, in situ generation and onto their applications in the synthesis of bioactive molecules and natural products.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eIntroduction to Dienamine Chemistry; Synthesis and Applications of Preformed Dienamines; Barbas Dienamines (2-Aminobuta-1,3-dienes): Scope and Applications; Ramachary’s Dienamines (Push-Pull Dienamines): In Situ Generation and Applications; Serebryakov-Jorgensen Dienamines (1-Aminobuta-1,3-dienes): Different In Situ Generation Methods and Applications in [4+2]-Cycloadditions; Serebryakov-Jorgensen Dienamines (1-Aminobuta-1,3-dienes): Different In Situ Generation Methods and Applications in [2+2]-, [3+2]- and a Few Other Cycloadditions; Asymmetric-Selective and Remote -Selective Functionalization of Enals and Enones through Serebryakov-Jorgensen Dienamines (1-Aminobuta-1,3-dienes); Applications of Serebryakov-Jorgensen Dienamines (1-Aminobuta-1,3-dienes) in Domino or Cascade Reactions; Aminoenyne (2-Aminobuta-1,3-enyne) Catalysis: In Situ Generation and Synthetic Applications in Organic Reactions; Trienamine catalyzed stereoselective cycloadditions and other remote functionalizations of polyconjugated enals\/enones; Tetraenamine catalyzed stereoselective cycloadditions of polyunsaturated carbonyl compounds","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887690166615,"sku":"9781782620907","price":141.55,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781782620907.jpg?v=1791476896"},{"product_id":"heterocycles-from-double-functionalized-arenes-transition-metal-catalyzed-coupling-reactions-9781782621362","title":"Heterocycles from Double-Functionalized Arenes:","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThe efficient synthesis of heterocycles has become one of the main branches in organic chemistry due to their use in the synthesis of natural products and pharmaceuticals. Current sythentic strategies based on C-H activation methodologies are met with many problems like harsh reaction conditions and low reaction efficiency. Double functionalized chemicals offer a perfect alternative for the synthesis of heterocycles.    Heterocycles from Double-Functionalized Arenes starts with a short discussion on the importance of heterocycles and a brief introduction on the preparation of double-functionalized arenes. Specific chapters then look at five-membered heterocycles synthesis, six-membered heterocycles synthesis and macroheterocycles synthesis.   This is the first book dedicated to the topic of transition metal catalyzed coupling reactions of double functionalized arenes in heterocycle synthesis and can be used as a handbook for senior researchers and as an introduction for organic chemistry students.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eIntroduction; Five-membered heterocycles synthesis; Six-membered heterocycles synthesis; Macroheterocycles synthesis; Conclusion and outlook;","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887690527063,"sku":"9781782621362","price":170.05,"currency_code":"GBP","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781782621362.jpg?v=1791476897"},{"product_id":"biocatalysis-an-industrial-perspective-9781782626190","title":"Biocatalysis: An Industrial Perspective","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eImplementing biocatalytic strategies in an industrial setting at a commercial scale is a challenging task, necessitating a balance between industrial need against economic viability. With invited contributions from small and large-scale chemical and pharmaceutical companies, this book bridges the gap between academia and industry. Contributors discuss current processes, types of biocatalysts and improvements, industrial motivation and key aspects to economically succeed. With its focus on industry related issues, this book will be a useful tool for future research by both practitioners and academics.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eAn Appreciation of Biocatalysis in the Swiss Manufacturing Environment; Biocatalysis - A greener alternative in synthetic chemistry; Biocatalysis synthesis of small molecules – Past, present and future; EntreChem: Building a sustainable business case in biotechnology: from biocatalysis to synthetic biology; Bristol-Myers Squibb: Preparation of chiral intermediates for the development of drugs and API's; Johnson Matthey: A technology provider perspective to biocatalysis in the fine chemicals industry; EnzymeWorks: Recent advance in enzyme engineering for chemical synthesis; Almac: Scalable reduction and oxidation catalysis using ene-reductase enzymes; GSK: Biocatalyst discovery and optimization; PETROBRAS: Efforts on biocatalysis for fuels and chemicals production; Metgen: Value from Wood – Enzymatic Solutions; LentiKat’s: Industrial Biotechnology, Experiences and Visions; EnginZyme: Universal Enzyme Immobilization; Cross-linked Enzyme Aggregates (CLEAs): from Concept to Industrial Biocatalyst; SynBiocat: Protein purification, immobilization and continuous-flow processes; Microvi: MicroNiche EngineeringTM for Biocatalysis in the Water and Chemical Industries; Nofima: Peptide recovery and commercialization by enzymatic hydrolysis of marine biomass; CO2 Solutions: A biomimetic approach to mitigate CO2 Emissions – The use of Carbonic Anhydrase in an \"Industrial Lung\"","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887692329303,"sku":"9781782626190","price":170.05,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781782626190.jpg?v=1791476903"},{"product_id":"modern-biocatalysis-advances-towards-synthetic-biological-systems-9781782627265","title":"Modern Biocatalysis: Advances Towards Synthetic","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThe synergy between synthetic biology and biocatalysis is emerging as an important trend for future sustainable processes. This book reviews all modern and novel techniques successfully implemented in biocatalysis, in an effort to provide better performing enzymatic systems and novel biosynthetic routes to (non-)natural products. This includes the use of molecular techniques in protein design and engineering, construction of artificial metabolic pathways, and application of computational methods for enzyme discovery and design. Stress is placed on current ‘hot’ topics in biocatalysis, where recent advances in research are defining new grounds in enzyme-catalyzed processes. With contributions from leading academics around the world, this book makes a ground-breaking contribution to this progressive field and is essential reading for graduates and researchers investigating (bio)catalysis, enzyme engineering, chemical biology, and synthetic biology.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eGenome Mining for Enzyme Discovery; Exploiting Natural Diversity for Industrial Enzymatic Applications; Artificial Metalloenzymes; Computational Enzyme Design: Successes, Challenges, and Future Directions; Computational Techniques for Efficient Biocatalysis; Modulating Enzyme Activity via Incorporation of Non-canonical Amino Acids; Enhancing Enzymatic Performance via Restricted Sequence Space Approaches; Customizing Transcription-factor Biosensors for Modern Biotechnology; Exploiting Biosynthetic Pathways in Fungi: Opportunities for Enhanced or Novel Production; Engineering Enzymes for Natural Product Biosynthesis and Diversification; Impact of Synthetic Biology on Secondary Metabolite Biosynthesis; Self-contained Biocatalysts; Designing Multi-enzymatic Systems for the Preparation of Optically Active Molecules; Artificial Biocatalytic Cascades to Alcohols and Amines; Emerging Fields in One-pot Multi-step Synthesis with Combined Chemo- and Bio-catalysts: Sequential- and Domino-type Process Concepts as well as Compartmentation Strategies; Technical Biocatalysis; Biocatalytic Process Engineering; Enzymes for Detection and Decontamination of Chemical Warfare Agents","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887692591447,"sku":"9781782627265","price":141.55,"currency_code":"GBP","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781782627265.jpg?v=1791476905"},{"product_id":"alternative-catalytic-materials-carbides-nitrides-phosphides-and-amorphous-boron-alloys-9781782629191","title":"Alternative Catalytic Materials: Carbides,","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eMany important industrial chemical processes rely heavily on catalysis and so researchers are always on the lookout for alternative catalytic materials that may improve existing processes or lead to new ones. Families of alternative catalytic materials currently being investigated include the carbides, nitrides and phosphides as well as amorphous boron catalysts. The addition of carbon, nitrogen or phosphorous to transition metals and the creation of boron-transition metal alloys leads to catalytic materials that have interesting properties, with applications in a range of different reactions, including electrocatalysis.   This book provides a comprehensive account of the preparation, characterisation and application of these catalytic materials. It is an important reference for researchers and industrialists working in heterogeneous catalysis and materials chemistry.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eIntroduction to the Application of Nitrides, Carbides, Phosphides and Amorphous Boron Alloys in Catalysis; Preparation Methods for Nitride and Carbide Catalysts; Metal Phosphides and Their Applications in Catalysis; Metal Carbide Catalysts; Metal Nitride Catalysts; Amorphous Boron Alloys and Their Catalytic Behaviour; Alternative Materials for Chemical Looping Applications; Applications of Transition Metal Nitrides as Electrocatalysts; Electrocatalysis with Metal Phosphides; Concluding Remarks","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887693640023,"sku":"9781782629191","price":116.85,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781782629191.jpg?v=1791476908"},{"product_id":"nox-trap-catalysts-and-technologies-fundamentals-and-industrial-applications-9781782629313","title":"NOx Trap Catalysts and Technologies: Fundamentals","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eVehicle exhaust emissions, particularly from diesel cars, are considered to be a significant problem for the environment and human health. Lean NOx Trap (LNT) or NOx Storage\/Reduction (NSR) technology is one of the current techniques used in the abatement of NOx from lean exhausts. Researchers are constantly searching for new inexpensive catalysts with high efficiency at low temperatures and negligible fuel penalties, to meet the challenges of this field.    This book will be the first to comprehensively present the current research on this important area. Covering the technology used, from its development in the early 1990s up to the current state-of-the-art technologies and new legislation. Beginning with the fundamental aspects of the process, the discussion will cover the real application standard through to the detailed modelling of full scale catalysts. Scientists, academic and industrial researchers, engineers working in the automotive sector and technicians working on emission control will find this book an invaluable resource.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eReview of deNOx Technology for Mobile Applications; NSR Technology; NSR Catalytic Materials; Lean NOx Trap Performance Degradation - Reversible Sulfur Poisoning and Irreversible Thermally-induced Sintering; Mechanism and Kinetics of NOx Storage; Active Sites for NOx Uptake, and the Nature of Stored NOx Species; Mechanistic Aspects of the Reduction of the Stored NOx by H2 Investigated by Isotopic Labelling Experiments and FTIR Spectroscopy; NOx Storage and Reduction: Effects of Pt Dispersion, Reductant Type, and Cycle Timing; Reduction of Stored NOx with CO\/H2 and Hydrocarbons: A Spatial Resolution Analysis; Global Kinetic Modelling of the NSR Catalysts; Combined LNT-SCR Catalysts for NOx Reduction from Lean Exhaust Gas; LNT Catalysts for the Simultaneous Removal of NOx and Soot: The DPNR Concept; Non-thermal Plasma NOx Storage-reduction; New deNOx Concept by Fast Reductants Injection Pulse Upstream NSR; Development of Combined NSR DeNOx and DeSOx Model and Application for Control Strategy Pre-calibration of a Modern Diesel Engine; LNT Catalysis at Ford Motor Company - A Case History","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887693771095,"sku":"9781782629313","price":170.05,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781782629313.jpg?v=1791476908"},{"product_id":"catalysis-volume-29-9781782629566","title":"Catalysis: Volume 29","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eCatalysts are required for a variety of applications and industrialists and academics are increasingly challenged to find cost effective and environmentally benign catalysts to use. This volume looks at modern approaches to catalysis and reviews the extensive literature on areas such as electrochemical promotion of catalysis, biodiesel-based metals on emission control devices, deoxygenation of fatty acids and transitioning rationally designed catalytic materials to real world catalysts produced on a commercial scale.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eAdvances in methanation catalysis; Recent advances in electrochemical promotion of catalysis; Mixed metal oxides and catalytic redox cycles; Heterogeneous electrocatalysts for CO2 reduction; Production and use of H2O2 for atom-efficient functionalization of hydrocarbons and small molecules; Transitioning rationally designed catalytic materials to real \"working\" catalysts produced at commercial scale: nanoparticle materials; Dehydrogenation of long chain n-paraffins to olefins - a perspective; Investigations of the impact of biodiesel metal contaminants on emissions control devices","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887694131543,"sku":"9781782629566","price":314.95,"currency_code":"GBP","in_stock":true}]},{"product_id":"sustainable-catalysis-for-biorefineries-9781782629634","title":"Sustainable Catalysis for Biorefineries","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eBiorefineries are becoming increasingly important in providing sustainable routes for chemical industry processes. The establishment of bio-economic models, based on biorefineries for the creation of innovative products with high added value, such as biochemicals and bioplastics, allows the development of “green chemistry” methods in synergy with traditional chemistry. This reduces the heavy dependence on imports and assists the development of economically and environmentally sustainable production processes, that accommodate the huge investments, research and innovation efforts.    This book explores the most effective or promising catalytic processes for the conversion of biobased components into high added value products, as platform chemicals and intermediates. With a focus on heterogeneous catalysis, this book is ideal for researchers working in catalysis and in green chemistry.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eCatalysts for Co-processing Biomass in Oil Refining Industry; Catalytic Processes and Catalyst Development in Biorefining; Catalysts for Depolymerization of Biomass; Advances in Catalytic Processes of Microalgae Conversion into Biofuels and Chemicals; Catalysts for Biofuels Production; Catalytic Upgrading of Bio-oils; Noble Metal Based Bimetallic Catalysts for the Catalytic Hydrotreatment of Phenolic Model Components for (Pyrolytic) Lignins; Microwaves in the Catalytic Valorisation of Biomass Derivatives; Biohydrogen and Biomethane Production; Biochar Production, Activation and Application as a Promising Catalyst","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887694229847,"sku":"9781782629634","price":141.55,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781782629634.jpg?v=1791476910"},{"product_id":"biocatalysis-biochemical-fundamentals-and-applications-9781783269082","title":"Biocatalysis: Biochemical Fundamentals And","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eIn this Completely Revised and Extended Edition with a significantly enhanced content, all Chapters have been updated considering relevant literature and recent developments until 2016 together with application oriented examples with a focus on Industrial Biocatalysis. Newly treated topics comprise among others systems metabolic engineering approaches, metagenome screening, new tools for pathway engineering, and de-novo computational design as actual research areas in biocatalysis. Information about different aspects of RNA technologies, and completely new Chapters on 'Fluorescent Proteins' and 'Biocatalysis and Nanotechnology' are also included.","brand":"Imperial College Press","offers":[{"title":"Default Title","offer_id":48887712088407,"sku":"9781783269082","price":76.95,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781783269082.jpg?v=1791477007"},{"product_id":"biocatalysis-biochemical-fundamentals-and-applications-9781783269075","title":"Biocatalysis: Biochemical Fundamentals And","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eIn this Completely Revised and Extended Edition with a significantly enhanced content, all Chapters have been updated considering relevant literature and recent developments until 2016 together with application oriented examples with a focus on Industrial Biocatalysis. Newly treated topics comprise among others systems metabolic engineering approaches, metagenome screening, new tools for pathway engineering, and de-novo computational design as actual research areas in biocatalysis. Information about different aspects of RNA technologies, and completely new Chapters on 'Fluorescent Proteins' and 'Biocatalysis and Nanotechnology' are also included.","brand":"Imperial College Press","offers":[{"title":"Default Title","offer_id":48887712153943,"sku":"9781783269075","price":177.65,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781783269075.jpg?v=1791477007"},{"product_id":"catalysis-with-earth-abundant-elements-9781788011181","title":"Catalysis with Earth-abundant Elements","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eCatalysis remains a key technology in a huge number of industrial processes in the 21st century. The catalytic properties of precious metals such as platinum and palladium are well understood. However, these metals are expensive and their supply is limited. Earth-abundant elements such as iron and nickel are, as the name suggests, in plentiful supply and much cheaper to use, but research on their use in catalysis has, historically, lagged behind. As researchers and companies increasingly look for ways to reduce costs and improve the sustainability of their processes there has been a renewed interest in these earth-abundant elements.    This book presents a detailed overview of current research on the catalytic uses of the most Earth-abundant elements. Highlighting the top ten most Earth-abundant elements and their various roles in modern synthetic chemistry: s-block metals (Na, K, Mg, Ca), first-row transition metals (Ti, Mn, Fe), and p-block elements (Al, Si, P). The significant stoichiometric use of these elements, and their use as acid, base, dual, and\/or redox catalysts will be discussed. It will be of use to industrial and academic researchers as well as graduate students with an interest in catalysis and sustainability.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eNa (including catalysis); K (including catalysis); Mg (stoichiometric use); Mg\/Ca (catalysis) ; Mg\/Ca (asymmetric catalysis); Ti (including catalysis); Mn (catalysis I); Mn (catalysis II); Fe (mechanistic studies); Fe (catalysis); Al (including catalysis); Si (stoichiometric use); Si (catalytic intermediates); P (acid catalysis); P (base catalysis)","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887839392087,"sku":"9781788011181","price":160.55,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788011181.jpg?v=1791477500"},{"product_id":"designing-nanoparticle-systems-for-catalysis-faraday-discussion-208-9781788011594","title":"Designing Nanoparticle Systems for Catalysis:","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThis volume brings together the work of both theoreticians and experimentalists on the synthesis of nanoparticles and their use in catalytic reactions.   Heterogeneous catalysis is a core area of contemporary physical chemistry posing major fundamental and conceptual challenges, and nanoparticles are ubiquitous in many heterogeneous catalysts, therefore it is now opportune to focus a Faraday Discussion on key aspects of their synthesis, characterisation and use.   This Faraday Discussion will explore the modern methods being used to design, synthesise and characterize nanoparticles and how these bridge across the disciplines of physical science and chemical engineering. The core aim of this discussion meeting is to develop a fundamental understanding of these crucial aspects of catalytic science, especially relating to nanoparticle synthesis and use in catalytic reactions, knowledge of which is essential for the design of new catalysts.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eControl of Catalytic Nanoparticle Synthesis; The Challenges of Characterising Nanoparticulate Catalyts; Theory as a driving force to understand reactions on nanoparticles; Application of new nanoparticle structures as catalysts","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887839818071,"sku":"9781788011594","price":161.5,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788011594.jpg?v=1791477501"},{"product_id":"organic-catalysis-for-polymerisation-9781788011846","title":"Organic Catalysis for Polymerisation","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eIn recent years polymerisation using organocatalysts has become an appealing alternative to more traditional metal-based catalysts. Conferring numerous advantages including low cost and ease of use, as well as the ability to precisely control the synthesis of advanced polymer structures, organocatalysts are increasingly used in polymer synthesis. Organic Catalysis for Polymerisation provides a holistic overview of the field, covering all process in the polymer synthesis pathway that are catalysed by organic catalysts. Sub-divided into two key sections for ease of use, the first focuses on recent developments in catalysis and the applications of catalysts to the full range of polymerisations that they have been utilised in; the second concerning monomers, arranges the field by monomer type and polymerisation mechanism. The book will therefore, provide a complimentary view of the field, providing both an overview of state-of-the-art catalyst development and also the best methodologies available to create specific polymer types. Edited by leading figures in the field and featuring contributions from researchers across the globe, this title will serve as an excellent reference for postgraduate students and researchers in both academia and industry interested in polymer chemistry, organic chemistry, catalysis and materials science.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eNucleophilic Catalysts and Organocatalyzed Zwitterionic Ring-opening Polymerization of Heterocyclic Monomers; Ring-opening Polymerization Promoted by Brønsted Acid Catalysts; Bifunctional and Supramolecular Organocatalysts for Polymerization; Base Catalysts for Organopolymerization; Ring-opening Polymerization of Lactones; Organic Catalysis for the Polymerization of Lactide and Related Cyclic Diesters; ROP of Cyclic Carbonates; Metal-free Polyether Synthesis by Organocatalyzed Ringopening Polymerization; Ring-opening Polymerization of N-carboxyanhydrides Using Organic Initiators or Catalysts; Organocatalytic Ring-opening Polymerization Towards Poly(cyclopropane)s, Poly(lactame)s, Poly(aziridine)s, Poly(siloxane)s, Poly(carbosiloxane)s, Poly(phosphate)s, Poly(phosphonate)s, Poly(thiolactone)s, Poly(thionolactone)s and Poly(thiirane)s; Organopolymerization of Acrylic Monomers; Organocatalyzed Step-growth Polymerization; Organocatalyzed Controlled Radical Polymerizations; Organocatalysis for Depolymerisation; Organic Catalysis Outlook: Roadmap for the Future","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887840276823,"sku":"9781788011846","price":189.05,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788011846.jpg?v=1791477501"},{"product_id":"enantioselective-cobalt-catalysed-transformations-9781788014625","title":"Enantioselective Cobalt-catalysed Transformations","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eWith a foreword from leading organic chemist Professor Paul Wender, this book collects the major developments reported in the past thirty years in the field of enantioselective reactions promoted by chiral cobalt catalysts, illustrating the power of these green catalysts to provide all types of organic reactions from the basic to completely novel methodologies.    The search for new methodologies to prepare optically pure products is one of the most active areas of research in organic synthesis. Of the methods available for preparing chiral compounds, catalytic asymmetric synthesis has attracted the most attention. In particular, asymmetric transition-metal catalysis is a powerful tool for performing reactions in a highly enantioselective fashion. Efforts to develop new asymmetric transformations have previously focused on the use of rare metals such as titanium, palladium, iridium and gold. However, the ever-growing need for environmentally friendly catalytic processes has prompted chemists to focus on the more abundant and less toxic first-row transition metals, such as cobalt, to develop new catalytic systems.    The ability of cobalt catalysts to adopt unexpected reaction pathways has led to an impressive number of enantioselective cobalt-promoted transformations being developed over the past three decades. These have included the synthesis of many different types of products, often under relatively mild conditions and with remarkable enantioselectivities. This book is a useful reference resource for chemists, both academic and industrial, working in organic synthesis and interested in greener or more economical catalytic alternatives.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eForeword; Enantioselective Cobalt-Catalysed [2+1] Cycloadditions; Other Enantioselective Cobalt-Catalysed Cycloadditions; Enantioselective Cobalt-Catalysed Cyclisations through Domino Reactions; Miscellaneous Enantioselective Cobalt-Catalysed Cyclisations; Synthesis of Chiral Acyclic Compounds through Enantioselective Cobalt-Catalysed Reduction Reactions; Synthesis of Chiral Acyclic Compounds through Enantioselective Cobalt-Catalysed Ring-Opening Reactions; Synthesis of Chiral Acyclic Compounds through Enantioselective Cobalt-Catalysed Michael and (Nitro)-Aldol Reactions; Synthesis of Chiral Acyclic Compounds through Enantioselective Cobalt-Catalysed 1,2-Nucleophilic Additions to Carbonyl Compounds and Derivatives; Synthesis of Chiral Acyclic Compounds through Enantioselective Cobalt-Catalysed Cross-Coupling Reactions; Synthesis of Chiral Acyclic Compounds through Enantioselective Cobalt-Catalysed Hydrovinylation Reactions; Synthesis of Chiral Acyclic Compounds through Miscellaneous Enantioselective Cobalt-Catalysed Reactions; General Conclusion","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887842406743,"sku":"9781788014625","price":116.85,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788014625.jpg?v=1791477506"},{"product_id":"noncovalent-interactions-in-catalysis-9781788014687","title":"Noncovalent Interactions in Catalysis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eNoncovalent interactions often provide the spine of biomolecular and material structures, and can therefore play a key role in biological and catalytic processes. Selectivity in chemical reactions, particularly in catalytic processes, is often an orchestral action of various noncovalent interactions occurring in intermediates and transition states. Although the role of hydrogen bonding is well explored in catalysis, the other types of weak interactions, namely cation–π, anion–π, π–π stacking, pseudo-agostic, halogen, chalcogen, pnictogen, tetrel and icosagen bonds, must also be considered. Naturally, the chemo-, regio- or stereoselectivity of a reaction depends on the stability of such noncovalent-interaction-supported species in catalytic systems. Therefore, an in-depth understanding of these weak interactions may be the key to designing new catalytic materials.    Providing an overview of the role of these different types of noncovalent interactions in both homogenous and heterogeneous catalysis, this book is a valuable resource for synthetic chemists who are interested in exploring and further developing noncovalent-interaction-assisted synthesis and catalysis.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eNoncovalent Interactions in C–H Bond Functionalization; Importance of C–H Hydrogen Bonding in Asymmetric Catalysis; Catalysis by Networks of Cooperative Hydrogen Bonds; Secondary (Agostic Si–H\/Electrostatic C–F) Interactions in Alkaline Earth-based Catalysts; Anion–π Catalysis; Onium Ion-assisted Organic Reactions Through Cation–π Interactions; The Role of Noncovalent Interactions in the Efficiency of Dendrimers in Catalysis; Noncovalent Interactions in Hydrogenation and Hydroformylation; Soft Forces in Organic Synthesis by C–N Coupling Reactions; Noncovalent Interactions in the Design of Chiral Brønsted Acid Catalysts; Noncovalent Interactions in the Nitroaldol (Henry) Reaction; Noncovalent Interactions in Asymmetric Reactions Catalysed by Chiral Phosphoric Acids; Baeyer–Villiger Oxidation Promoted by Noncovalent Interactions; Noncovalent Interactionassisted Redox Catalysis in Reductive Dehalogenation; Noncovalent Immobilization of Catalysts on Electrode Surfaces; Noncovalent Interactions in Ionic Liquids; Ionic Liquid Effect in Catalysed Multicomponent Reactions; Noncovalent Interactions in Olefin Polymerization Catalysis Promoted by Transition Metals; Influence of Noncovalent Interactions in Catalytic Ring-opening Polymerization Processes; Cavity Effects in Metal–Organic Frameworks; Cavity Effects in Metal–Organic Frameworks in CO2 Capture and Conversion; Hybrids of Metal–Organic Frameworks as Organized Supramolecular Nano-reactors; The Nature of Hydrogen Bonding in Adsorbed CO2 and H2O on Solid Amines in CO2 Capture; Noncovalent Interactions of Biogenic Impurities with Transition Metal Catalyst Surfaces; Mechanochemical Activation and Catalysis; Role of Ion Pairing in the Mechanisms of Au(i)-catalysed Reactions: Theory and Experiment; Noncovalent Interactions in Key Metal-centred Catalytic Intermediates: Structure– Electronic Relationship; Noncovalent Interactions in Biocatalysis – A Theoretical Perspective; Analysis of Reactivity from the Noncovalent Interactions Perspective","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887842472279,"sku":"9781788014687","price":189.05,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788014687.jpg?v=1791477508"},{"product_id":"nanoparticle-design-and-characterization-for-catalytic-applications-in-sustainable-chemistry-9781788014908","title":"Nanoparticle Design and Characterization for","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eNanoparticles exhibit a range of different properties when compared to bulk materials. Their high surface-area to volume ratio makes them particularly attractive for use as catalysts and recent years have seen an explosion of research in this area. The ability to fine-tune the size and structure of nanoparticles means that it is possible to design catalytic materials for improved activity or specificity.   As catalysis is one of the key technologies for more sustainable production of both chemicals and energy, the past few years have seen increasing numbers of nanomaterials reported for these applications. Depending on the application, a number of different catalyst synthesis and optimization protocols can be used. This book provides comprehensive links between the design and fabrication method for nanoparticles and their catalytic performance (activity, selectivity and stability) in various applications.   Presenting an introduction to the concept of catalyst design and recent developments in the preparation and characterisation of nanomaterials, followed by several chapters on the design of catalysts for specific applications, this book is a valuable resource for researchers working on catalytic reactions, industrial processes and nanomaterial applications.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eIntroduction to Nanocatalysts; Characterization of Nanoparticles: Advances; Support Morphology-dependent Activity of Nanocatalysts; Design of Metal-modified Zeolites and Mesoporous Aluminosilicates and Application in the Synthesis of Fine Chemicals; Metal–Organic-framework Nanoparticles: Synthesis, Characterization and Catalytic Applications; Design of Metal-free Nanocatalysts; Nanoparticle Design for the Catalytic Valorization of Lignocellulosic Biomass; Nanocatalysts for CO2 Conversion; Nanoparticles and Nanocomposites Design in Photocatalysis; Nanoparticles in the Water–Gas Shift Reaction and Steam Reforming Reactions; Plasmonic Photocatalysts for Environmental Applications; Nanoparticles-based Electrochemical Sensors and Biosensors","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887842767191,"sku":"9781788014908","price":141.55,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788014908.jpg?v=1791477507"},{"product_id":"carbon-dioxide-electrochemistry-homogeneous-and-heterogeneous-catalysis-9781788015462","title":"Carbon Dioxide Electrochemistry: Homogeneous and","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eConversion of light and electricity to chemicals is an important component of a sustainable energy system. The exponential growth in renewable energy generation implies that there will be strong market pull for chemical energy storage technology in the near future, and here carbon dioxide utilization must play a central role. The electrochemical conversion of carbon dioxide is key in achieving these goals. Carbon Dioxide Electrochemistry showcases different advances in the field, and bridges the two worlds of homogeneous and heterogeneous catalysis that are often perceived as in competition in research. Chapters cover homogeneous and heterogeneous electrochemical reduction of CO2, nanostructures for CO2 reduction, hybrid systems for CO2 conversion, electrochemical reactors, theoretical approaches to catalytic reduction of CO2, and photoelectrodes for electrochemical conversion. With internationally well-known editors and authors, this book will appeal to graduate students and researchers in energy, catalysis, chemical engineering and chemistry who work on carbon dioxide.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eApproaches to Controlling Homogeneous Electrochemical Reduction of Carbon Dioxide; Homogeneous Electrochemical Reduction of CO2: From Homogeneous to Supported Systems; Heterogeneous Electrochemical CO2 Reduction; Nanostructures for CO2 reduction: from theoretical insight to material design; Theoretical Approach to Homogeneous Catalytic Reduction of CO2: Mechanistic Understanding to Build New Catalysts; Bridging Homogeneous and Heterogeneous Systems: Atomically Dispersed Metal Atoms in Carbon Matrices for Electrocatalytic CO2 Reduction; Bridging Homogeneous and Heterogeneous systems: Photoelectrodes for CO2 Electrochemical Conversion; Hybrid Biological-Inorganic Systems for CO2 Conversion to Fuels; In Situ Spectroscopic Methods to Study Electrochemical CO2 Reduction; Electrochemical Reactors","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887843324247,"sku":"9781788015462","price":170.05,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788015462.jpg?v=1791477509"},{"product_id":"hot-electron-science-and-microscopic-processes-in-plasmonics-and-catalysis-faraday-discussion-214-9781788016704","title":"Hot-electron Science and Microscopic Processes in","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eOver the last 10 years, the field of plasmonic research has emerged as an extremely promising technology with several main fields of application: information technologies, energy, high-density data storage, photovoltaics, chemistry, biology, medicine and security. The main focus up to a few years ago was on the ability of plasmonic nanostructures to generate localized regions of highly concentrated electromagnetic fields, however more recently it has also been realized that the electron part of plasmonic excitations can also be exploited in the physical and chemical sciences.    Fascinating proof-of-concept applications have over the last three years been demonstrated in areas such as surface-enhanced catalysis (water splitting), photodetectors without bandgaps (Schottky junctions), and nanoscale control over chemical reactions. These applications as well as the most recent breakthroughs and key challenges in this multidisciplinary and dynamic field are the focus of this Faraday Discussion, offering the perspectives of physicists, chemists and ab-initio theoreticians.   In this volume the topics covered include:      Dynamics of hot electron generation in metallic nanostructures  Theory of hot electrons  New materials for hot electron generation  Applications in catalysis, photochemistry, and photodetection\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eDynamics of Hot-electron Generation in Metallic Nanostructures; Theory of Hot-electrons; New Materials for Hot-electron Generation; Applications in Catalysis, Photochemistry, and Photodetection","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887843553623,"sku":"9781788016704","price":161.5,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788016704.jpg?v=1791477510"},{"product_id":"catalytic-aerobic-oxidations-9781788017206","title":"Catalytic Aerobic Oxidations","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eOxidation reactions are an important chemical transformation in both academia and industry. Among the major advances in the field has been the development of catalytic processes, which are not only selective and efficient, but also allow the replacement of common stoichiometric oxidants with molecular oxygen, ideally from air at atmospheric pressure. This results in processes with higher atom efficiency, where water is the only side product in line with the principles of green chemistry.   Focusing on the use of molecular oxygen as the terminal oxidant, this book covers recent advances in both heterogeneous and homogeneous systems, with and without metals and on the “taming” of the highly reactive oxygen gas by use of micro-flow reactors and membranes. A useful reference for industrial and academic chemists working on oxidation processes, as well as green chemists.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eIntroduction: Catalysis, Oxygen and Sustainability; Aerobic Oxidations Reactions using Metal-Based Homogeneous Systems; Aerobic Oxidations Reactions using Metal-Based Heterogeneous Systems; Aerobic Oxidations Reactions using Metal-Free Heterogeneous Systems; Aerobic Oxidations Reactions using Metal-Free Homogeneous Systems; Photocatalytic Aerobic Oxidations Reactions; Bio-catalyzed Aerobic Oxidations Reactions; Aerobic Oxidation Reactions in Continuous Flow Microreactors; Aerobic Oxidation Reactions in Fine Chemicals and Pharmaceuticals Industries; Industrial Aerobic Oxidation Reactions of Hydrocarbons","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887843946839,"sku":"9781788017206","price":160.55,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788017206.jpg?v=1791477510"},{"product_id":"heterogeneous-catalysis-for-energy-applications-9781788017183","title":"Heterogeneous Catalysis for Energy Applications","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eHeterogeneous catalysis plays a central role in the global energy paradigm, with practically all energy-related process relying on a catalyst at a certain point. The application of heterogeneous catalysts will be of paramount importance to achieve the transition towards low carbon and sustainable societies. This book provides an overview of the design, limitations and challenges of heterogeneous catalysts for energy applications. In an attempt to cover a broad spectrum of scenarios, the book considers traditional processes linked to fossil fuels such as reforming and hydrocracking, as well as catalysis for sustainable energy applications such as hydrogen production, photocatalysis, biomass upgrading and conversion of CO2 to clean fuels. Novel approaches in catalysts design are covered, including microchannel reactors and structured catalysts, catalytic membranes and ionic liquids. With contributions from leaders in the field, Heterogeneous Catalysis for Energy Applications will be an essential toolkit for chemists, physicists, chemical engineers and industrials working on energy.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eDesign of advanced catalysts for natural gas reforming reactions; Catalysis for industrial hydrocracking processes; Catalytic Upgrading of hydrocarbon: approaches using sub and supercritical water as reaction media; Sustainable photocatalytic materials for clean energy applications; Catalytic Technologies for clean hydrogen production; Application of solid catalysts on catalytic conversion of biomass into valuable chemicals; Catalysis in modern bio-refineries: towards a new bio-energy paradigm; Microchannel reactors, structured catalysts and non-conventional reactor design for energy applications; MOFS – from material chemistry to catalytic applications; Application of Ionic Liquids for Sustainable Catalysis; Catalytic membranes and their application in green energy technologies; Catalytic Conversion of CO2 to fuels and added value Chemicals; Operando Characterisation of model energy catalysts: from fundamental aspects to real catalysts design; Catalysts design for Gas to Liquid processes; Catalytic aspects of Fuels cells and Electrolysers","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887843979607,"sku":"9781788017183","price":170.05,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788017183.jpg?v=1791477511"},{"product_id":"carbon-nanomaterials-in-hydrogenation-catalysis-9781788017237","title":"Carbon Nanomaterials in Hydrogenation Catalysis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eHydrogenation is a key reaction in both the food and petrochemical industries, where it is used to reduce carbon–carbon double bonds. Without a catalyst, hydrogenation reactions require extreme temperatures to occur, meaning catalysts are essential for the reaction to be industrially useful. During the past decade, the properties of many carbon nanomaterials that are relevant to hydrogenation catalysis have been described, including carbon nanotubes (CNTs), carbon nanofibers (CNFs), carbon nanohorns (CNHs), graphene oxide (GO), reduced graphene oxides (rGO) and fullerenes, that are relevant to hydrogenation catalysis, have been described. For many of these the production methods have advanced to the commercial stage. Numerous studies on the development of catalysts on carbon nano-supports have appeared in the scientific literature and these catalysts have shown remarkable activity and specificity.  Carbon Nanomaterials in Hydrogenation Catalysis is a valuable reference for researchers and chemical engineers working on improving hydrogenation processes and those interested in applications for carbon nanomaterials. Covering their production, modification and applications as a catalyst support this book provides an in-depth review of the current state-of-the art in using carbon nanomaterials for hydrogenation reactions.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eIntroduction; Properties of Carbons; Modifications of Carbon Nanomaterials; Stability of Carbon Nanosupports; Reactants and Feeds; Development of Catalysts Supported on Carbon Nanosupports; Catalysts Supported on Carbon Nanotubes; Catalysts Supported on Carbon Nanofibers and Carbon Nanohorns; Catalysts Supported on Graphenes; Catalysts Supported on Fullerenes; Selection of Carbon Supports; Future Perspectives","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887844208983,"sku":"9781788017237","price":141.55,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788017237.jpg?v=1791477511"},{"product_id":"reactivity-in-confined-spaces-9781788017763","title":"Reactivity in Confined Spaces","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eThe chemistry that occurs within confined spaces is the product of a collection of forces, often beyond the molecule, and is not easily ascribed to singular factors. There is a breadth of material types that can define a confined space (e.g. macrocycles, interlocked molecules, porous and non-porous crystals, organic and inorganic\/coordination cages) which are rarely discussed together. Studies of supramolecular entities in the solution and solid states are also not often compared in the same discussion, even though the concepts are often similar or can be easily transferred between the two.  Chapters in this book combine classical host-guest chemistry with catalysis, reactivity, and modern supramolecular chemistry. They cover the many different technologies used to describe and understand reactivity in confined spaces in one accessible title. With contributions from leading experts, Reactivity in Confined Spaces will be relevant for graduate students and researchers working in supramolecular chemistry, both organic- and inorganic-based, homogeneous and heterogeneous catalysis, polymer chemistry, and materials science in general.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eMacrocycles, Catenanes and Rotaxanes; Catalytic Strategies Within the Confined Spaces of Coordination Cages; Light-induced Processes in Coordination Cages; Stabilising Reactive Intermediates in Cages; Reactivity in a Self-assembled Organic Host; Properties and Reactivities of Metal Complexes Within Organic Nanocontainers; Catalysis at the Confined Interface of Supramolecular Gels; Catalysis in Confined Space: Relationship Between Metal–Organic Frameworks and Discrete Coordination Cages; Solid\/Gas Reactivity of Organometallic Species in Confined Spaces; Topochemistry Meets Supramolecular Chemistry: Opportunities for Targeted Organic Synthesis in Molecular Crystals; Stabilising and Characterising Homogeneous Catalysts in MOFs; Biomimetic Metal–Organic Frameworks: Construction and Catalytic Performance; Catalytic Nanoparticles in Metal–Organic Frameworks; Atomically Precise Metal Clusters in Confined Spaces of Metal–Organic Frameworks","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887844864343,"sku":"9781788017763","price":170.05,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788017763.jpg?v=1791477513"},{"product_id":"vanadium-catalysis-9781788018579","title":"Vanadium Catalysis","description":"\u003cb\u003eBook Synopsis\u003c\/b\u003e\u003cbr\u003eVanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast.   Bringing together the research on the catalytic uses of this element into one essential resource, including theoretical perspectives on proposed mechanisms for vanadium catalysis and an overview of its relevance in biological processes, this book is a useful reference for industrial and academic chemists alike.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eTable of Contents\u003c\/b\u003e\u003cbr\u003eIntroduction; Amavadin and related complexes as oxidation catalysts (alkane carboxylation, electrocatalytic oxidation of thiols, oxidation of water); Activating peroxides by vanadium(V) compounds; The vanadate\/pyrazinecarboxylic acid\/hydrogen peroxide reagent and similar systems for efficient oxidations with peroxides; Peroxido-vanadium complexes as sustainable catalysts in oxidations, halogenations and other organic transformations; Vanadium-scorpionate catalyzed oxidations; Vanadium-carbohydrazones catalyzed oxidations; Polyoxidovanadate catalysts in nonaqeuous solution; Polyoxidometalates and soft-oxidometalates in catalysis; Use of vanadium catalysts in epoxidation and sulfoxidation reactions with  Green Chemistry criteria; Vanadium-based catalysts: heterogeneous molecular complexes, supramolecular compounds, and their applications; Carbon-supported vanadium catalysis; Structure, characterization and applications of VOx supported materials; Vanadium oxides in photocatalysis, including bare oxides and VOx based organic-inorganic nanocomposites; Theoretical mechanistic analysis on vanadium oxidation catalysis; Vanadium catalyzed olefin oligomerization, polymerization and copolymerization; Vanadium catalyzed olefin metathesis and related chemistry; Vanadium catalyzed enantioselective C-C bond forming reactions; Vanadium-induced oxidative and reductive coupling; Vanadium-catalyzed transformations of selected functional groups; Catalysis exerted by cells on polyoxidometalate anions; Dioxygen activation by biomimetic vanadium complexes; Vanadium in catalytically proceeding natural processes; Vanadium chloroperoxidases as versatile biocatalysts; Vanadium catalysis relevant to nitrogenase","brand":"Royal Society of Chemistry","offers":[{"title":"Default Title","offer_id":48887845257559,"sku":"9781788018579","price":189.05,"currency_code":"GBP","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0817\/1739\/5799\/files\/9781788018579.jpg?v=1791477513"}],"url":"https:\/\/bookcurl.com\/collections\/catalysis.oembed?page=5","provider":"Book Curl","version":"1.0","type":"link"}